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One-pot formation of SnO2 hollow nanospheres and α-Fe2O3@SnO2 nanorattles with large void space and their lithium storage properties
Abstract
In this work, uniform SnO(2) hollow nanospheres with large void space have been synthesized by a modified facile method. The void space can be easily controlled by varying the reaction time. The formation of interior void space is based on an inside-out Ostwald ripening mechanism. More importantly, this facile one-pot process can be extended to fabricate rattle-type hollow structures using alpha-Fe(2)O(3)@SnO(2) as an example. Furthermore, the electrochemical lithium storage properties have been investigated. It is found that alpha-Fe(2)O(3)@SnO(2) nanorattles manifest a much lower initial irreversible loss and higher reversible capacity compared to SnO(2) hollow spheres. This interesting finding supports a general hypothesis that a synergistic effect between functional core and shell materials can lead to improved lithium storage capabilities.
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Citations
Cited by
Jiang, J., Li, Y., Liu, J., Huang, X., Yuan, C., & Lou, X. W. (. (2012) · Advanced Materials · doi:10.1002/adma.201202146 · Cited by 2,473
Self-citationSynthesis, Properties, and Applications of Hollow Micro-/Nanostructures
Wang, X., Feng, J., Bai, Y., Zhang, Q., & Yin, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00731 · Cited by 1,456
Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries
Wu, H. B., Chen, J. S., Hng, H. H., & Wen (David) Lou, X. (2012) · Nanoscale · doi:10.1039/c2nr11966h · Cited by 1,082
Self-citationMetal–Organic-Frameworks-Derived General Formation of Hollow Structures with High Complexity
Zhang, L., Wu, H. B., & Lou, X. W. (. (2013) · Journal of the American Chemical Society · doi:10.1021/ja401727n · Cited by 580
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Metadata
- Authors
- Chen, J. S., Li, C. M., Zhou, W. W., Yan, Q. Y., Archer, L. A., & Lou, X. W.
- Venue
- Nanoscale
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2009
- Volume
- 1
- Issue
- 2
- Pages
- 280
- ISSN
- 2040-3364 (ISSN-L)
- 2040-3372
- OpenAlex
- W2127578805
- Cited by
- 207
- References
- 0
- FWCI
- 14.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, J. S., Li, C. M., Zhou, W. W., Yan, Q. Y., Archer, L. A., & Lou, X. W. (2009). One-pot formation of SnO2 hollow nanospheres and α-Fe2O3@SnO2 nanorattles with large void space and their lithium storage properties. Nanoscale. https://doi.org/10.1039/b9nr00102f
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