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Cited by 507

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High efficiency nanocomposite sorbents for CO2 capture based on amine-functionalized mesoporous capsules

Open access
Qi, Genggeng, Wang, Yanbing, Estevez, Luis, Duan, Xiaonan, Anako, Nkechi, Park, Ah-Hyung Alissa, Li, Wen, Jones, Christopher W., Giannelis, Emmanuel P.·2011·Energy Environ. Sci.

Abstract

A novel high efficiency nanocomposite sorbent for CO2 capture has been developed based on oligomeric amine (polyethylenimine, PEI, and tetraethylenepentamine, TEPA) functionalized mesoporous silica capsules. The newly synthesized sorbents exhibit extraordinary capture capacity up to 7.9 mmol g−1 under simulated flue gas conditions (pre-humidified 10% CO2). The CO2 capture kinetics were found to be fast and reached 90% of the total capacities within the first few minutes. The effects of the mesoporous capsule features such as particle size and shell thickness on CO2 capture capacity were investigated. Larger particle size, higher interior void volume and thinner mesoporous shell thickness all improved the CO2 capacity of the sorbents. PEI impregnated sorbents showed good reversibility and stability during cyclic adsorption–regeneration tests (50 cycles).

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Crossref · 10.1039/c0ee00213e

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Metadata

Authors
Qi, G., Wang, Y., Estevez, L., Duan, X., Anako, N., Park, A.-H. A., Li, W., Jones, C. W., & Giannelis, E. P.
Venue
Energy Environ. Sci.
Published
2011
Volume
4
Issue
2
Pages
444-452
ISSN
  • 1754-5692 (ISSN-L)
  • 1754-5706
OpenAlex
W1991079121
Cited by
507
References
1
FWCI
51.72
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: High efficiency nanocomposite sorbents for CO2 capture based on amine-functionalized mesoporous capsules. https://app.cochat.ai/papers/10.1039/c0ee00213e
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Qi, G., Wang, Y., Estevez, L., Duan, X., Anako, N., Park, A.-H. A., Li, W., Jones, C. W., & Giannelis, E. P. (2011). High efficiency nanocomposite sorbents for CO2 capture based on amine-functionalized mesoporous capsules. Energy Environ. Sci. https://doi.org/10.1039/c0ee00213e

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