Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates

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Items 401–494 of 494

1. Molecular Weight Control via Cross Metathesis in Photo‐Redox Mediated Ring‐Opening Metathesis Polymerization
   Victoria K. Kensy, Rachel L. Tritt, Farihah M. Haque, Laura M. Murphy, Daniel B. Knorr, Scott M. Grayson, Andrew J. Boydston · 2020 · Angewandte Chemie
2. Synthetic biodegradable medical polyesters
   P. Dobrzyński, Janusz Kasperczyk, S. Li · 2016 · Elsevier eBooks
3. Iron( <scp>ii</scp> ) carboxylates and simple carboxamides: an inexpensive and modular catalyst system for the synthesis of PLLA and PLLA-PCL block copolymers
   Kirchhecker, Sarah, Nguyen, Ngoc, Reichert, Stefan, Lützow, Karola, Eselem Bungu, Paul S., Jacobi von Wangelin, Axel, Sandl, Sebastian, Neffe, Axel T. · 2023 · RSC Advances
4. Heteroleptic Calcium Complexes Supported by a Phenoxy-Imine NON Ligand: Polymerization of Cyclic Esters by a Ligand-Assisted, Activated-Monomer Mechanism
   Rebecca L. Jones, Zoë R. Turner, Clement G. Collins Rice, Dermot M. O'Hare · 2024 · Organometallics
5. Advanced ionic liquid technologies for sustainable reaction intensification
   Pengzhi Bei, Jiayin Zhao, Xiaolu Gao, Yuning Qi, Peng Jia, Zehua Cheng, Lili Deng, Xingtang Xu, Zhenzhong Li · 2026 · RSC Sustainability
6. Synergistic Catalysis by Brønsted Acid/Carbodicarbene Mimicking Frustrated Lewis Pair‐Like Reactivity
   Yi‐Chen Chan, Yuna Bai, Wen‐Ching Chen, Hsing‐Yin Chen, Chenyu Li, Ying‐Yann Wu, Mei‐Chun Tseng, Glenn P. A. Yap, Lili Zhao, Hsuan‐Ying Chen et al. · 2021 · Angewandte Chemie
7. La[N( SiMe3 )2]3: A highly active catalyst for the ring‐opening polymerization of trimethylene carbonate
   Naoto Hirano, Hiroaki Yoshida, Tsuyoshi Ando, Hiroharu Ajiro · 2024 · Journal of Polymer Science
8. Sodium complexes as precise tools for cutting polymer chains. Exploration of PLA degradation by unique cooperation of sodium centers
   Edyta Nizioł, Dawid Jędrzkiewicz, Agata Wiencierz, Wojciech Paś, Danuta Trybuła, Wiktor Zierkiewicz, Aleksandra Marszałek-Harych, Jolanta Ejfler · 2022 · Inorganic Chemistry Frontiers
9. Synthesis and X‐ray Crystal Structures of Zinc Dichloride Complexes Supported by a β‐Diimine Ligand
   Christoph Scheiper, Dominik Naglav, Dieter Bläser, Christoph Wölper, Stephan Schulz · 2015 · Zeitschrift für anorganische und allgemeine Chemie
10. Synthesis, Structure, and Catalytic Behavior of Ytterbium Complexes Derived from a Linked Bis(β‐ketoiminato) Ligand
    Lingling Fan, Yaorong Wang, Yingming Yao, Bing Wu, Qi Shen · 2013 · Zeitschrift für anorganische und allgemeine Chemie
11. Zinc Complexes with Mono- and Polydentate Behaving Guanidine Ligands and Their Application in Lactide Polymerization
    Janna Börner, Ines dos Santos Vieira, Ülrich Flörke, Artjom Döring, Dirk Kuckling, Sonja Herres‐Pawlis · 2011 · ACS symposium series
12. Synthesis and Structural Characterisation of Dinuclear Aluminium Complexes Supported by NNO‐Tridentate Schiff‐Base Ligands and Their Catalysis in the Ring‐Opening Polymerisation of ϵ‐Caprolactone
    Xiaofeng Yu, Zhong‐Xia Wang, Zhi‐Yong Han · 2021 · ChemistrySelect
13. Metal Catalyzed Polymerization: From Stereoregular Poly(α‐olefins) to Tailor‐Made Biodegradable/Biorenewable Polymers and Copolymers
    Carmine Capacchione, Fabia Grisi, Marina Lamberti, Mina Mazzeo, Bárbara Milani, Stefano Milione, Daniela Pappalardo, Cristiano Zuccaccia, Claudio Pellecchia · 2023 · European Journal of Inorganic Chemistry
