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Reaction of elemental chalcogens with imidazolium acetates to yield imidazole-2-chalcogenones: direct evidence for ionic liquids as proto-carbenes
Abstract
Mechanistic analysis of the reaction between elemental sulfur or selenium and 1,3-dialkylimidazolium acetate ionic liquids, in the absence of an external base or solvent, affords evidence for the equilibrium presence of carbene species in these ionic liquids. It demonstrates the potential to control, through anion selection, the concentration of carbene in stable ionic liquids.
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Cited by
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Bui, M., Adjiman, C. S., Bardow, A., Anthony, E. J., Boston, A., Brown, S., Fennell, P. S., Fuss, S., Galindo, A., Hackett, L. A., et al. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02342a · Cited by 4,374
Ionic liquid processing of cellulose
Wang, H., Gurau, G., & Rogers, R. D. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15311d · Cited by 1,369
Self-citationHydrogen bonding in ionic liquids
Hunt, P. A., Ashworth, C. R., & Matthews, R. P. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00278d · Cited by 836
Are Ionic Liquids Chemically Stable?
Wang, B., Qin, L., Mu, T., Xue, Z., & Gao, G. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00594 · Cited by 665
Active chemisorption sites in functionalized ionic liquids for carbon capture
Cui, G., Wang, J., & Zhang, S. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00462d · Cited by 498
Metadata
- Authors
- Rodríguez, H., Gurau, G., Holbrey, J. D., & Rogers, R. D.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 47
- Issue
- 11
- Pages
- 3222
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2074132708
- Cited by
- 195
- References
- 0
- FWCI
- 8.74
- Type
- journal article
- Language
- en
- Open access
- closed
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- Rodríguez, H., Gurau, G., Holbrey, J. D., & Rogers, R. D. (2011). Reaction of elemental chalcogens with imidazolium acetates to yield imidazole-2-chalcogenones: direct evidence for ionic liquids as proto-carbenes. Chemical Communications. https://doi.org/10.1039/c0cc05223j
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