Cited by 28biodegradable polymer synthesis and propertiesEnzyme Catalysis and ImmobilizationAdvanced Polymer Synthesis and Characterization

Entropically-driven ring-opening polymerization of macrocyclic esters with up to 84-membered rings catalysed by polymer-supported Candida antarctica lipase B

Manzini, Barbara, Hodge, Philip, Ben-Haida, Abderrazak·2010·Polym. Chem.

Abstract

Macrocyclic esters with 24- to 84-ring atoms can be polymerized successfully using PS Candida antarctica lipase B as the catalyst. This method allows the polymerization of macrocycles containing substantial in-chain functional moieties, such as monomers incorporating steroid residues. It also affords metal-free products.

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Crossref · 10.1039/b9py00350a

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35 of 35 references verified0 citation errors · 0 not checkable

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  • Gains in rotational and vibrational degrees of freedom can lead to positive changes in ΔS_p° but are only rarely large enough to fully offset the large decrease in translational entropy that usually accompanies polymerization.

    “Gains in rotational and vibrational degrees of freedom can lead to positive changes in Δ S p ° but are only rarely large enough to fully o ff set the large decrease in translational entropy that usually accompanies polymerization. 71,72”

    From Aliphatic Polyester Block Polymer Design (2016) · cites this paper as [71]

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Authors
Manzini, B., Hodge, P., & Ben-Haida, A.
Affiliations
University of Manchester (GB)
Corresponding author
Hodge, Philip
Venue
Polym. Chem.
Published
2010
Volume
1
Issue
3
Pages
339-346
ISSN
  • 1759-9954 (ISSN-L)
  • 1759-9962
OpenAlex
W2017892995
Cited by
28
References
35
Citations by year
2023: 1 · 2022: 2 · 2021: 4 · 2019: 2 · 2017: 3 · 2016: 5 · 2015: 3 · 2014: 2 · 2013: 1 · 2012: 2
FWCI
0.73
Type
journal article
Language
en
Open access
closed
Locations
Polymer Chemistry (publishedVersion)
Funders
Engineering and Physical Sciences Research Council
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Biology › Enzyme Catalysis and Immobilization
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Keywords
ring-opening polymerization, Candida antarctica lipase B, entropic driving force, enzymatic polymerization

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