14. Facile green ring-opening polymerization of l -lactide catalyzed by natural kaoline
    Jie Gao, Feng Bao, Duo Wang, Rui Ma, Sanfeng Jiang, Xu Zhang, Yanjin Yao, Xiaobing Han, Chunjie Yan · 2015 · Polymer Chemistry
15. Organometal-catalyzed synthesis of high molecular weight poly-( l -lactic acid) with a covalently attached imidazolium salt: performance-enhanced reduced graphene oxide–PLLA biomaterials
    Yuri Clemente Andrade Sokolovicz, Clarissa M. L. Schrekker, Frédéric Hild, Leonardo de Oliveira Bodo, Júlia Lacerda Couto, Joice Sandra Klitzke, Thuany Garcia Maraschin, Nara Regina de Souza Basso, João Henrique Zimnoch dos Santos, Samuel Dagorne et al. · 2019 · New Journal of Chemistry
16. Amides as Non-polymerizable Catalytic Adjuncts Enable the Ring-Opening Polymerization of Lactide With Ferrous Acetate Under Mild Conditions
    Naolou, Toufik, Lendlein, Andreas, Neffe, Axel T. · 2019 · Frontiers in Chemistry
17. Lactide Polymerization Using Zinc Dichloride Complexes Containing a Neutral Bidentate Ligand with a Diacylated Cyclic Guanidine
    Brandon S. Khan, Víctor Flores-Romero, Jesse H. Leblanc, Gino G. Lavoie · 2022 · Organometallics
18. Aluminium complexes of phenoxy-azo ligands in the catalysis of rac -lactide polymerisation
    Pattarawut Sumrit, Sirawan Kamavichanurat, Wasan Joopor, Worawat Wattanathana, Chutikan Nakornkhet, Pimpa Hormnirun · 2024 · Dalton Transactions
19. Synthesis and structural characterisation of copper complexes containing methylthiophene and methylfuryl derivatives of (R,R)-1,2-diaminocyclohexane as precatalysts for polymerisation of rac-lactide
    Ji-Hye Ham, Juhyun Cho, Saira Nayab, Jong Hwa Jeong · 2018 · Inorganica Chimica Acta
20. Synthesis and characterization of β-diketiminato lanthanide amide complexes and their catalytic activity toward L-lactide polymerization
    Yong Zhang, Weiren Qiu, Yingming Yao · 2021 · Journal of Organometallic Chemistry
21. N3/4-pyridinyl Schiff base copper(II) benzoate complexes: synthesis, crystal structures and ring-opening polymerization studies
    Damilola C. Akintayo, Wisdom Archford Munzeiwa, Sreekantha Babu Jonnalagadda, Bernard O. Omondi · 2022 · Transition Metal Chemistry
22. ROP of Cyclic Carbonates and ROP of Macrocycles – Latest Developments
    Gabriel Rokicki, Paweł Grzegorz Parzuchowski · 2015 · Elsevier eBooks
23. Rapid one-pot catalytic synthesis of double-capped oligoesters from lactones
    Parichat Piromjitpong, Jiraya Kiriratnikom, Thasanaporn Ungpittagul, Sirilata Yotphan, Khamphee Phomphrai · 2017 · Applied Catalysis A General
24. Replacing sulfonate by carboxylate: application of pyridyliminocarboxylato copper(II) complexes in rac -lactide polymerization and Chan–Evans–Lam coupling
    Valérie Hardouin Duparc, Clémentine Dimeck, Frank Schaper · 2018 · Canadian Journal of Chemistry
25. Metal Phenolates as Polymerization Catalysts
    Jean‐François Carpentier, Evgeny Kirillov, Yann Sarazin · 2012 · Patai's chemistry of functional groups
26. New Trends in Organometallic Catalysts
    Kathrin Junge, Gerrit Wienhöfer, Matthias Beller, Anis Tlili, Gwilherm Evano, Marc Taillefer, Rhett Kempe, Christoph Malbertz, Jürgen Klankermayer · 2017 · Wiley eBooks
27. Titanium Alkoxide Complexes of Phenoxy-Azo and Phenoxy-Imine Ligands for Cyclic Ester (Co)Polymerization Studies: Tuning Polymerization Activity through Ligand Design
    Wasan Joopor, Worawat Wattanathana, Chawakorn Chansaenroch, Pimpa Hormnirun · 2025 · Inorganic Chemistry
