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High “C” rate Li-S cathodes: sulfur imbibed bimodal porous carbons

He, Guang, Ji, Xiulei, Nazar, Linda·2011·Energy & Environmental Science

Abstract

A highly ordered mesoporous carbon with a bimodal pore structure which exhibits a high specific area and large pore volume, was synthesized by a triblock-copolymer-templating approach. This optimized framework served as the scaffold for the preparation of carbon/sulfur (C/S) nanocomposites that serve as novel cathodes for Li-S batteries. They exhibit high discharge capacities and good cycling stability at very high current rates of 1675 mA g−1 (1 C), which can be attributed to the unique bimodal porous structure of the carbon. The small mesopores contain the majority of the sulfur mass and aid in suppressing the diffusion of polysulfide species into the electrolyte, whilst the large interconnected cylindrical pores favour rapid transport of solvated Li+ on charge/discharge. Additional doping with hydrophilic nanoporous silica also aids in capacity retention on cycling.

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Metadata

Authors
He, G., Ji, X., & Nazar, L.
Venue
Energy & Environmental Science
Published
2011
Volume
4
Issue
8
Pages
2878
ISSN
  • 1754-5692 (ISSN-L)
  • 1754-5706
OpenAlex
W2071245550
Cited by
475
References
1
FWCI
33.87
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: High “C” rate Li-S cathodes: sulfur imbibed bimodal porous carbons. https://app.cochat.ai/papers/10.1039/c1ee01219c
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He, G., Ji, X., & Nazar, L. (2011). High “C” rate Li-S cathodes: sulfur imbibed bimodal porous carbons. Energy & Environmental Science. https://doi.org/10.1039/c1ee01219c

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