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Vacuum-assisted synthesis of graphene from thermal exfoliation and reduction of graphite oxide
Abstract
We report a vacuum-assisted method for thermal exfoliation and in situreduction of graphite oxide in large quantity at a temperature as low as 135 °C. The resulting graphene sheets contain only few-layered sheets with an average thickness of 0.9 nm, and their specific surface area (758 m2 g−1) is comparable to that of conventional graphene generated at 1050 °C at atmospheric pressure (700 m2 g−1). The in situ thermal reduction during the exfoliation process was confirmed by the increased C/O atomic ratio compared to that of graphite oxide. The restoration of the graphitic sp2 network makes it highly efficient in improving the electrical conductivity of polymers at a low graphene loading.
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Citations
Cited by
Chabot, V., Higgins, D., Yu, A., Xiao, X., Chen, Z., & Zhang, J. (2014) · Energy & Environmental Science · doi:10.1039/c3ee43385d · Cited by 1,119
Graphene based metal and metal oxide nanocomposites: synthesis, properties and their applications
Khan, M., Tahir, M. N., Adil, S. F., Khan, H. U., Siddiqui, M. R. H., Al-warthan, A. A., & Tremel, W. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta02240a · Cited by 709
Methods of graphite exfoliation
Cai, M., Thorpe, D., Adamson, D. H., & Schniepp, H. C. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm34517j · Cited by 508
Functional Biochar Synergistic Solid/Liquid-Phase CO2 Capture: A Review
Zhang, Y., Wang, S., Feng, D., Gao, J., Dong, L., Zhao, Y., Sun, S., Huang, Y., & Qin, Y. (2022) · Energy & Fuels · doi:10.1021/acs.energyfuels.1c04372 · Cited by 91
(0D/3D) MoS2 on porous graphene as catalysts for enhanced electrochemical hydrogen evolution
Liu, Y., Zhu, Y., Fan, X., Wang, S., Li, Y., Zhang, F., Zhang, G., & Peng, W. (2017) · Carbon · doi:10.1016/j.carbon.2017.05.092 · Cited by 60
Metadata
- Authors
- Zhang, H.-B., Wang, J.-W., Yan, Q., Zheng, W.-G., Chen, C., & Yu, Z.-Z.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 21
- Issue
- 14
- Pages
- 5392
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2031713041
- Cited by
- 215
- References
- 0
- FWCI
- 10.53
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, H.-B., Wang, J.-W., Yan, Q., Zheng, W.-G., Chen, C., & Yu, Z.-Z. (2011). Vacuum-assisted synthesis of graphene from thermal exfoliation and reduction of graphite oxide. Journal of Materials Chemistry. https://doi.org/10.1039/c1jm10099h
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