Cited by 1,378Ionic liquids properties and applicationsPhase Equilibria and ThermodynamicsLubricants and Their Additives

Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents

Francisco, María, van den Bruinhorst, Adriaan, Kroon, Maaike C.·2013·Angewandte Chemie International Edition

Abstract

A new generation of designer solvents emerged in the last decade as promising green media for multiple applications, including separation processes: the low‐transition‐temperature mixtures (LTTMs). They can be prepared by mixing natural high‐melting‐point starting materials, which form a liquid by hydrogen‐bond interactions. Among them, deep‐eutectic solvents (DESs) were presented as promising alternatives to conventional ionic liquids (ILs). Some limitations of ILs are overcome by LTTMs, which are cheap and easy to prepare from natural and readily available starting materials, biodegradable, and renewable.

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Crossref · 10.1002/anie.201207548

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Authors
Francisco, M., van den Bruinhorst, A., & Kroon, M. C.
Affiliations
Eindhoven University of Technology (NL)
Corresponding author
Kroon, Maaike C.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2013-02-10
Volume
52
Issue
11
Pages
3074-3085
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2133982938
Cited by
1,378
References
71
Citations by year
2026: 97 · 2025: 101 · 2024: 106 · 2023: 115 · 2022: 123 · 2021: 121 · 2020: 144 · 2019: 140 · 2018: 105 · 2017: 116 · 2016: 74 · 2015: 73 · 2014: 47 · 2013: 15
FWCI
27.61
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
  • TU/e Research Portal (submittedVersion)
Topics
  • Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
  • Physical Sciences › Engineering › Biomedical Engineering › Phase Equilibria and Thermodynamics
  • Physical Sciences › Engineering › Mechanical Engineering › Lubricants and Their Additives
Keywords
low transition temperature mixtures, deep eutectic solvents, ionic liquids, hydrogen bonding, green solvents, separation processes, biodegradable solvents, renewable solvents

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