The DOI matches its Crossref record; 58 of the 58 references it cites were found in a registry or an index.
Catalytic conversion of biomass-derived feedstocks into olefins and aromatics with ZSM-5: the hydrogen to carbon effective ratio
Open accessAbstract
Catalytic conversion of ten biomass-derived feedstocks, i.e.glucose, sorbitol, glycerol, tetrahydrofuran, methanol and different hydrogenated bio-oil fractions, with different hydrogen to carbon effective (H/Ceff) ratios was conducted in a gas-phase flow fixed-bed reactor with a ZSM-5 catalyst. The aromatic + olefin yield increases and the coke yield decreases with increasing H/Ceff ratio of the feed. There is an inflection point at a H/Ceff ratio = 1.2, where the aromatic + olefin yield does not increase as rapidly as it does prior to this point. The ratio of olefins to aromatics also increases with increasing H/Ceff ratio. CO and CO2 yields go through a maximum with increasing H/Ceff ratio. The deactivation rate of the catalyst decreases significantly with increasing H/Ceff ratio. Coke was formed from both homogeneous and heterogeneous reactions. Thermogravimetric analysis (TGA) for the ten feedstocks showed that the formation of coke from homogeneous reactions decreases with increasing H/Ceff ratio. Feedstocks with a H/Ceff ratio less than 0.15 produce large amounts of undesired coke (more than 12 wt%) from homogeneous decomposition reactions. This paper shows that the conversion of biomass-derived feedstocks into aromatics and olefins using zeolite catalysts can be explained by the H/Ceff ratio of the feed.
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Cites
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Self-citationIntegrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels
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Conversion of methanol to hydrocarbons over zeolite H-ZSM-5: On the origin of the olefinic species
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Catalytic fast pyrolysis of biomass over zeolites for high quality bio-oil – A review
Rahman, M. M., Liu, R., & Cai, J. (2018) · Fuel Processing Technology · doi:10.1016/j.fuproc.2018.08.002 · Cited by 383
Controlling the selectivity to chemicals from lignin via catalytic fast pyrolysis
Ma, Z., Troussard, E., & van Bokhoven, J. A. (2012) · Applied Catalysis A: General · doi:10.1016/j.apcata.2012.02.027 · Cited by 363
Dai, L., Wang, Y., Liu, Y., He, C., Ruan, R., Yu, Z., Jiang, L., Zeng, Z., & Wu, Q. (2020) · Science of The Total Environment · doi:10.1016/j.scitotenv.2020.142386 · Cited by 264
Metadata
- Authors
- Zhang, H., Cheng, Y.-T., Vispute, T. P., Xiao, R., & Huber, G. W.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 4
- Issue
- 6
- Pages
- 2297
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2166891613
- Cited by
- 513
- References
- 58
- FWCI
- 13.50
- Type
- journal article
- Language
- en
- Open access
- green
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- Zhang, H., Cheng, Y.-T., Vispute, T. P., Xiao, R., & Huber, G. W. (2011). Catalytic conversion of biomass-derived feedstocks into olefins and aromatics with ZSM-5: the hydrogen to carbon effective ratio. Energy & Environmental Science. https://doi.org/10.1039/c1ee01230d
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