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Chiral Brønsted acid catalyzed Friedel–Crafts alkylation reactions
Abstract
The asymmetric Friedel-Crafts reaction is one of the most powerful methods to synthesize optically active aromatic compounds. Particularly, the Friedel-Crafts alkylation of arenes with unsaturated compounds activated by chiral Brønsted acids provides direct access to enantiopure aromatic derivatives with perfect atom economy. In this tutorial review, recent progress in the development of chiral Brønsted acid-catalyzed asymmetric Friedel-Crafts reactions is presented.
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Citations
Cited by
Parmar, D., Sugiono, E., Raja, S., & Rueping, M. (2014) · Chemical Reviews · doi:10.1021/cr5001496 · Cited by 2,118
Combining transition metal catalysis and organocatalysis – an update
Du, Z., & Shao, Z. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35258c · Cited by 706
Chiral phosphoric acid-catalyzed asymmetric dearomatization reactions
Xia, Z.-L., Xu-Xu, Q.-F., Zheng, C., & You, S.-L. (2020) · Chemical Society Reviews · doi:10.1039/c8cs00436f · Cited by 398
Self-citationOrganocatalyzed Asymmetric Friedel–Crafts Reactions
Terrasson, V., Marcia de Figueiredo, R., & Campagne, J. M. (2010) · European Journal of Organic Chemistry · doi:10.1002/ejoc.200901492 · Cited by 286
Wang, X., Liu, J., Xu, L., Hao, Z., Wang, L., & Xiao, J. (2015) · RSC Advances · doi:10.1039/c5ra21919a · Cited by 28
Metadata
- Authors
- You, S.-L., Cai, Q., & Zeng, M.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2009
- Volume
- 38
- Issue
- 8
- Pages
- 2190
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2118422638
- Cited by
- 766
- References
- 0
- FWCI
- 1.76
- Type
- journal article
- Language
- en
- Open access
- closed
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