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Lead halide inorganic–organic hybrids incorporating diammonium cations

Lemmerer, Andreas, Billing, David G.·2012·CrystEngComm

Abstract

Diammonium cations of general formula (H3N–R–NH3) have been used as templating moieties on lead(II) halide motifs, forming a variety of inorganic–organic nanocomposites. The R group can have simple, straight alkyl chains, which if even-membered and greater than ethane, form 2-D layers based on the RbAlF4 structure type, as found in [(H3N(CH2)4NH3)PbBr4] (1), [(H3N(CH2)4NH3)PbI4] (2), [(H3N(CH2)8NH3)PbI4] (4), [(H3N(CH2)10NH3)PbBr4] (5), and [(H3N(CH2)12NH3)PbI4] (6). If the R group has fused aromatic rings like naphthalene, the 2-D layered perovskite-type motif is still adopted, as in [(H3NC10H6NH3)PbI4] (7). If the chain is odd-membered, a 0-D inorganic motif, consisting of isolated blocks of face-sharing PbI6 octahedra and isolated iodide anions is seen, as in [(H3N(CH2)7NH3)4Pb3I12·2I−] (3). 1-D motifs, which have edge-sharing twin-anionic chains of corner-sharing ribbons are also observed in the compounds [(H3NC2H4NH3)4PbBr4] (8) and [(H3NC6H4CH2C6H4NH3)PbI6] (9) respectively.

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Metadata

Authors
Lemmerer, A., & Billing, D. G.
Venue
CrystEngComm
Published
2012
Volume
14
Issue
6
Pages
1954
ISSN
1466-8033 (ISSN-L)
OpenAlex
W2050463411
Cited by
177
References
1
FWCI
2.85
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Lead halide inorganic–organic hybrids incorporating diammonium cations. https://app.cochat.ai/papers/10.1039/c2ce06498g
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Lemmerer, A., & Billing, D. G. (2012). Lead halide inorganic–organic hybrids incorporating diammonium cations. CrystEngComm. https://doi.org/10.1039/c2ce06498g

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