28. The unexpected behaviour of epoxidised macromonomers derived from catalytic chain transfer during ring opening copolymerisation
    Gemma C. Sanders, Bas G. P. van Ravensteijn, Robbert Duchateau, Johan P. A. Heuts · 2012 · Polymer Chemistry
29. Stereoselective homo- and co-polymerization of lactides and ε-caprolactone catalysed by highly active racemic zinc(II) pyridyl complexes
    Wisdom Archford Munzeiwa, Vincent Onserio Nyamori, Bernard O. Omondi · 2022 · Transition Metal Chemistry
30. Alkaline and alkaline earth metals
    Michael S. Hill · 2011 · Annual Reports Section A (Inorganic Chemistry)
31. Branched phosphazenium salts as effective and versatile cocatalysts for epoxide/CO 2 coupling
    Massimiliano Brivio, Lorenzo Veronese, Incoronata Tritto, Paolo Biagini, Riccardo Pó, Laura Boggioni, Simona Losio · 2023 · Polymer Chemistry
32. Copolymerization of l-lactide and ε-caprolactone using aluminum aminobisphenolate as an initiator: a quantum chemical study
    M. V. Zabalov, Badma Nikolaevich Mankaev, Mikhail Petrovich Egorov, Sergey Sergeevich Karlov · 2023 · Russian Chemical Bulletin
33. Recent Advances in the Functionalized Poly(α-Hydroxy Acids) Synthesized fromO-Carboxyanhydrides
    Ziyu Huo, Xiaoyu Xie, Rong Tong · 2023 · ACS symposium series
34. Ring-Opening Polymerization of L-lactide Initiated by Samarium(III) Acetate
    Jesús Contreras, Dimas Medina, Francisco López‐Carrasquero, R. Contreras · 2018 · Current Applied Polymer Science
35. Alkaline and alkaline earth metals
    Michael S. Hill · 2013 · Annual Reports Section A (Inorganic Chemistry)
36. Dialkylgallium alkoxides – a tool for facile and stereoselective synthesis of PLA–drug conjugates
    Martyna Cybularczyk‐Cecotka, Rafał Zaremba, Aleksander Hurko, Andrzej Plichta, Maciej Dranka, Paweł Horeglad · 2017 · New Journal of Chemistry
37. Polymerization of Alkenes and Polar Monomers by Early Main Group Metal Complexes
    Sjoerd Harder · 2019
38. Phenoxybis(imine) complexes of vanadium: structure, ethylene polymerization, and ring opening polymerization of ε-caprolactone
    Yi Gong, Kaname Shibata, Kenji Michiue, Joseph Aondoaver Gbertyo, Zaid Rais, M.R.J. Elsegood, Timothy J. Prior, Carl Redshaw · 2025 · Dalton Transactions
39. Exploring the Catalytic Efficiency of Lithium Bis(trimethylsilyl)amide (LiHMDS) in Lactide Polymerization
    Almas Kiran, Chinedu Kingsley Achukee, Hassan Ahmed · 2025 · Polymers
40. Amino-triphenolate cerium (Ⅳ) complexes for high molecular weight PLLA synthesis and highly stereoselective ROP of rac-LA
    Jianxin Sun, Xin Zhao, Luya Cao, Hongzhang Cao, Ji Xian, Xiaobo Pan, Jincai Wu · 2025 · Polymer
41. Recyclable, Biobased Polycarbonates and Polyesters by Naphthoxy‐Imine Zinc and Magnesium Complexes
    Federica Tufano, Maria Vittoria Galotto, Alfredo D'Elia, Federica Santulli, Mina Mazzeo, Marina Lamberti · 2025 · Chemistry - A European Journal
42. Immortal polymerization of LA: the influence of steric effects, electronic effects and p K a on chain transfer agents
    Na Liu, Jince Zhang, Jingyi Wen, Xiaolei You, Dawei Fang · 2022 · Polymer Chemistry
43. Scalable and Room-Temperature Ring-Opening Polymerization of ε-Caprolactone Catalyzed by Active Lithium Tetramethylene-Tethered Bis[N-(N′-butylimidazol-2-ylidene)] N-Heterocyclic Carbene as a Lewis Acid Organocatalyst
    Natthapol Akkravijitkul, Nathaporn Cheechana, Puracheth Rithchumpon, Thiti Junpirom, Wanich Limwanich, Kanarat Nalampang, Praput Thavornyutikarn, Winita Punyodom, Puttinan Meepowpan · 2022 · The Journal of Organic Chemistry
