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Selective hydrolysis of cellulose into glucose over solid acid catalysts
Abstract
The mildly hydrothermal method using solid acid catalysts for the glucose production from cellulose can be one of the key technologies for a future sustainable society using cellulose biomass. This article is the first to indicate solid acid catalysis for the hydrolysis of cellulose with β-1,4-glycosidic bonds into glucose selectively higher than 90 C-%. Among the solid acid catalysts we tested, such as the H-form zeolite catalysts and the sulfated and sulfonated catalysts, a sulfonated activated-carbon catalyst showed a remarkably high yield of glucose, which was due to the high hydrothermal stability and the excellent catalytic property attributed to the strong acid sites of SO3H functional groups and the hydrophobic planes.
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Cited by
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Clarke, C. J., Tu, W.-C., Levers, O., Bröhl, A., & Hallett, J. P. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00571 · Cited by 2,071
Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels
Zhou, C.-H., Xia, X., Lin, C.-X., Tong, D.-S., & Beltramini, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15124j · Cited by 1,420
Catalytic conversion of lignocellulosic biomass into chemicals and fuels
Deng, W., Feng, Y., Fu, J., Guo, H., Guo, Y., Han, B., Jiang, Z., Kong, L., Li, C., Liu, H., et al. (2023) · Green Energy & Environment · doi:10.1016/j.gee.2022.07.003 · Cited by 854
Hydrogenolysis Goes Bio: From Carbohydrates and Sugar Alcohols to Platform Chemicals
Ruppert, A. M., Weinberg, K., & Palkovits, R. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201105125 · Cited by 836
Synthesis and utilisation of sugar compounds derived from lignocellulosic biomass
Kobayashi, H., & Fukuoka, A. (2013) · Green Chemistry · doi:10.1039/c3gc00060e · Cited by 489
Metadata
- Authors
- Onda, A., Ochi, T., & Yanagisawa, K.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 10
- Issue
- 10
- Pages
- 1033
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2036683485
- Cited by
- 602
- References
- 0
- FWCI
- 18.55
- Type
- journal article
- Language
- en
- Open access
- closed
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