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Infrared study of the influence of reducible iron(iii) metal sites on the adsorption of CO, CO2, propane, propene and propyne in the mesoporous metal–organic framework MIL-100
Abstract
The present study illustrates the importance of the oxidation state of iron within the mesoporous iron trimesate [{Fe(3)O(H(2)O)(2)F(0.81)(OH)(0.19)}{C(6)H(3)(CO(2))(3)}(2)] denoted MIL-100(Fe) (MIL= Material from Institut Lavoisier) during adsorption of molecules that can interact with the accessible metal sites through π-back donation. Adsorption of CO has been first followed by FTIR spectroscopy to quantify the Lewis acid sites in the dehydrated Fe(III) sample, outgassed at 150 °C, and on the partially reduced Fe(II/III), outgassed at 250 °C. The exposure of MIL-100(Fe) to CO(2), propane, propene and propyne has then been studied by FTIR spectroscopy and microcalorimetry. It appears that π-back donating molecules are strongly adsorbed on reduced iron(II) sites despite the weaker Lewis acidity of cus Fe(2+) sites compared to that of Fe(3+) ones, as shown by pyridine adsorption.
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Cites
BioMOFs: Metal–Organic Frameworks for Biological and Medical Applications
McKinlay, A. C., Morris, R. E., Horcajada, P., Férey, G., Gref, R., Couvreur, P., & Serre, C. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000048 · Cited by 1,256
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Cited by
Li, B., Zhang, Y., Krishna, R., Yao, K., Han, Y., Wu, Z., Ma, D., Shi, Z., Pham, T., Space, B., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja502119z · Cited by 455
Wang, Y., Peh, S. B., & Zhao, D. (2019) · Small · doi:10.1002/smll.201900058 · Cited by 342
Influence of framework metal ions on the dye capture behavior of MIL-100 (Fe, Cr) MOF type solids
Tong, M., Liu, D., Yang, Q., Devautour-Vinot, S., Maurin, G., & Zhong, C. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta11807j · Cited by 320
Nitric Oxide Adsorption and Delivery in Flexible MIL-88(Fe) Metal–Organic Frameworks
McKinlay, A. C., Eubank, J. F., Wuttke, S., Xiao, B., Wheatley, P. S., Bazin, P., Lavalley, J.-C., Daturi, M., Vimont, A., De Weireld, G., et al. (2013) · Chemistry of Materials · doi:10.1021/cm304037x · Cited by 294
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Metadata
- Authors
- Leclerc, H., Vimont, A., Lavalley, J.-C., Daturi, M., Wiersum, A. D., Llwellyn, P. L., Horcajada, P., Férey, G., & Serre, C.
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 13
- Issue
- 24
- Pages
- 11748
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2074129088
- Cited by
- 259
- References
- 1
- FWCI
- 9.07
- Type
- journal article
- Language
- en
- Open access
- closed
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- Leclerc, H., Vimont, A., Lavalley, J.-C., Daturi, M., Wiersum, A. D., Llwellyn, P. L., Horcajada, P., Férey, G., & Serre, C. (2011). Infrared study of the influence of reducible iron(iii) metal sites on the adsorption of CO, CO2, propane, propene and propyne in the mesoporous metal–organic framework MIL-100. Physical Chemistry Chemical Physics. https://doi.org/10.1039/c1cp20502a
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