The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Application of quantitative 31P NMR in biomass lignin and biofuel precursors characterization
Abstract
The last decade has seen tremendous growth and interest in renewable energy and fuels aimed primarily at addressing issues of climate change, energy security, and rising energy costs. These efforts coupled with the demand for efficient utilization of biomass place a premium on the detailed analysis of the fundamental chemical structures of biomass, especially in light of the ever-increasing efforts to generate transgenic plants with reduced recalcitrance and altered lignin structure. This review examines the growing application of phosphitylation followed by 31P NMR to quantitatively analyze biomass lignin structures including guaiacyl, syringyl, guaiacyl with carbon substituents at the C5 position, catechol, p–hydroxyphenyl, aliphatic and carboxylic hydroxyl groups. The application of this methodology to provide a rapid analytical tool for lignin/biomass derived bio-oils and biodiesel precursors is also discussed. Utilizing lignin isolated from native and transgenic plants as well as from pretreatment and biological/thermal deconstruction processes, researchers have demonstrated that this technique has unique characterization capabilities which have broad applicability in the biofuels research community.
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Cites
Features of promising technologies for pretreatment of lignocellulosic biomass
MOSIER, N. (2005) · Bioresource Technology · doi:10.1016/j.biortech.2004.06.025 · Cited by 6,251
Pretreatment: the key to unlocking low‐cost cellulosic ethanol
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Sustainable Development of the Agricultural Bio-Economy
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From wood to fuels: Integrating biofuels and pulp production
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Self-citationChemical structure of residual lignin from kraft pulp
Froass, P. M., Ragauskas, A. J., & Jiang, J.-E. (1996) · Journal of Wood Chemistry and Technology · doi:10.1080/02773819608545820 · Cited by 129
Self-citation
Cited by
Sturgeon, M. R., Kim, S., Lawrence, K., Paton, R. S., Chmely, S. C., Nimlos, M., Foust, T. D., & Beckham, G. T. (2014) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc400384w · Cited by 414
Yuan, Y., Jiang, B., Chen, H., Wu, W., Wu, S., Jin, Y., & Xiao, H. (2021) · Biotechnology for Biofuels · doi:10.1186/s13068-021-02054-1 · Cited by 344
Zhu, J., Yan, C., Zhang, X., Yang, C., Jiang, M., & Zhang, X. (2020) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2019.100788 · Cited by 303
Advances in lignin valorization towards bio-based chemicals and fuels: lignin biorefinery
Cao, Y., Chen, S. S., Zhang, S., Ok, Y. S., Matsagar, B. M., Wu, K. C.-W., & Tsang, D. C. W. (2019) · Bioresource Technology · doi:10.1016/j.biortech.2019.121878 · Cited by 267
Structural elucidation of whole lignin from Eucalyptus based on preswelling and enzymatic hydrolysis
Wen, J.-L., Sun, S.-L., Yuan, T.-Q., & Sun, R.-C. (2015) · Green Chemistry · doi:10.1039/c4gc01889c · Cited by 207
Metadata
- Authors
- Pu, Y., Cao, S., & Ragauskas, A. J.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 4
- Issue
- 9
- Pages
- 3154
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2155878184
- Cited by
- 543
- References
- 6
- FWCI
- 6.20
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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