The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Aqueous biphasic systems composed of a water-stable ionic liquid + carbohydrates and their applications
Abstract
A water-stable ionic liquid, 1-butyl-3-methylimidazolium trifluoromethanesulfonate, [C4mim][CF3SO3], is herein proposed to be used in the formation of aqueous biphasic systems (ABS) with a large range of mono- and disaccharides, as well as polyols. Binodal curves, tie-lines, and densities and viscosities of the co-existing aqueous phases, were determined for each ternary system. The proposed systems are low-viscous offering enhanced features over conventional polymer-based ABS. In addition, the partitioning of model biomolecules, such as L-tryptophan, caffeine, and β-carotene, was further investigated to ascertain the applicability of such ABS. These systems are particularly interesting in the recovery of bioactive products from natural sources, while the availability of carbon-based sources to cells constitutes a major advantage in separations from fermentative media. Moreover, the use of carbohydrates in ionic-liquid-based ABS constitutes a step forward along the biorefinery concept envisaging sustainable conversions of biomass into a broad spectrum of bio-based products.
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Citations
Cites
Solubility of Carbohydrates in Ionic Liquids
Zakrzewska, M. E., Bogel-Łukasik, E., & Bogel-Łukasik, R. (2010) · Energy & Fuels · doi:10.1021/ef901215m · Cited by 490
Cited by
Aqueous biphasic systems: a boost brought about by using ionic liquids
Freire, M. G., Cláudio, A. F. M., Araújo, J. M. M., Coutinho, J. A. P., Marrucho, I. M., Lopes, J. N. C., & Rebelo, L. P. N. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35151j · Cited by 817
Self-citationPaduszyński, K., & Domańska, U. (2014) · Journal of Chemical Information and Modeling · doi:10.1021/ci500206u · Cited by 277
Farias, F. O., Sosa, F. H. B., Igarashi-Mafra, L., Coutinho, J. A. P., & Mafra, M. R. (2017) · Fluid Phase Equilibria · doi:10.1016/j.fluid.2017.05.018 · Cited by 88
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Metadata
- Authors
- Freire, M. G., Louros, C. L. S., Rebelo, L. P. N., & Coutinho, J. A. P.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 13
- Issue
- 6
- Pages
- 1536
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2120860543
- Cited by
- 192
- References
- 1
- FWCI
- 17.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- Freire, M. G., Louros, C. L. S., Rebelo, L. P. N., & Coutinho, J. A. P. (2011). Aqueous biphasic systems composed of a water-stable ionic liquid + carbohydrates and their applications. Green Chemistry. https://doi.org/10.1039/c1gc15110j
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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