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Cited by 182

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Selecting metal organic frameworks as enabling materials in mixed matrix membranes for high efficiency natural gas purification

Keskin, Seda, Sholl, David S.·2010·Energy & Environmental Science

Abstract

The addition of nonpolymeric particles to polymer films represents an important avenue for enhancing the performance of polymeric membranes for gas separations. We examine the challenge of selecting metal organic frameworks (MOFs) for use in high performance mixed matrix membranes using a combination of atomistic and continuum modeling. We validate our models by comparing with experimental data for IRMOF-1/Matrimid membranes. We then identify a highly selective MOF that is predicted to greatly enhance the performance of Matrimid and a range of other polymers for CO2/CH4 separations. The methods we introduce will create many opportunities for selecting MOF/polymer combinations for mixed matrix membranes with useful properties for large volume separations.

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Crossref · 10.1039/b923980b

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Metadata

Authors
Keskin, S., & Sholl, D. S.
Venue
Energy & Environmental Science
Published
2010
Volume
3
Issue
3
Pages
343
ISSN
  • 1754-5692 (ISSN-L)
  • 1754-5706
OpenAlex
W2027566647
Cited by
182
References
1
FWCI
31.64
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.