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Synthesis, characterization and phase transitions of the inorganic–organic layered perovskite-type hybrids [(CnH2n+1NH3)2PbI4] (n = 12, 14, 16 and 18)
Abstract
The room temperature single-crystal structures of the inorganic–organic layered perovskite-type hybrids of general formula [(CnH2n+1NH3)2PbI4] (n = 12, 14, 16 and 18) have been determined. The four compounds each display two reversible phase transitions above room temperature, with phases labelled III, II and I. The single-crystal structures of phase II have also been determined. The phase transition from phase III to phase II is a first-order transition and corresponds to a change in the conformation of the alkylammonium chains and a shift of the inorganic layers relative to each other. The phase change from III to II is thermochromic for all compounds, going from a yellow to an orange colour.
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Cited by
Li, X., Hoffman, J. M., & Kanatzidis, M. G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01006 · Cited by 1,085
Du, K.-Z., Tu, Q., Zhang, X., Han, Q., Liu, J., Zauscher, S., & Mitzi, D. B. (2017) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b01094 · Cited by 587
Yangui, A., Garrot, D., Lauret, J. S., Lusson, A., Bouchez, G., Deleporte, E., Pillet, S., Bendeif, E. E., Castro, M., Triki, S., et al. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b06211 · Cited by 312
Lyu, R., Moore, C. E., Liu, T., Yu, Y., & Wu, Y. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05441 · Cited by 114
Metadata
- Authors
- Billing, D. G., & Lemmerer, A.
- Venue
- New Journal of Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 32
- Issue
- 10
- Pages
- 1736
- ISSN
- 0398-9836 (ISSN-L)
- 1144-0546
- 1369-9261
- OpenAlex
- W2092705122
- Cited by
- 183
- References
- 0
- FWCI
- 1.79
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Synthesis, characterization and phase transitions of the inorganic–organic layered perovskite-type hybrids [(CnH2n+1NH3)2PbI4] (n = 12, 14, 16 and 18). https://app.cochat.ai/papers/10.1039/b805417g
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- Billing, D. G., & Lemmerer, A. (2008). Synthesis, characterization and phase transitions of the inorganic–organic layered perovskite-type hybrids [(CnH2n+1NH3)2PbI4] (n = 12, 14, 16 and 18). New Journal of Chemistry. https://doi.org/10.1039/b805417g
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