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High “C” rate Li-S cathodes: sulfur imbibed bimodal porous carbons
Abstract
A highly ordered mesoporous carbon with a bimodal pore structure which exhibits a high specific area and large pore volume, was synthesized by a triblock-copolymer-templating approach. This optimized framework served as the scaffold for the preparation of carbon/sulfur (C/S) nanocomposites that serve as novel cathodes for Li-S batteries. They exhibit high discharge capacities and good cycling stability at very high current rates of 1675 mA g−1 (1 C), which can be attributed to the unique bimodal porous structure of the carbon. The small mesopores contain the majority of the sulfur mass and aid in suppressing the diffusion of polysulfide species into the electrolyte, whilst the large interconnected cylindrical pores favour rapid transport of solvated Li+ on charge/discharge. Additional doping with hydrophilic nanoporous silica also aids in capacity retention on cycling.
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Cites
Adsorption of Gases in Multimolecular Layers
Brunauer, S., Emmett, P. H., & Teller, E. (1938) · Journal of the American Chemical Society · doi:10.1021/ja01269a023 · Cited by 28,156
Cited by
Challenges and Prospects of Lithium–Sulfur Batteries
Manthiram, A., Fu, Y., & Su, Y.-S. (2013) · Accounts of Chemical Research · doi:10.1021/ar300179v · Cited by 2,380
Porous electrode materials for lithium-ion batteries–how to prepare them and what makes them special
Vu, A., Qian, Y., & Stein, A. (2012) · Advanced Energy Materials · doi:10.1002/aenm.201200320 · Cited by 719
From lithium to sodium: Cell chemistry of room temperature sodium–air and sodium–sulfur batteries
Adelhelm, P., Hartmann, P., Bender, C. L., Busche, M., Eufinger, C., & Janek, J. (2015) · Beilstein Journal of Nanotechnology · doi:10.3762/bjnano.6.105 · Cited by 478
Lu, S., Cheng, Y., Wu, X., & Liu, J. (2013) · Nano Letters · doi:10.1021/nl400543y · Cited by 319
Wang, J., Yao, Z., Monroe, C. W., Yang, J., & Nuli, Y. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201201847 · Cited by 266
Metadata
- Authors
- He, G., Ji, X., & Nazar, L.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 4
- Issue
- 8
- Pages
- 2878
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2071245550
- Cited by
- 475
- References
- 1
- FWCI
- 33.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- He, G., Ji, X., & Nazar, L. (2011). High “C” rate Li-S cathodes: sulfur imbibed bimodal porous carbons. Energy & Environmental Science. https://doi.org/10.1039/c1ee01219c
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