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Lead halide inorganic–organic hybrids incorporating diammonium cations
Abstract
Diammonium cations of general formula (H3N–R–NH3) have been used as templating moieties on lead(II) halide motifs, forming a variety of inorganic–organic nanocomposites. The R group can have simple, straight alkyl chains, which if even-membered and greater than ethane, form 2-D layers based on the RbAlF4 structure type, as found in [(H3N(CH2)4NH3)PbBr4] (1), [(H3N(CH2)4NH3)PbI4] (2), [(H3N(CH2)8NH3)PbI4] (4), [(H3N(CH2)10NH3)PbBr4] (5), and [(H3N(CH2)12NH3)PbI4] (6). If the R group has fused aromatic rings like naphthalene, the 2-D layered perovskite-type motif is still adopted, as in [(H3NC10H6NH3)PbI4] (7). If the chain is odd-membered, a 0-D inorganic motif, consisting of isolated blocks of face-sharing PbI6 octahedra and isolated iodide anions is seen, as in [(H3N(CH2)7NH3)4Pb3I12·2I−] (3). 1-D motifs, which have edge-sharing twin-anionic chains of corner-sharing ribbons are also observed in the compounds [(H3NC2H4NH3)4PbBr4] (8) and [(H3NC6H4CH2C6H4NH3)PbI6] (9) respectively.
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Cites
Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
Cited by
Li, X., Hoffman, J. M., & Kanatzidis, M. G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01006 · Cited by 1,085
Structural Diversity in White-Light-Emitting Hybrid Lead Bromide Perovskites
Mao, L., Guo, P., Kepenekian, M., Hadar, I., Katan, C., Even, J., Schaller, R. D., Stoumpos, C. C., & Kanatzidis, M. G. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b08691 · Cited by 508
Han, Y., Yue, S., & Cui, B. (2021) · Advanced Science · doi:10.1002/advs.202004805 · Cited by 282
Li, X., Hoffman, J., Ke, W., Chen, M., Tsai, H., Nie, W., Mohite, A. D., Kepenekian, M., Katan, C., Even, J., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b07712 · Cited by 253
Lyu, R., Moore, C. E., Liu, T., Yu, Y., & Wu, Y. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05441 · Cited by 114
Metadata
- Authors
- Lemmerer, A., & Billing, D. G.
- Venue
- CrystEngComm
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 14
- Issue
- 6
- Pages
- 1954
- ISSN
- 1466-8033 (ISSN-L)
- OpenAlex
- W2050463411
- Cited by
- 177
- References
- 1
- FWCI
- 2.85
- Type
- journal article
- Language
- en
- Open access
- closed
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