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Enhancement of Pt and Pt-alloy fuel cell catalyst activity and durability via nitrogen-modified carbon supports

Zhou, Yingke, Neyerlin, Kenneth, Olson, Tim S., Pylypenko, Svitlana, Bult, Justin, Dinh, Huyen N., Gennett, Thomas, Shao, Zongping, O'Hayre, Ryan·2010·Energy & Environmental Science

Abstract

Insufficient catalytic activity and durability are key barriers to the commercial deployment of low temperature polymer electrolyte membrane (PEM) and direct-methanol fuel cells (DMFCs). Recent observations suggest that carbon-based catalyst support materials can be systematically doped with nitrogen to create strong, beneficial catalyst-support interactions which substantially enhance catalyst activity and stability. Data suggest that nitrogen functional groups introduced into a carbon support appear to influence at least three aspects of the catalyst/support system: 1) modified nucleation and growth kinetics during catalyst nanoparticle deposition, which results in smaller catalyst particle size and increased catalyst particle dispersion, 2) increased support/catalyst chemical binding (or “tethering”), which results in enhanced durability, and 3) catalyst nanoparticle electronic structure modification, which enhances intrinsic catalytic activity. This review highlights recent studies that provide broad-based evidence for these nitrogen-modification effects as well as insights into the underlying fundamental mechanisms.

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Metadata

Authors
Zhou, Y., Neyerlin, K., Olson, T. S., Pylypenko, S., Bult, J., Dinh, H. N., Gennett, T., Shao, Z., & O'Hayre, R.
Venue
Energy & Environmental Science
Published
2010
Volume
3
Issue
10
Pages
1437
ISSN
  • 1754-5692 (ISSN-L)
  • 1754-5706
OpenAlex
W2170774098
Cited by
644
References
6
FWCI
28.41
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Enhancement of Pt and Pt-alloy fuel cell catalyst activity and durability via nitrogen-modified carbon supports. https://app.cochat.ai/papers/10.1039/c003710a
The paper
Zhou, Y., Neyerlin, K., Olson, T. S., Pylypenko, S., Bult, J., Dinh, H. N., Gennett, T., Shao, Z., & O'Hayre, R. (2010). Enhancement of Pt and Pt-alloy fuel cell catalyst activity and durability via nitrogen-modified carbon supports. Energy & Environmental Science. https://doi.org/10.1039/c003710a

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.