Structure–charge transport relationship of 5,15-dialkylated porphyrins
Abstract
5,15-Dialkyl-substituted porphyrins that are symmetrically capped with ethyl (C(2)-Por), butyl (C(4)-Por) and hexyl (C(6)-Por) were synthesized and characterized. Molecular structure versus physical property relationship has been established through the analysis of planar charge transport using thin film transistor (TFT) structure.
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The alkyl chain plays a very important role in enhancing the solubility of small molecules in organic solvents and in controlling crystallinity and film morphology.
“It was believed that the alkyl chain plays a very important role in enhancing the solubility of small molecules in organic solvents, as well as controlling the crystallinity and lm morphology.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [98]
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Recent progress in porphyrin-based materials for organic solar cells
Mahmood, A., Hu, J.-Y., Xiao, B., Tang, A., Wang, X., & Zhou, E. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta06392c · Cited by 311 · see citing works
- Authors
- Zhou, L., Xu, Z.-X., Zhou, Y., Feng, Y., Zhou, X.-G., Xiang, H.-F., & Roy, V. A. L.
- Affiliations
- Sichuan University (CN)
- City University of Hong Kong (HK)
- Corresponding author
- Roy, V. A. L.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 48
- Issue
- 42
- Pages
- 5139
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2013542452
- Cited by
- 13
- References
- 0
- Citations by year
- 2020: 1 · 2019: 1 · 2018: 1 · 2017: 1 · 2016: 2 · 2015: 4 · 2013: 3
- FWCI
- 1.03
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Communications (publishedVersion)
- PubMed (publishedVersion)
- ENLIGHTEN (Jurnal Bimbingan dan Konseling Islam) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Porphyrin and Phthalocyanine Chemistry
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Physical Sciences › Chemistry › Organic Chemistry › Synthesis and Properties of Aromatic Compounds
- Keywords
- porphyrin derivatives, structure-property relationships, charge transport, thin-film transistors, organic semiconductors, alkyl substituent effects
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