The DOI matches its Crossref record; 24 of the 24 references it cites were found in a registry or an index.
Gas storage in porous aromatic frameworks (PAFs)
Abstract
A series of porous aromatic frameworks (PAFs) were synthesized via a Yamamoto-type Ullmann reaction containing quadricovalent Si (PAF-3) and Ge (PAF-4). These PAFs are thermally stable up to 465 °C for PAF-3 and 443 °C for PAF-4, corresponding to a 5% weight loss according to the TG pattern. As PAF-1, they exhibit high surface areas (up to 2932 m2 g−1) and excellent adsorption ability to hydrogen, methane and carbon dioxide. Low pressure gas uptake experiments on PAFs show PAF-3 has the highest heat of adsorption (Qst) of hydrogen (6.6 kJ mol−1) and carbon dioxide (19.2 kJ mol−1), while PAF-4 has the highest Qst for methane adsorption (23.2 kJ mol−1) among PAFs. Gas molecule recognition at 273 K was performed and results show only greenhouse gases such as carbon dioxide and methane could be adsorbed onto PAFs.
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Cites
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Self-citation
Cited by
Nanoporous organic polymer networks
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Defects on carbons for electrocatalytic oxygen reduction
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High-throughput computational screening of metal–organic frameworks
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Porous Organic Polymers for Post‐Combustion Carbon Capture
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Enhanced CO2 Capture Capacity of Nitrogen-Doped Biomass-Derived Porous Carbons
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Metadata
- Authors
- Ben, T., Pei, C., Zhang, D., Xu, J., Deng, F., Jing, X., & Qiu, S.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 4
- Issue
- 10
- Pages
- 3991
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2079588474
- Cited by
- 458
- References
- 24
- FWCI
- 16.27
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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