Cited by 490Ionic liquids properties and applicationsCatalysis for Biomass ConversionCarbohydrate Chemistry and Synthesis

Solubility of Carbohydrates in Ionic Liquids

Zakrzewska, Małgorzata Ewa, Bogel-Łukasik, Ewa, Bogel-Łukasik, Rafał·2010·Energy & Fuels

Abstract

While carbohydrates serve as an abundant, diverse, and reusable source of carbon, their derivatization for industrial applications is still a challenging task because of the low solubility in solvents other than water. Ionic liquids are recognized as green solvents for carbohydrate processing. However, only a limited number of studies have been carried out to investigate their ability to dissolve and modify saccharides. Most of the works focus on cellulose. The aim of this Review is to assess the current state of knowledge regarding the solubility of carbohydrates in ionic liquids but not on modifications of carbohydrates in ionic liquids. We herein collect all of the available literature data about the solubility of various carbohydrates in ionic liquids and highlight their interactions with carbohydrates. The subject of functionalization of carbohydrates in ionic liquids is not discussed in this Review.

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Crossref · 10.1021/ef901215m

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62 of 62 references verified0 citation errors · 0 not checkable

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  • Suitable ionic liquids for cellulose dissolution contain anions that can form strong hydrogen bonds with hydroxyl groups, e.g. chloride, carboxylates, dialkyl phosphates, dialkyl and trialkylphosphonates, and amino acid anions.

    “Suitable ionic liquids identified to date contain anions that can form strong hydrogen bonds with hydroxyl groups, e.g.chloride, 69a carboxylates (acetate, formate, propionate, lactate), 78 dialkyl phosphates, dialkyl and trialkylphosphonates 69d and amino acid anions.79”

    From Deconstruction of lignocellulosic biomass with ionic liquids (2013) · cites this paper as [78]

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Authors
Zakrzewska, M. E., Bogel-Łukasik, E., & Bogel-Łukasik, R.
Affiliations
  • Universidade Nova de Lisboa (PT)
  • REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal
Venue
Energy & Fuels
Published
2010-01-07
Volume
24
Issue
2
Pages
737-745
ISSN
  • 0887-0624 (ISSN-L)
  • 1520-5029
OpenAlex
W1981259160
Cited by
490
References
62
Citations by year
2026: 3 · 2025: 2 · 2024: 8 · 2023: 21 · 2022: 19 · 2021: 18 · 2020: 23 · 2019: 26 · 2018: 33 · 2017: 28 · 2016: 44 · 2015: 53 · 2014: 46 · 2013: 53 · 2012: 50
FWCI
22.08
Type
journal article
Language
en
Open access
closed
Locations
Energy & Fuels (publishedVersion)
Topics
  • Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
  • Physical Sciences › Engineering › Biomedical Engineering › Catalysis for Biomass Conversion
  • Physical Sciences › Chemistry › Organic Chemistry › Carbohydrate Chemistry and Synthesis
Keywords
carbohydrates, ionic liquids, solubility, green solvents

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