The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
TiO2 nanocomposites with high refractive index and transparency
Abstract
Transparent polymer nanocomposites with high refractive index were prepared by grafting polymer chains onto anatase TiO2 nanoparticlesvia a combination of phosphate ligand engineering and alkyne-azide “click” chemistry. Highly crystalline TiO2 nanoparticles with 5 nm diameter were synthesized by a solvothermal method and used as high refractive index filler. The synthesized phosphate-azide ligand anchors strongly onto the TiO2 nanoparticle surface and the azide end group allows for attachment of poly(glycidyl methacrylate) (PGMA) polymer chains through an alkyne-azide “click” reaction. The refractive index of the composite material increased linearly from 1.5 up to 1.8 by increasing the loading of TiO2 particles to 30 vol % (60 wt %). UV-vis spectra show that the nanocomposites exhibited a transparency around 90% throughout the visible light range. It was also found that the PGMA-grafted TiO2 nanoparticles can be well dispersed into a commercial epoxy resin, forming transparent high refractive index TiO2-epxoy nanocomposites.
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Barbey, R., Lavanant, L., Paripovic, D., Schüwer, N., Sugnaux, C., Tugulu, S., & Klok, H.-A. (2009) · Chemical Reviews · doi:10.1021/cr900045a · Cited by 1,753
Near Monodisperse TiO2 Nanoparticles and Nanorods
Li, X., Peng, Q., Yi, J., Wang, X., & Li, Y. (2006) · Chemistry – A European Journal · doi:10.1002/chem.200500893 · Cited by 175
Self-citation
Cited by
Nanocomposites with Polymer Grafted Nanoparticles
Kumar, S. K., Jouault, N., Benicewicz, B., & Neely, T. (2013) · Macromolecules · doi:10.1021/ma4001385 · Cited by 772
Self-citationDispersion stability of thermal nanofluids
Yu, F., Chen, Y., Liang, X., Xu, J., Lee, C., Liang, Q., Tao, P., & Deng, T. (2017) · Progress in Natural Science: Materials International · doi:10.1016/j.pnsc.2017.08.010 · Cited by 355
Self-citationInorganic nanoparticles engineered to attack bacteria
Miller, K. P., Wang, L., Benicewicz, B. C., & Decho, A. W. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00041f · Cited by 290
Self-citationTopologically Induced Heterogeneity in Gradient Copolymer Brush Particle Materials
Zhao, Y., Wang, Z., Yu, C., Wu, H., Olszewski, M., Yin, R., Zhai, Y., Liu, T., Coronado, A., Matyjaszewski, K., et al. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c01131 · Cited by 20
Metadata
- Authors
- Tao, P., Li, Y., Rungta, A., Viswanath, A., Gao, J., Benicewicz, B. C., Siegel, R. W., & Schadler, L. S.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 21
- Issue
- 46
- Pages
- 18623
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2129396599
- Cited by
- 303
- References
- 2
- FWCI
- 13.64
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tao, P., Li, Y., Rungta, A., Viswanath, A., Gao, J., Benicewicz, B. C., Siegel, R. W., & Schadler, L. S. (2011). TiO2 nanocomposites with high refractive index and transparency. Journal of Materials Chemistry. https://doi.org/10.1039/c1jm13093e
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