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Directed electron transfer in Langmuir–Schäfer layers of porphyrin–fullerene and phthalocyanine–fullerene dyads in inverted organic solar cells
Abstract
In this study double linked porphyrin-fullerene and phthalocyanine-fullerene dyads and a single linked phthalocyanine-fullerene dyad were studied as components in inverted organic solar cells (OSCs) equipped with the well known P3HT:PCBM bulk heterojunction as the photoactive layer. The dyad monolayers were deposited onto a surface of P3HT:PCBM by using the Langmuir-Schäfer method, therefore forming oriented monolayers in which the electron donor (D) and the acceptor (A) exist as a close proximity pair in a 1:1 molar ratio. As a result of this structure short circuit current density (J(sc)), open circuit voltage (V(oc)), and power conversion efficiency (η) increased, while the fill factor (FF) remained the same. The devices which contained dyads with double linkage produced higher efficiencies than the one with a single linked dyad. This result can be explained in terms of molecular orientation. It was also verified that the prepared OSC devices have promising long term air stability.
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“In 2012, Lemmetyinen et al. used a doubly linked porphyrin -fullerene dyad ( J1 , Fig. 19) as an interlayer between P3HT:PC61BM and a tris(8-hydroxyquinolinato)aluminum (Alq3) layer, 152 which improved the PCE from 1.8% to 2.6%.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [152]
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Cites
Polymer–Fullerene Bulk‐Heterojunction Solar Cells
Brabec, C. J., Gowrisanker, S., Halls, J. J. M., Laird, D. W., Jia, S., & Williams, S. P. (2010) · Advanced Materials · doi:10.1002/adma.200903697 · Cited by 2,652
He, Z., Zhong, C., Huang, X., Wong, W., Wu, H., Chen, L., Su, S., & Cao, Y. (2011) · Advanced Materials · doi:10.1002/adma.201103006 · Cited by 2,134
Inverted bulk-heterojunction organic photovoltaic device using a solution-derived ZnO underlayer
White, M. S., Olson, D. C., Shaheen, S. E., Kopidakis, N., & Ginley, D. S. (2006) · Applied Physics Letters · doi:10.1063/1.2359579 · Cited by 834
Degradation of organic solar cells due to air exposure
Kawano, K., Pacios, R., Poplavskyy, D., Nelson, J., Bradley, D. D. C., & Durrant, J. R. (2006) · Solar Energy Materials and Solar Cells · doi:10.1016/j.solmat.2006.06.041 · Cited by 735
Molecular and Morphological Influences on the Open Circuit Voltages of Organic Photovoltaic Devices
Perez, M. D., Borek, C., Forrest, S. R., & Thompson, M. E. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9007722 · Cited by 528
Estimating the manufacturing cost of purely organic solar cells
Kalowekamo, J., & Baker, E. D. (2009) · Solar Energy · doi:10.1016/j.solener.2009.02.003 · Cited by 399
Flexible organic P3HT:PCBM bulk-heterojunction modules with more than 1 year outdoor lifetime
Hauch, J., Schilinsky, P., Choulis, S. A., Childers, R., Biele, M., & Brabec, C. J. (2008) · Solar Energy Materials and Solar Cells · doi:10.1016/j.solmat.2008.01.004 · Cited by 375
Zehner, R. W., Parsons, B. F., Hsung, R. P., & Sita, L. R. (1999) · Langmuir · doi:10.1021/la981114f · Cited by 237
Hasobe, T., Saito, K., Kamat, P. V., Troiani, V., Qiu, H., Solladié, N., Kim, K. S., Park, J. K., Kim, D., D'Souza, F. W., et al. (2007) · Journal of Materials Chemistry · doi:10.1039/b706678c · Cited by 159
Effect of metal electrodes on the performance of polymer:fullerene bulk heterojunction solar cells
Mihailetchi, V. D., Koster, L. J. A., & Blom, P. W. M. (2004) · Applied Physics Letters · doi:10.1063/1.1782252 · Cited by 144
Roles of Interlayers in Efficient Organic Photovoltaic Devices
Park, J. H., Lee, T., Chin, B., Wang, D. H., & Park, O. O. (2010) · Macromolecular Rapid Communications · doi:10.1002/marc.201000310 · Cited by 112
Optical Modulation of Molecular Conductance
Battacharyya, S., Kibel, A., Kodis, G., Liddell, P. A., Gervaldo, M., Gust, D., & Lindsay, S. M. (2011) · Nano Letters · doi:10.1021/nl200977c · Cited by 96
Chukharev, V. I., Tkachenko, N. V., Efimov, A., Guldi, D. M., Hirsch, A., Scheloske, M., & Lemmetyinen, H. J. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp037442s · Cited by 91
Self-citationSelf-Organization of Amphiphilic Porphyrins at the Air-Water Interface
