The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Novel choline-chloride-based deep-eutectic-solvents with renewable hydrogen bond donors: levulinic acid and sugar-based polyols
Abstract
Choline chloride (ChCl) has been combined with renewable hydrogen bond donors (HBD) to form novel deep eutectic solvents (DES) with melting points lower than 100 °C. In some cases (e.g. sorbitol or isosorbide as HBDs) chiral DES can be easily produced. Moreover, the addition of glycerol decreases the viscosity of DES significantly. In the ChCl : levulinic acid DES case, singular properties were observed. Thus, equimolecular mixtures of ChCl : levulinic acid (1 : 1) formed a crystal at room temperature, rapidly melting in contact with air humidity. Addition of excess of acetone to ChCl : levulinic acid (1 : 2) leads to the almost quantitative precipitation of choline chloride, which can be used again to form a DES.
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Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., & Tambyrajah, V. (2003) · Chemical Communications · doi:10.1039/b210714g · Cited by 5,738
Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048266j · Cited by 4,340
Abbott, A. P., Capper, G., Davies, D. L., Munro, H. L., Rasheed, R. K., & Tambyrajah, V. (2001) · Chemical Communications · doi:10.1039/b106357j · Cited by 1,100
Cited by
Deep eutectic solvents: syntheses, properties and applications
Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899
Deep eutectic solvents: A review of fundamentals and applications
Hansen, B. B., Spittle, S., Chen, B., Poe, D., Zhang, Y., Klein, J. M., Horton, A., Adhikari, L., Zelovich, T., Doherty, B. W., et al. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00385 · Cited by 3,422
Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents
Francisco, M., van den Bruinhorst, A., & Kroon, M. C. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201207548 · Cited by 1,378
Deep Eutectic Solvents: Physicochemical Properties and Gas Separation Applications
García, G., Aparicio, S., Ullah, R., & Atilhan, M. (2015) · Energy & Fuels · doi:10.1021/ef5028873 · Cited by 1,112
Florindo, C., Oliveira, F. S., Rebelo, L. P. N., Fernandes, A. M., & Marrucho, I. M. (2014) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc500439w · Cited by 977
Metadata
- Authors
- Maugeri, Z., & Domínguez de María, P.
- Venue
- RSC Adv.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 2
- Issue
- 2
- Pages
- 421-425
- ISSN
- 2046-2069 (ISSN-L)
- OpenAlex
- W1994619041
- Cited by
- 434
- References
- 3
- FWCI
- 6.62
- Type
- journal article
- Language
- en
- Open access
- closed
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