Solubility of Carbohydrates in Ionic Liquids
Abstract
While carbohydrates serve as an abundant, diverse, and reusable source of carbon, their derivatization for industrial applications is still a challenging task because of the low solubility in solvents other than water. Ionic liquids are recognized as green solvents for carbohydrate processing. However, only a limited number of studies have been carried out to investigate their ability to dissolve and modify saccharides. Most of the works focus on cellulose. The aim of this Review is to assess the current state of knowledge regarding the solubility of carbohydrates in ionic liquids but not on modifications of carbohydrates in ionic liquids. We herein collect all of the available literature data about the solubility of various carbohydrates in ionic liquids and highlight their interactions with carbohydrates. The subject of functionalization of carbohydrates in ionic liquids is not discussed in this Review.
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Suitable ionic liquids for cellulose dissolution contain anions that can form strong hydrogen bonds with hydroxyl groups, e.g. chloride, carboxylates, dialkyl phosphates, dialkyl and trialkylphosphonates, and amino acid anions.
“Suitable ionic liquids identified to date contain anions that can form strong hydrogen bonds with hydroxyl groups, e.g.chloride, 69a carboxylates (acetate, formate, propionate, lactate), 78 dialkyl phosphates, dialkyl and trialkylphosphonates 69d and amino acid anions.79”
From Deconstruction of lignocellulosic biomass with ionic liquids (2013) · cites this paper as [78]
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Self-citation
- Authors
- Zakrzewska, M. E., Bogel-Łukasik, E., & Bogel-Łukasik, R.
- Affiliations
- Universidade Nova de Lisboa (PT)
- REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal
- Venue
- Energy & Fuels
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-01-07
- Volume
- 24
- Issue
- 2
- Pages
- 737-745
- ISSN
- 0887-0624 (ISSN-L)
- 1520-5029
- OpenAlex
- W1981259160
- Cited by
- 490
- References
- 62
- Citations by year
- 2026: 3 · 2025: 2 · 2024: 8 · 2023: 21 · 2022: 19 · 2021: 18 · 2020: 23 · 2019: 26 · 2018: 33 · 2017: 28 · 2016: 44 · 2015: 53 · 2014: 46 · 2013: 53 · 2012: 50
- FWCI
- 22.08
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Energy & Fuels (publishedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
- Physical Sciences › Engineering › Biomedical Engineering › Catalysis for Biomass Conversion
- Physical Sciences › Chemistry › Organic Chemistry › Carbohydrate Chemistry and Synthesis
- Keywords
- carbohydrates, ionic liquids, solubility, green solvents
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