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Exploration of the active center structure of nitrogen-doped graphene-based catalysts for oxygen reduction reaction
Abstract
We present two different ways to fabricate nitrogen-doped graphene (N-graphene) and demonstrate its use as a metal-free catalyst to study the catalytic active center for the oxygen reduction reaction (ORR). N-graphene was produced by annealing of graphene oxide (G-O) under ammonia or by annealing of a N-containing polymer/reduced graphene oxide (RG-O) composite (polyaniline/RG-O or polypyrrole/RG-O). The effects of the N precursors and annealing temperature on the performance of the catalyst were investigated. The bonding state of the N atom was found to have a significant effect on the selectivity and catalytic activity for ORR. Annealing of G-O with ammonia preferentially formed graphitic N and pyridinic N centers, while annealing of polyaniline/RG-O and polypyrrole/RG-O tended to generate pyridinic and pyrrolic N moieties, respectively. Most importantly, the electrocatalytic activity of the catalyst was found to be dependent on the graphitic N content which determined the limiting current density, while the pyridinic N content improved the onset potential for ORR. However, the total N content in the graphene-based non-precious metal catalyst does not play an important role in the ORR process.
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Cites
Preparation of Graphitic Oxide
Hummers, W. S., & Offeman, R. E. (1958) · Journal of the American Chemical Society · doi:10.1021/ja01539a017 · Cited by 29,920
Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction
Gong, K., Du, F., Xia, Z., Durstock, M., & Dai, L. (2009) · Science · doi:10.1126/science.1168049 · Cited by 7,188
Nitrogen-Doped Graphene as Efficient Metal-Free Electrocatalyst for Oxygen Reduction in Fuel Cells
Qu, L., Liu, Y., Baek, J.-B., & Dai, L. (2010) · ACS Nano · doi:10.1021/nn901850u · Cited by 3,948
Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
Greeley, J., Stephens, I. E. L., Bondarenko, A. S., Johansson, T. P., Hansen, H. A., Jaramillo, T. F., Rossmeisl, J., Chorkendorff, I., & Nørskov, J. K. (2009) · Nature Chemistry · doi:10.1038/nchem.367 · Cited by 3,203
Sheng, Z.-H., Shao, L., Chen, J.-J., Bao, W.-J., Wang, F.-B., & Xia, X.-H. (2011) · ACS Nano · doi:10.1021/nn103584t · Cited by 2,573
Structural evolution during the reduction of chemically derived graphene oxide
Bagri, A., Mattevi, C., Acik, M., Chabal, Y. J., Chhowalla, M., & Shenoy, V. B. (2010) · Nature Chemistry · doi:10.1038/nchem.686 · Cited by 1,819
Zheng, Y., Liu, J., Liang, J., Jaroniec, M., & Qiao, S. Z. (2012) · Energy & Environmental Science · doi:10.1039/c2ee03479d · Cited by 1,741
Liu, R., Wu, D., Feng, X., & Müllen, K. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200907289 · Cited by 1,393
High oxygen-reduction activity and durability of nitrogen-doped graphene
Geng, D., Chen, Y., Chen, Y., Li, Y., Li, R., Sun, X., Ye, S., & Knights, S. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00326c · Cited by 1,219
Toward N-Doped Graphene via Solvothermal Synthesis
Deng, D., Pan, X., Yu, L., Cui, Y., Jiang, Y., Qi, J., Li, W.-X., Fu, Q., Ma, X., Xue, Q., et al. (2011) · Chemistry of Materials · doi:10.1021/cm102666r · Cited by 1,064
Pyridinic N doped graphene: synthesis, electronic structure, and electrocatalytic property
Luo, Z., Lim, S., Tian, Z., Shang, J., Lai, L., MacDonald, B., Fu, C., Shen, Z., Yu, T., & Lin, J. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm10845j · Cited by 1,014
Self-citationInfluence of Nitrogen Doping on Oxygen Reduction Electrocatalysis at Carbon Nanofiber Electrodes
