The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
The identification of hydroxyl groups on ZnO nanoparticles by infrared spectroscopy
Abstract
The interaction of water with ZnO nanoparticles has been studied by means of diffuse reflectance infrared spectroscopy (DRIFTS) and ultra-high vacuum FTIR spectroscopy (UHV-FTIRS). Exposing clean ZnO powder to water at 323 K leads to both molecular and dissociative adsorption of H2O forming a number of hydroxyl species. All the OH bands are clearly identified by the adsorption of D2O showing the expected isotopic shifts. According to the vibrational and thermal stability data obtained from single crystal surfaces, the OH species observed on ZnO nanoparticles are identified as follows: (1) OH group (3620 cm(-1)) on the polar O-ZnO(0001[combining macron]) surface formed via dissociation of water on oxygen vacancy sites; (2) partial dissociation of water on the mixed-terminated ZnO(101[combining macron]0) surface yielding coexistent H2O ( approximately 3150 and 3687 cm(-1)) and OH species (3672 cm(-1)), where the molecularly adsorbed H2O is further identified by the characteristic scissoring mode at 1617 cm(-1); (3) isolated OH species (3639 and 3656 cm(-1)) formed on the mixed-terminated ZnO(101[combining macron]0) surface; (4) interaction of water with defects forming hydroxyl (or O-HO) species (3564 and 3448 cm(-1)).
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Cites
The surface science of titanium dioxide
Diebold, U. (2003) · Surface Science Reports · doi:10.1016/s0167-5729(02)00100-0 · Cited by 7,944
The interaction of water with solid surfaces: fundamental aspects revisited
Henderson, M. (2002) · Surface Science Reports · doi:10.1016/s0167-5729(01)00020-6 · Cited by 2,299
Surface Science Studies of the Photoactivation of TiO 2 New Photochemical Processes
Thompson, T. L., & Yates, J. T. (2006) · Chemical Reviews · doi:10.1021/cr050172k · Cited by 2,064
The chemistry and physics of zinc oxide surfaces
WOLL, C. (2007) · Progress in Surface Science · doi:10.1016/j.progsurf.2006.12.002 · Cited by 826
Density-functional study of the structure and stability of ZnO surfaces
Meyer, B., & Marx, D. (2003) · Physical Review B · doi:10.1103/physrevb.67.035403 · Cited by 634
Direct visualization of defect-mediated dissociation of water on TiO2(110)
Bikondoa, O., Pang, C. L., Ithnin, R., Muryn, C. A., Onishi, H., & Thornton, G. (2006) · Nature Materials · doi:10.1038/nmat1592 · Cited by 620
Novel Stabilization Mechanism on Polar Surfaces: ZnO(0001)-Zn
Dulub, O., Diebold, U., & Kresse, G. (2003) · Physical Review Letters · doi:10.1103/physrevlett.90.016102 · Cited by 547
Yoshihara, J., & Campbell, C. T. (1996) · Journal of Catalysis · doi:10.1006/jcat.1996.0240 · Cited by 417
The infrared spectrum of hydrogen chemisorbed on zinc oxide
Eischens, R. P. (1962) · Journal of Catalysis · doi:10.1016/0021-9517(62)90022-2 · Cited by 196
Water adsorption on ZnO(101̄0): from single molecules to partially dissociated monolayers
Meyer, B., Rabaâ, H., & Marx, D. (2006) · Physical Chemistry Chemical Physics · doi:10.1039/b515604a · Cited by 161
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Uribe-López, M. C., Hidalgo-López, M. C., López-González, R., Frías-Márquez, D. M., Núñez-Nogueira, G., Hernández-Castillo, D., & Alvarez-Lemus, M. A. (2021) · Journal of Photochemistry and Photobiology A: Chemistry · doi:10.1016/j.jphotochem.2020.112866 · Cited by 299
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Metadata
- Authors
- Noei, H., Qiu, H., Wang, Y., Löffler, E., Wöll, C., & Muhler, M.
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 10
- Issue
- 47
- Pages
- 7092
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2007798704
- Cited by
- 419
- References
- 15
- FWCI
- 5.56
- Type
- journal article
- Language
- en
- Open access
- closed
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