44. A theoretical exploration of monomer activation mechanisms in bis-lithium Nheterocyclic carbenes complexes for enhanced understanding of charge distribution in ring-opening polymerization of ε-caprolactone
    Nathaporn Cheechana, Natthapol Akkravijitkul, Nopawit Khamto, Wanwanut Chueasupcharoen, Wanich Limwanich, Winita Punyodom, Puttinan Meepowpan · 2024 · Journal of Molecular Structure
45. Zinc, cadmium and mercury
    Martyn P. Coles · 2011 · Annual Reports Section A (Inorganic Chemistry)
46. Ring-opening copolymerization of epoxide and dianhydride in the presence of manganese(III) asymmetrical bis-Schiff base catalysts
    Deng-Feng Liu, Luqun Zhu, Jing Wu, Liying Wu, Xingqiang Lü · 2014 · Canadian Journal of Chemistry
47. Evaluación de la actividad de complejos de samario(III) con ácido L-aspártico, ácido L-glutámico, glicina y o-fenantrolina, como iniciadores en la polimerizacion de carbonatos cíclicos
    Meribary Margarita Monsalve, Jesús Contreras, Eduardo Cardozo, R. Contreras · 2016 · Avances en Química
48. Combining Sustainable Polymerization Routes for the Preparation of Polyesters, Polycarbonates, and Copolymers
    Charles Romain, Charlotte K. Williams · 2015 · ACS symposium series
49. Aluminium complexes containing indolyl-phenolate ligands as catalysts for ring-opening polymerization of cyclic esters
    Chi‐Tien Chen, Zi-Ling Lai · 2022 · RSC Advances
50. Rare earth-based auxiliary agents in synthesis and functionalization of biodegradable polymers: Application and prospect
    Yuxuan Qi, Jia Niu, Huhu Tian, Tingting Lu, Hongzhang Cao, Yanlin Feng, Xiaoli Yu · 2025 · Journal of Rare Earths
51. D‐Optimal Design for Enzymatic Ring‐Opening Polymerization of ε‐Caprolactone: Toward Sustainable Polyester Synthesis Using Biobased Solvents
    Emily G. Dixon, Emily Chau, Luisa Ciano, Anca Pordea, Karen E. Alvey, Vincenzo Taresco · 2025 · Journal of Polymer Science
52. A Supported Catalyst that Enables the Synthesis of Colorless CO 2 ‐Polyols with Ultra‐Low Molecular Weight
    Qingxian Kuang, Ruoyu Zhang, Zhenzhen Zhou, Can Liao, Shunjie Liu, Xuesi Chen, Xianhong Wang · 2023 · Angewandte Chemie
53. Development of a H-bond donor–Lewis basic anion bifunctional organocatalyst for ring-opening polymerizations
    Bo Liu, Peng Kang, Zhenjiang Li, Na Shi, Xin Qi, Ziqi Liu, Tao Cai, Jun He, Chunyu Li, Kai Guo · 2024 · Polymer Chemistry
54. Tunable zinc benzamidinate complexes: coordination modes and catalytic activity in the ring-opening polymerization of l -lactide
    Chen-Chieh Chang, Ming‐Tsz Chen, Tzu-Lun Huang, Chi‐Tien Chen · 2024 · Dalton Transactions
55. Tetradentate iminophenolate copper complexes in rac-lactide polymerization
    Pargol Daneshmand, Aurélie Randimbiarisolo, Frank Schaper · 2018 · Canadian Journal of Chemistry
56. Investigation of ring‐opening polymerization of 5‐[2‐{2‐(2‐methoxyethoxy)ethoxy}‐ethoxymethyl]‐5‐methyl‐1,3‐dioxa‐2‐one by organometallic catalysts
    Nalinthip Chanthaset, Klaus Beckerle, Jun Okuda, Hiroharu Ajiro · 2020 · Journal of Applied Polymer Science
57. Aluminum: Organometallic Chemistry
    Mark R. Mason · 2016 · Wiley eBooks
58. Yttrium-mediated ring-opening polymerization of functionalizable dihydrocarvide: tunable terpene-based polyesters using grafting from and block copolymerization strategies
    Lea-Sophie Hornberger, Julian Fischer, Alexandra Friedly, Ingo Hartenbach, Thomas Sottmann, Friederike Adams · 2025 · Polymer Chemistry
