The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
In situ preparation of functionalized graphene oxide/epoxy nanocomposites with effective reinforcements
Abstract
In order to obtain homogeneous dispersion and strong filler-matrix interface in epoxy resin, graphene oxide was functionalized via surface modification by hexachlorocyclotriphosphazene and glycidol and then incorporated into epoxy resin to obtain nanocomposites via in situ thermal polymerization. The morphology of nanocomposites was characterized by scanning electron microscopy and transmission electron microscopy, implying good dispersion of graphene nano-sheets. The incorporation of functionalized graphene oxide effectively enhanced various property performances of epoxy nanocomposites. The storage modulus of the epoxy nanocomposites was significantly increased by 113% (2% addition) and the hardness was improved by 38% (4% addition). Electrical conductivity was improved by 6.5 orders of magnitude. Enhanced thermal stability was also achieved. This work demonstrates a cost-effective approach to construct a flexible interphase structure, strong interfacial interaction and good dispersion of functionalized graphene in epoxy nanocomposites through a local epoxy-rich environment around graphene oxide sheets, which reinforces the polymer properties and indicates further application in research and industrial areas.
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Cites
Two-dimensional gas of massless Dirac fermions in graphene
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Katsnelson, M. I., Grigorieva, I. V., Dubonos, S. V., & Firsov, A. A. (2005) · Nature · doi:10.1038/nature04233 · Cited by 21,611
Superior Thermal Conductivity of Single-Layer Graphene
Balandin, A. A., Ghosh, S., Bao, W., Calizo, I., Teweldebrhan, D., Miao, F., & Lau, C. N. (2008) · Nano Letters · doi:10.1021/nl0731872 · Cited by 13,823
Cited by
Graphene-polymer nanocomposites for structural and functional applications
Hu, K., Kulkarni, D. D., Choi, I., & Tsukruk, V. V. (2014) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2014.03.001 · Cited by 1,085
Wan, Y.-J., Tang, L.-C., Gong, L.-X., Yan, D., Li, Y.-B., Wu, L.-B., Jiang, J.-X., & Lai, G.-Q. (2014) · Carbon · doi:10.1016/j.carbon.2013.12.050 · Cited by 788
Morphology, Crystallinity, and Molecular Weight of Poly(ε-caprolactone)/Graphene Oxide Hybrids
Castilla-Cortázar, I., Vidaurre, A., Marí, B., & Campillo-Fernández, A. J. (2019) · Polymers · doi:10.3390/polym11071099 · Cited by 86
Qiu, S., Xing, W., Mu, X., Feng, X., Ma, C., Yuen, R. K. K., & Hu, Y. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b11101 · Cited by 58
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Metadata
- Authors
- Bao, C., Guo, Y., Song, L., Kan, Y., Qian, X., & Hu, Y.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 21
- Issue
- 35
- Pages
- 13290
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2067358826
- Cited by
- 412
- References
- 2
- FWCI
- 20.73
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bao, C., Guo, Y., Song, L., Kan, Y., Qian, X., & Hu, Y. (2011). In situ preparation of functionalized graphene oxide/epoxy nanocomposites with effective reinforcements. Journal of Materials Chemistry. https://doi.org/10.1039/c1jm11434d
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