Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents
Abstract
A new generation of designer solvents emerged in the last decade as promising green media for multiple applications, including separation processes: the low‐transition‐temperature mixtures (LTTMs). They can be prepared by mixing natural high‐melting‐point starting materials, which form a liquid by hydrogen‐bond interactions. Among them, deep‐eutectic solvents (DESs) were presented as promising alternatives to conventional ionic liquids (ILs). Some limitations of ILs are overcome by LTTMs, which are cheap and easy to prepare from natural and readily available starting materials, biodegradable, and renewable.
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Deep eutectic solvents are analogues and alternative green solvents to conventional ionic liquids, with advantages of easy preparation with high purities and low cost.
“Deep eutectic solvents (DESs) were introduced as analogues and alternative green solvents to the conventional ILs, with the advantage of easy preparation with high purities and low cost [28,29].”
From Development of hydrophobic deep eutectic solvents for extraction of pesticides from aqueous environments (2017) · cites this paper as [29]
Most of the synthesized DES reviewed are hydrophilic.
“Most of the synthesized DES reviewed [10,12,22] are hydrophilic.”
From Recent Advances in Hydrophobic Deep Eutectic Solvents for Extraction (2019) · cites this paper as [22]
Some underexplored fields of DES include biomass processing and liquid-liquid extractions or extractive distillation.
“Some of the underexplored fields of DES include biomass processing and liquid-liquid extractions or extractive distillation [22].”
From Recent Advances in Hydrophobic Deep Eutectic Solvents for Extraction (2019) · cites this paper as [22]
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“Most of the synthesized DES reviewed [10, 12,22] are hydrophilic.”
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- Authors
- Francisco, M., van den Bruinhorst, A., & Kroon, M. C.
- Affiliations
- Eindhoven University of Technology (NL)
- Corresponding author
- Kroon, Maaike C.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-02-10
- Volume
- 52
- Issue
- 11
- Pages
- 3074-3085
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2133982938
- Cited by
- 1,378
- References
- 71
- Citations by year
- 2026: 97 · 2025: 101 · 2024: 106 · 2023: 115 · 2022: 123 · 2021: 121 · 2020: 144 · 2019: 140 · 2018: 105 · 2017: 116 · 2016: 74 · 2015: 73 · 2014: 47 · 2013: 15
- FWCI
- 27.61
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- TU/e Research Portal (submittedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
- Physical Sciences › Engineering › Biomedical Engineering › Phase Equilibria and Thermodynamics
- Physical Sciences › Engineering › Mechanical Engineering › Lubricants and Their Additives
- Keywords
- low transition temperature mixtures, deep eutectic solvents, ionic liquids, hydrogen bonding, green solvents, separation processes, biodegradable solvents, renewable solvents
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