59. Diversity in Zwitterionic Metal Ammonium Tris(phenolate)s for the Controlled Immortal Polymerization of Lactide: Dramatic Activity Enhancement and Mechanistic Insight on Expansion beyond Zirconium
    Matthew G. Davidson, Catherine J. Frankis, Matthew D. Jones, Gabriele I. Kociok-Köhn, Frank Marken, Strachan N. McCormick, James Tipler, Philip B. Yang · 2025 · ACS Catalysis
60. New aluminum complexes based on S,N,S-type Aminobisthiophenol Ligands for ring-opening polymerization of lactide and ε-caprolactone
    Valeriia A. Serova, Artem V. Lykov, Badma Nikolaevich Mankaev, Milana U. Agaeva, Konstantin Alexandrovich Lyssenko, Elena Vyacheslavna Chernikova, Mikhail Petrovich Egorov, Sergey Sergeevich Karlov · 2025 · Journal of Organometallic Chemistry
61. Synthetic memory: a key link between biocatalytically synthesized polyesters and melt electrowriting performance
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62. [(Salen*)Co(OAc)] as a robust initiator for the immortal bulk ring-opening (co)polymerization of l -lactide and ε-caprolactone
    Maxime Michelas, Gabrielle Duffaut, Rinaldo Poli, Christophe Fliedel · 2025 · Catalysis Science & Technology
63. Synthesis of the Poly(ε‐Caprolactone‐b‐Methyl Methacrylate‐b‐ε‐Caprolactone) ABA Type Block Copolymer by Reverse Atom Transfer Radical Polymerization and “Click” Chemistry
    Nilgün Asan, Temel Öztürk, Bakı Hazer · 2026 · ChemistrySelect
64. Potassium complexes of the acids Ph2C(X)CO2H (X = OH, NH2): ring opening polymerization of ε-caprolactone and δ-valerolactone
    Qi Sun, Yahya Al‐Khafaji, Mohammed Aljohani, Thamer A. A. M. Alalwani, Richard Grindell, Timothy J. Prior, Carl Redshaw · 2026 · Inorganica Chimica Acta
65. Silica-Supported Zinc(II)–Schiff-Base Catalysts for Lactide Ring-Opening Polymerization: Influence of Support Morphology and Ligand Substituents
    Darío M. González, Felipe Picero, Ornella Realini Fuentes, Jocelyn Oyarce, Enrique Blázquez‐Blázquez · 2026 · Polymers
66. 1,10-Phenanthroline complexes of zinc as highly active biocompatible catalysts in cyclic oxalates polymerization displaying unique regioselectivity
    Nikolai Petrovich Iakimov, Badma Nikolaevich Mankaev, Evgenii Olegovich Fomin, Ekaterina Mikhailovna Budynina, Marina V. Serebryakova, Irina Dmitrievna Grozdova, Sergey Sergeevich Karlov, N. S. Melik‐Nubarov · 2026 · European Polymer Journal
67. Tridentate [ONN] Iminophenolate Aluminum Complexes for Controlled Ring-Opening (Co)Polymerization of rac -Lactide, ε-Caprolactone, and δ-Valerolactone: Impact of Pendant Diamine Donor Arms and Ligand Substituents on Catalytic Performance
    Kunanon Jampakaew, Wasan Joopor, Pimpa Hormnirun · 2026 · Macromolecules
68. Enzymatically Synthesized Polyesters for Drug Delivery
    Shengfan Lu, Jianxun Ding, Jinjin Chen, Wei Wang, Xiuli Zhuang, Xuesi Chen · 2016 · Pan Stanford eBooks
69. Synthesis of N,N ‐Dimethylaminoethyl Acrylate via a Zinc Phenoxyimine and Phenoxyamidine Complexes Catalyzed Transesterification Reaction
    Quentin Gaydon, Raluca Malacea‐Kabbara, Jérôme Bayardon, Laurent Plasseraud, Michel Picquet, Pierre Le Gendre, Benoît Legras, Johann Kieffer · 2025 · Applied Organometallic Chemistry
70. HNTs/GO composite as efficient catalyst for ring-opening polymerization of ε-Caprolactone
    Rui Ma, Pan Hu, Jinxu Fan, Wei Tang, Tao Chen, Luyao Shi · 2018 · Polymer-Plastics Technology and Materials
71. Stereoselective Ring‐Opening Polymerization of Heterocyclic Monomers
