Cited by 494biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisAdvanced Polymer Synthesis and Characterization

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Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates

Ajellal, Noureddine, Carpentier, Jean-François, Guillaume, Clémence, Guillaume, Sophie M., Helou, Marion, Poirier, Valentin, Sarazin, Yann, Trifonov, Alexander·2010·Dalton Transactions

DOI 10.1039/c001226b

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Abstract

This Perspective article summarizes efforts paid in our group to develop efficient metal-based catalysts for the immortal ring-opening polymerization (iROP) of cyclic esters in the presence of large amounts of alcohols (ROH) as chain transfer agents. The catalyst systems reviewed include discrete organometallic complexes based on rare earths, magnesium, calcium and more specifically zinc, as well as simple systems employing metal triflate salts, notably Al(OTf)(3), for the (stereo)controlled iROP of lactide (LA), beta-butyrolactone (BBL) and trimethylenecarbonate (TMC). Special emphasis is given to systems that allow the use of minute amounts of metal catalysts and large loadings of both monomer and alcohol for the rapid and productive formation of functional polyesters (H-Pol-OR) with controlled molecular features.

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Authors: Ajellal, N., Carpentier, J.-F., Guillaume, C., Guillaume, S. M., Helou, M., Poirier, V., Sarazin, Y., & Trifonov, A.
Affiliations: Centre National de la Recherche Scientifique (FR)
Russian Academy of Sciences (RU)
Corresponding author: Carpentier, Jean-François
Guillaume, Sophie M.
ORCID: Carpentier, Jean-François
Guillaume, Sophie M.
Poirier, Valentin
Sarazin, Yann
Trifonov, Alexander
Venue: Dalton Transactions
Publisher: Royal Society of Chemistry (RSC)
Published: 2010
Volume: 39
Issue: 36
Pages: 8363
ISSN: 1477-9226 (ISSN-L)
1477-9234
DOI: 10.1039/c001226b
OpenAlex: W2009027332
Cited by: 494
References: 101
Citations by year: 2026: 8 · 2025: 15 · 2024: 15 · 2023: 22 · 2022: 24 · 2021: 17 · 2020: 23 · 2019: 26 · 2018: 37 · 2017: 48 · 2016: 39 · 2015: 52 · 2014: 36 · 2013: 55 · 2012: 41
FWCI: 17.31
Type: journal article
Language: en
Open access: closed
Locations: Dalton Transactions (publishedVersion)
PubMed (publishedVersion)
HAL (submittedVersion)
Topics: Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Keywords: metal-catalyzed polymerization, cyclic esters, lactones, lactide, β-butyrolactone, cyclic carbonates, chain transfer agent, rare earth complexes, zinc catalyst, magnesium catalyst, calcium catalyst, aluminum triflate, functional polyesters, molecular weight control
MeSH terms: Alcohols, Carbonates, Catalysis, Dioxanes, Metals, Organometallic Compounds, 4-Butyrolactone, Coordination Complexes, Polymerization

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Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates

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