Kinetics of hydride transfer from 1,3-dioxolan to the free triphenylmethyl cation preceding the true initiation
Abstract
The process preceding the true initiation of polymerization of 1,3-dioxolan induced by Ph3C+, A– salts is hydride-transfer to the free trityl ion or ion pair.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Initiation of CROP by various carbenium ions has been frequently studied.
“Initiation of CROP by various carbenium ions has been frequently studied, the general reaction scheme is shown in Figure 18 (R + = (C6H5)3C + [49], (C6H5)2CH + [50], (C6H5)CH2 + , H2C = CH -CH2 + and (CH3)3C + [38]).”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [49]
Cited by
Sorted by citations
Ring-Opening Polymerization—An Introductory Review
Nuyken, O., & Pask, S. (2013) · Polymers · doi:10.3390/polym5020361 · Cited by 456 · see citing works
Stable organic cation salts: Ion pair equilibria and use in cationic polymerisation
Ledwith, A., & Sherrington, D. C. (1975) · Advances in polymer science · doi:10.1007/3-540-07460-0_1 · Cited by 31 · see citing works
Penczek, S., & Pretula, J. (2016) · Elsevier eBooks · doi:10.1016/b978-0-12-409547-2.11351-4 · Cited by 25 · see citing works
Self-citationDeMejo, L. P., MacKnight, W. J., & Vogl, O. (1979) · Polymer Journal · doi:10.1295/polymj.11.15 · Cited by 17 · see citing works
Cationic Ring-opening Polymerization: Acetals
Penczek, S., & Kubisa, P. (1989) · Comprehensive Polymer Science and Supplements · doi:10.1016/b978-0-08-096701-1.00111-7 · Cited by 15 · see citing works
Self-citationStolarczyk, A., Kubisa, P., & Penczek, S. (1977) · Journal of Macromolecular Science Part A - Chemistry · doi:10.1080/00222337708061349 · Cited by 13 · see citing works
Self-citationOn the interaction of triphenylmethyl salts with α‐methylstyrene
Velichkova, R., Panayotov, I. M., Doicheva, J., et al. (1982) · Journal of Polymer Science Polymer Chemistry Edition · doi:10.1002/pol.1982.170201015 · Cited by 5 · see citing works
The mechanism of decay of active centres in polymerization of trioxan in solution
Smirnov, Y. N., Volkov, V. P., Rozenberg, B. A., et al. (1974) · Polymer Science U.S.S.R. · doi:10.1016/0032-3950(74)90557-7 · Cited by 5 · see citing works
The polymerization characteristics of lactones in the presence of trityl salts
Khomyakov, A. K., Lyudvig, Y. B., Gorelikov, A. T., et al. (1976) · Polymer Science U.S.S.R. · doi:10.1016/0032-3950(76)90522-0 · Cited by 4 · see citing works
Penczek, S. (2015) · AccessScience · doi:10.1036/1097-8542.801760 · Cited by 4 · see citing works
Self-citationChapter 2 Kinetics of Homogeneous Cationic Polymerization
Ledwith, A., & Sherrington, D. C. (1976) · Elsevier eBooks · doi:10.1016/s0069-8040(08)70048-7 · Cited by 2 · see citing works
Komarov, B. A., Ponomarenko, A. T., Volkov, V. P., et al. (1974) · Polymer Science U.S.S.R. · doi:10.1016/0032-3950(74)90488-2 · Cited by 2 · see citing works
Copolymerization of styrene oxide and cyclohexene oxide
Pasika, W. M., & Chen, D. J. (1991) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.1991.080291011 · Cited by 1 · see citing works
The polymerization of cyclic acetals on poly- and mono-functional catalysts
Kartsovnik, V. I., Vasil'ev, N. I., & Irzhak, V. I. (1975) · Polymer Science U.S.S.R. · doi:10.1016/0032-3950(75)90068-4
Volkov, V. P., Oleinik, E. F., Smirnov, Y. N., et al. (1974) · Polymer Science U.S.S.R. · doi:10.1016/0032-3950(74)90442-0
- Authors
- Słomkowski, S., & Penczek, S.
- Venue
- J. Chem. Soc. D
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1970
- Volume
- 0
- Issue
- 20
- Pages
- 1347-1348
- ISSN
- 0577-6171 (ISSN-L)
- OpenAlex
- W2074461617
- Cited by
- 14
- References
- 0
- Citations by year
- 2016: 1 · 2013: 1
- FWCI
- 0.00
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the Chemical Society D Chemical Communications (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Reaction Mechanisms
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Chemistry › Spectroscopy › Organic and Inorganic Chemical Reactions
- Keywords
- 1,3-dioxolane, triphenylmethyl cation, hydride transfer, polymerization initiation, ion pairs, radical polymerization, reaction kinetics
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
