The DOI matches its Crossref record; 55 of the 55 references it cites were found in a registry or an index.
Bite angle effects of diphosphines in C–C and C–X bond forming cross coupling reactions
Abstract
Catalytic reactions of C-C and C-X bond formation are discussed in this critical review with particular emphasis on cross coupling reactions catalyzed by palladium and wide bite angle bidentate diphosphine ligands. Especially those studies have been collected that allow comparison of the ligand bite angles for the selected ligands: dppp, BINAP, dppf, DPEphos and Xantphos. Similarities with hydrocyanation and CO/ethene/MeOH reactions have been highlighted, while rhodium hydroformylation has been mentioned as a contrasting example, in which predictability is high and steric and electronic effects follow smooth trends. In palladium catalysis wide bite angles and bulkiness of the ligands facilitate generally the reductive elimination thus giving more efficient cross coupling catalysis (174 references).
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Asymmetric Transition-Metal-Catalyzed Allylic Alkylations: Applications in Total Synthesis
Trost, B. M., & Crawley, M. L. (2003) · Chemical Reviews · doi:10.1021/cr020027w · Cited by 2,845
Palladium‐Catalyzed Cross‐Coupling Reactions in Total Synthesis
Nicolaou, K. C., Bulger, P. G., & Sarlah, D. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200500368 · Cited by 2,708
Modern Synthetic Methods for Copper‐Mediated C(aryl)O, C(aryl)N, and C(aryl)S Bond Formation
Ley, S. V., & Thomas, A. W. (2003) · Angewandte Chemie International Edition · doi:10.1002/anie.200300594 · Cited by 2,554
Catalysts for Suzuki−Miyaura Coupling Processes: Scope and Studies of the Effect of Ligand Structure
Barder, T. E., Walker, S. D., Martinelli, J. R., & Buchwald, S. L. (2005) · Journal of the American Chemical Society · doi:10.1021/ja042491j · Cited by 1,796
Rational Development of Practical Catalysts for Aromatic Carbon−Nitrogen Bond Formation
Wolfe, J. P., Wagaw, S., Marcoux, J.-F., & Buchwald, S. L. (1998) · Accounts of Chemical Research · doi:10.1021/ar9600650 · Cited by 1,791
Hartwig, J. F. (1998) · Angewandte Chemie International Edition · Cited by 1,719
Kantchev, E. A. B., O'Brien, C. J., & Organ, M. G. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200601663 · Cited by 1,616
Metal-Catalyzed Carbon−Sulfur Bond Formation
Kondo, T., & Mitsudo, T. (2000) · Chemical Reviews · doi:10.1021/cr9902749 · Cited by 1,415
Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation
van Leeuwen, P. W. N. M., Kamer, P. C. J., Reek, J. N. H., & Dierkes, P. (2000) · Chemical Reviews · doi:10.1021/cr9902704 · Cited by 1,053
Self-citationPalladium-Catalyzed Alternating Copolymerization of Alkenes and Carbon Monoxide
Drent, E., & Budzelaar, P. H. M. (1996) · Chemical Reviews · doi:10.1021/cr940282j · Cited by 974
Cited by
Computational Ligand Descriptors for Catalyst Design
Durand, D. J., & Fey, N. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00588 · Cited by 406
Metadata
- Authors
- Birkholz (née Gensow), M.-N., Freixa, Z., & van Leeuwen, P. W. N. M.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2009
- Volume
- 38
- Issue
- 4
- Pages
- 1099
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2141725143
- Cited by
- 585
- References
- 55
- FWCI
- 1.00
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Bite angle effects of diphosphines in C–C and C–X bond forming cross coupling reactions. https://app.cochat.ai/papers/10.1039/b806211k
- The paper
- Birkholz (née Gensow), M.-N., Freixa, Z., & van Leeuwen, P. W. N. M. (2009). Bite angle effects of diphosphines in C–C and C–X bond forming cross coupling reactions. Chemical Society Reviews. https://doi.org/10.1039/b806211k
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
