Glycosylation initiated cationic ring-opening polymerization of tetrahydrofuran to prepare neo-glycopolymers
Abstract
An unprecedented and highly efficient glycosylation initiated cationic ring-opening polymerization (CROP) of tetrahydrofuran is disclosed employing glycosyl ortho-hexynylbenzoates as donors and gold(I) as a catalyst, that provides an easy access to novel glycopolymers which could self-assemble into nanostructures.
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Glycosyl ortho-alkynyl benzoates and a gold triflate salt (PPh3AuNTf2) can be used to prepare poly-THF with glycosyl terminal groups.
“A variation on this type of initiation is reported by Li and Yu [55] who have reported the use of glycosyl ortho-alkynyl benzoates and a gold triflate salt (PPh3AuNTf2) to prepare poly-THF with glycosyl terminal groups.”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [55]
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Ring-Opening Polymerization—An Introductory Review
Nuyken, O., & Pask, S. (2013) · Polymers · doi:10.3390/polym5020361 · Cited by 456 · see citing works
- Authors
- Li, Y., & Yu, B.
- Affiliations
- Chinese Academy of Sciences (CN)
- Corresponding author
- Yu, Biao
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 46
- Issue
- 33
- Pages
- 6060
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2065067166
- Cited by
- 40
- References
- 30
- Citations by year
- 2026: 3 · 2025: 2 · 2022: 1 · 2021: 2 · 2020: 1 · 2019: 2 · 2018: 3 · 2017: 1 · 2016: 1 · 2015: 5 · 2014: 1 · 2013: 3 · 2012: 7
- FWCI
- 2.85
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Communications (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Carbohydrate Chemistry and Synthesis
- Keywords
- cationic ring-opening polymerization, tetrahydrofuran, glycosylation, glycopolymers, gold(I) catalysts, self-assembly, nanostructures, glycosyl donors
- MeSH terms
- Butylene Glycols, Catalysis, Furans, Glycosylation, Gold, Oligosaccharides, Polymers, Molecular Structure, Nanostructures
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