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Cited by 180

The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.

Synthesis of urea derivatives from amines and CO2 in the absence of catalyst and solvent

Wu, Chaoyong, Cheng, Haiyang, Liu, Ruixia, Wang, Qiang, Hao, Yufen, Yu, Yancun, Zhao, Fengyu·2010·Green Chemistry

Abstract

Urea derivatives are obtained in mild to good yield from the reactions of primary aliphatic amines with CO2 in the absence of any catalysts, organic solvents or other additives. To optimize reaction conditions, experimental variables including temperature, pressure, the concentration of amine, reaction time etc. were studied. Satisfactory yields were obtained at the optimized conditions that are comparable to the presence of catalyst and solvent. The preliminary investigation of the reaction mechanism showed that alkyl ammonium alkyl carbamate was quickly formed as the intermediate, and then the final product was formed by the intramolecular dehydration.

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Metadata

Authors
Wu, C., Cheng, H., Liu, R., Wang, Q., Hao, Y., Yu, Y., & Zhao, F.
Venue
Green Chemistry
Published
2010
Volume
12
Issue
10
Pages
1811
ISSN
  • 1463-9262 (ISSN-L)
  • 1463-9270
OpenAlex
W2110184908
Cited by
180
References
2
FWCI
6.53
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Synthesis of urea derivatives from amines and CO2 in the absence of catalyst and solvent. https://app.cochat.ai/papers/10.1039/c0gc00059k
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Wu, C., Cheng, H., Liu, R., Wang, Q., Hao, Y., Yu, Y., & Zhao, F. (2010). Synthesis of urea derivatives from amines and CO2 in the absence of catalyst and solvent. Green Chemistry. https://doi.org/10.1039/c0gc00059k

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.