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Cited by 195

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Reaction of elemental chalcogens with imidazolium acetates to yield imidazole-2-chalcogenones: direct evidence for ionic liquids as proto-carbenes

Rodríguez, Héctor, Gurau, Gabriela, Holbrey, John D., Rogers, Robin D.·2011·Chemical Communications

Abstract

Mechanistic analysis of the reaction between elemental sulfur or selenium and 1,3-dialkylimidazolium acetate ionic liquids, in the absence of an external base or solvent, affords evidence for the equilibrium presence of carbene species in these ionic liquids. It demonstrates the potential to control, through anion selection, the concentration of carbene in stable ionic liquids.

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Metadata

Authors
Rodríguez, H., Gurau, G., Holbrey, J. D., & Rogers, R. D.
Venue
Chemical Communications
Published
2011
Volume
47
Issue
11
Pages
3222
ISSN
  • 1359-7345 (ISSN-L)
  • 1364-548X
OpenAlex
W2074132708
Cited by
195
References
0
FWCI
8.74
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Reaction of elemental chalcogens with imidazolium acetates to yield imidazole-2-chalcogenones: direct evidence for ionic liquids as proto-carbenes. https://app.cochat.ai/papers/10.1039/c0cc05223j
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Rodríguez, H., Gurau, G., Holbrey, J. D., & Rogers, R. D. (2011). Reaction of elemental chalcogens with imidazolium acetates to yield imidazole-2-chalcogenones: direct evidence for ionic liquids as proto-carbenes. Chemical Communications. https://doi.org/10.1039/c0cc05223j

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