The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Synthesis of urea derivatives from amines and CO2 in the absence of catalyst and solvent
Abstract
Urea derivatives are obtained in mild to good yield from the reactions of primary aliphatic amines with CO2 in the absence of any catalysts, organic solvents or other additives. To optimize reaction conditions, experimental variables including temperature, pressure, the concentration of amine, reaction time etc. were studied. Satisfactory yields were obtained at the optimized conditions that are comparable to the presence of catalyst and solvent. The preliminary investigation of the reaction mechanism showed that alkyl ammonium alkyl carbamate was quickly formed as the intermediate, and then the final product was formed by the intramolecular dehydration.
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Citations
Cites
Carbon capture and storage: how green can black be
Haszeldine, R. S. (2009) · Science · doi:10.1126/science.1172246 · Cited by 2,021
The synthesis of organic carbonates from carbon dioxide
Sakakura, T., & Kohno, K. (2009) · Chemical Communications · doi:10.1039/b819997c · Cited by 1,067
Cited by
Closing the loop: captured CO 2 as a feedstock in the chemical industry
Otto, A., Grube, T., Schiebahn, S., & Stolten, D. (2015) · Energy & Environmental Science · doi:10.1039/c5ee02591e · Cited by 482
CO2-Induced Degradation of Amine-Containing Adsorbents: Reaction Products and Pathways
Sayari, A., Heydari-Gorji, A., & Yang, Y. (2012) · Journal of the American Chemical Society · doi:10.1021/ja304888a · Cited by 365
Carbon capture and utilization technologies: a literature review and recent advances
Baena-Moreno, F. M., Rodríguez-Galán, M., Vega, F., Alonso-Fariñas, B., Vilches Arenas, L. F., & Navarrete, B. (2019) · Energy Sources, Part A: Recovery, Utilization, and Environmental Effects · doi:10.1080/15567036.2018.1548518 · Cited by 351
Green catalytic process for cyclic carbonate synthesis from carbon dioxide under mild conditions
Lang, X.-D., & He, L.-N. (2016) · The Chemical Record · doi:10.1002/tcr.201500293 · Cited by 122
Metadata
- Authors
- Wu, C., Cheng, H., Liu, R., Wang, Q., Hao, Y., Yu, Y., & Zhao, F.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 12
- Issue
- 10
- Pages
- 1811
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2110184908
- Cited by
- 180
- References
- 2
- FWCI
- 6.53
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wu, C., Cheng, H., Liu, R., Wang, Q., Hao, Y., Yu, Y., & Zhao, F. (2010). Synthesis of urea derivatives from amines and CO2 in the absence of catalyst and solvent. Green Chemistry. https://doi.org/10.1039/c0gc00059k
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.