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Multifunctional ligands in transition metal catalysis
Abstract
Sophisticated ligands are now being designed that do far more than just fulfil their traditional spectator roles by binding to the metal and providing a sterically-defined binding pocket for the substrate in homogeneous transition metal catalysis. This Focus review emphasizes selected cases in which ligands carry additional functional groups that change the properties of the ligand as a result of an external stimulus or undergo catalytically-relevant ligand-based reactivity. These include proton responsive ligands capable of gaining or losing one or more protons, ligands having a hydrogen bonding function, electroresponsive ligands capable of gaining or losing one or more electrons, and photoresponsive ligands capable of undergoing a useful change of properties upon irradiation. Molecular recognition ligands and proton coupled electron transfer (PCET) are briefly discussed.
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Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Schmeier, T. J., Dobereiner, G. E., Crabtree, R. H., & Hazari, N. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2035514 · Cited by 438
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Metadata
- Authors
- Crabtree, R. H.
- Venue
- New J. Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 35
- Issue
- 1
- Pages
- 18-23
- ISSN
- 0398-9836 (ISSN-L)
- 1144-0546
- 1369-9261
- OpenAlex
- W2045316549
- Cited by
- 259
- References
- 0
- FWCI
- 7.74
- Type
- journal article
- Language
- en
- Open access
- closed
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