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73. Immobilized Ionic Liquids on Fe3o4 Nanoparticles: A Potential Catalyst for Organic Synthesis
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74. Development of H-Bond Donor–Lewis Basic Anion Bifunctional Organocatalyst for Ring-Opening Polymerizations
    Bo Liu, Peng Kang, Zhenjiang Li, Na Shi, Xin Qi, Ziqi Liu, Tao Cai, Jun He, Chunyu Li, Kai Guo · 2024 · SSRN Electronic Journal
75. Secondary (Agostic Si–H/Electrostatic C–F) Interactions in Alkaline Earth-based Catalysts
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76. Main Group Complexes in Polymer Synthesis
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79. Bidentate and tridentate coordination modes of bis(3-methylindolyl)-2-(1-methylimidazolyl)methane in complexes of aluminum and gallium
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80. The synthesis of benzyl alcohol: process optimization, photo-illuminated liquid phase hydrogenation, the improved green catalysts from natural zeolite
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81. 16.5. Polymerization of ε-Caprolactone Using a Ruthenium( ii ) Mixed Metallocene Catalyst
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82. Contrasting a series of bidentate amido phosphine oxide, sulfide, or selenide ligands and complexes of dimethyl aluminum and indium
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83. Amino-Triphenolate Cerium (IV) Complexes for High Molecular Weight Plla Synthesis and Highly Stereoselective Rop of Rac-La
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84. Influence of the Substitution Pattern of Terpene‐Based Seven‐Membered Lactones on Yttrium‐Mediated Ring‐Opening Polymerization: A Kinetic and Mechanistic Investigation
    Lea-Sophie Hornberger, Svenja Hiotidis, Shailja Jain, Michael Benz, Hugo Montan, Deven P. Estes, Johannes Kästner, Friederike Adams · 2025 · Chemistry - A European Journal
85. New poly(hydroxyalkanoate)-based copolymers : from synthesis to tunable self-assembled systems
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86. Les acides gras comme source de matériaux polycarbonates aliphatiques originaux
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87. Synthèse de morpholine-2,5-diones et de (co)polydepsipeptides pour la valorisation d'acides aminés
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88. Alkaline-earth metals : coordination chemistry and catalytic applications
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89. Synthesis of functionalized lactones by thiol-ene reaction and their application to the preparation of tunable biodegradable polymers
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90. Green polymerizations in microflow devices
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91. Molecular coordination chemistry of barium andrelated elements : structure, reactivity and catalysis
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92. Surface initiated organocatalyzed ring-opening polymerization as a tool for grafting polymers on nanocelluloses
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93. Metal–Ligand Interplay Governs the Coordination Flexibility and Catalytic Performance of Ca (II) , Mg (II) , and Zn (II) Complexes Supported by Benzamidinate‐Oxazolinate Type Ligands
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94. Synthesis, Characterization, and Reactivity of “NONO” Calix[4]arene Zirconium Complexes
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