Kroon, J. M., Sudhölter, E. J. R., Schenning, A. P. H. J., & Nolte, R. J. M. (1995) · Langmuir · doi:10.1021/la00001a037 · Cited by 87
Influence of Alq3/Au cathode on stability and efficiency of a layered organic solar cell in air
Vivo, P., Jukola, J., Ojala, M., Chukharev, V. I., & Lemmetyinen, H. J. (2008) · Solar Energy Materials and Solar Cells · doi:10.1016/j.solmat.2008.06.002 · Cited by 80
Self-citationPhotoinduced Electron Transfer in Langmuir−Blodgett Monolayers of Porphyrin−Fullerene Dyads
Vuorinen, T., Kaunisto, K. M., Tkachenko, N. V., Efimov, A., Lemmetyinen, H. J., Alekseev, A. S., Hosomizu, K., & Imahori, H. (2005) · Langmuir · doi:10.1021/la050347l · Cited by 69
Self-citationPhotoinduced electron transfer of double-bridged phthalocyanine–fullerene dyads
Isosomppi, M., Tkachenko, N. V., Efimov, A., Vahasalo, H., Jukola, J., Vainiotalo, P., & Lemmetyinen, H. J. (2006) · Chemical Physics Letters · doi:10.1016/j.cplett.2006.08.107 · Cited by 66
Self-citationEfficient synthesis of highly soluble doubly-bridged porphyrin-fullerene dyad
Efimov, A., Vainiotalo, P., Tkachenko, N. V., & Lemmetyinen, H. J. (2003) · Journal of Porphyrins and Phthalocyanines · doi:10.1142/s1088424603000768 · Cited by 44
Self-citationSelf-Organization of Porphyrins and Fullerenes for Molecular Photoelectrochemical Devices
Umeyama, T., & Imahori, H. (2006) · Photosynthesis Research · doi:10.1007/s11120-005-4632-z · Cited by 41
Lemmetyinen, H. J., Tkachenko, N. V., Efimov, A., & Niemi, M. (2010) · Physical Chemistry Chemical Physics · doi:10.1039/c0cp01106a · Cited by 40
Self-citationAlekseev, A. S., Tkachenko, N. V., Tauber, A. Y., Hynninen, P. H., Österbacka, R., Stubb, H., & Lemmetyinen, H. J. (2002) · Chemical Physics · doi:10.1016/s0301-0104(01)00515-8 · Cited by 36
Self-citationLehtivuori, H. K., Kumpulainen, T., Efimov, A., Lemmetyinen, H. J., Kira, A., Imahori, H., & Tkachenko, N. V. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp8026918 · Cited by 34
Self-citationPhotocurrent Generation from Porphyrin/Fullerene Complexes Assembled in a Tethered Lipid Bilayer
Zhan, W., Jiang, K., Smith, M. D., Bostic, H. E., Best, M. D., Auad, M. L., Ruppel, J. V., Kim, C., & Zhang, X. P. (2010) · Langmuir · doi:10.1021/la102884u · Cited by 22
Kinetics of Photoinduced Electron Transfer in Polythiophene−Porphyrin−Fullerene Molecular Films
Vuorinen, T., Kaunisto, K. M., Chukharev, V. I., Tkachenko, N. V., Efimov, A., & Lemmetyinen, H. J. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp063076b · Cited by 15
Self-citationLong-lived charge separated state in molecular films containing porphyrin–fullerene dyad
Kaunisto, K. M., Chukharev, V. I., Tkachenko, N. V., & Lemmetyinen, H. J. (2008) · Chemical Physics Letters · doi:10.1016/j.cplett.2008.06.012 · Cited by 15
Self-citationAlekseev, A. S., Tkachenko, N. V., Efimov, A., & Lemmetyinen, H. J. (2010) · Russian Journal of Physical Chemistry A · doi:10.1134/s0036024410070253 · Cited by 9
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Kesters, J., Verstappen, P., Kelchtermans, M., Lutsen, L., Vanderzande, D., & Maes, W. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201500218 · Cited by 193
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Metadata
- Authors
- Tolkki, A., Kaunisto, K., Efimov, A., Kivistö, H., Storbacka, L., Savikoski, R., Huttunen, K., Lehtimäki, S., & Lemmetyinen, H.
- Affiliations
- Tampere University of Technology (FI)
- Corresponding author
- Tolkki, A.
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 14
- Issue
- 10
- Pages
- 3498
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W1992642444
- Cited by
- 18
- References
- 26
- Citations by year
- 2026: 2 · 2023: 1 · 2022: 1 · 2021: 2 · 2020: 1 · 2018: 2 · 2017: 1 · 2015: 2 · 2014: 5 · 2013: 1
- FWCI
- 1.63
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Physical Chemistry Chemical Physics (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Physical Sciences › Chemistry › Organic Chemistry › Fullerene Chemistry and Applications
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Light-Emitting Diodes Research
- Keywords
- inverted organic solar cells, porphyrin-fullerene dyads, donor-acceptor pairs, molecular orientation, power conversion efficiency, air stability, organic solar cells
- MeSH terms
- Electron Transport, Indoles, Membranes, Artificial, Porphyrins, Solar Energy, Fullerenes, Isoindoles
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