Maldonado, S., & Stevenson, K. J. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp044442z · Cited by 846
On the mechanism of enhanced oxygen reduction reaction in nitrogen-doped graphene nanoribbons
Kim, H., Lee, K., Woo, S. I., & Jung, Y. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp21665a · Cited by 694
Kinetic Model of Platinum Dissolution in PEMFCs
Darling, R. M., & Meyers, J. P. (2003) · Journal of The Electrochemical Society · doi:10.1149/1.1613669 · Cited by 688
Rao, C. V., Cabrera, C. R., & Ishikawa, Y. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz100971v · Cited by 635
Progress in preparation of non-noble electrocatalysts for PEM fuel cell reactions
Zhang, L., Zhang, J., Wilkinson, D. P., & Wang, H. (2006) · Journal of Power Sources · doi:10.1016/j.jpowsour.2005.05.069 · Cited by 503
Graphene-Based Non-Noble-Metal Catalysts for Oxygen Reduction Reaction in Acid
Byon, H. R., Suntivich, J., & Shao-Horn, Y. (2011) · Chemistry of Materials · doi:10.1021/cm2000649 · Cited by 453
Nallathambi, V., Lee, J.-W., Kumaraguru, S. P., Wu, G., & Popov, B. N. (2008) · Journal of Power Sources · doi:10.1016/j.jpowsour.2008.05.020 · Cited by 419
Subramanian, N. P., Li, X., Nallathambi, V., Kumaraguru, S. P., Colon-Mercado, H., Wu, G., Lee, J.-W., & Popov, B. N. (2009) · Journal of Power Sources · doi:10.1016/j.jpowsour.2008.11.087 · Cited by 418
Nitrogen doped carbon nanotubes and their impact on the oxygen reduction reaction in fuel cells
Chen, Z., Higgins, D., & Chen, Z. (2010) · Carbon · doi:10.1016/j.carbon.2010.04.038 · Cited by 370
Feng, L., Yan, Y., Chen, Y., & Wang, L. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01153g · Cited by 367
Self-citationPreparation and oxygen reduction activity of BN-doped carbons
Ozaki, J.-I., Kimura, N., Anahara, T., & Oya, A. (2007) · Carbon · doi:10.1016/j.carbon.2007.04.031 · Cited by 324
Electrochemical oxygen reduction on nitrogen doped graphene sheets in acid media
Lee, K. R., Lee, K. U., Lee, J. W., Ahn, B. T., & Woo, S. I. (2010) · Electrochemistry Communications · doi:10.1016/j.elecom.2010.05.023 · Cited by 278
Fe-Based Catalysts for Oxygen Reduction in PEMFCs
Jaouen, F., Charreteur, F., & Dodelet, J. P. (2006) · Journal of The Electrochemical Society · doi:10.1149/1.2168418 · Cited by 272
Enhancement of Chemical Activity in Corrugated Graphene
Boukhvalov, D. W., & Katsnelson, M. I. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp905702e · Cited by 244
Nitrogen-Containing Carbon Nanostructures as Oxygen-Reduction Catalysts
Biddinger, E. J., von Deak, D., & Ozkan, U. S. (2009) · Topics in Catalysis · doi:10.1007/s11244-009-9289-y · Cited by 224
Nitrogen-Treated Graphite and Oxygen Electroreduction on Pyridinic Edge Sites
Kurak, K. A., & Anderson, A. B. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp811518e · Cited by 212
Huang, S.-F., Terakura, K., Ozaki, T., Ikeda, T., Boero, M., Oshima, M., Ozaki, J.-I., & Miyata, S. (2009) · Physical Review B · doi:10.1103/physrevb.80.235410 · Cited by 193
Role of Graphitic Edge Plane Exposure in Carbon Nanostructures for Oxygen Reduction Reaction
Biddinger, E. J., & Ozkan, U. S. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp104074t · Cited by 188
Nitrogen doped carbon nanotubes synthesized from aliphatic diamines for oxygen reduction reaction
Higgins, D. C., Chen, Z., & Chen, Z. (2010) · Electrochimica Acta · doi:10.1016/j.electacta.2010.11.003 · Cited by 137
Wang, P., Wang, Z., Jia, L., & Xiao, Z. (2009) · Physical Chemistry Chemical Physics · doi:10.1039/b818408a · Cited by 126
Gochi‐Ponce, Y., Alonso-Núñez, G., & Alonso‐Vante, N. (2006) · Electrochemistry Communications · doi:10.1016/j.elecom.2006.06.026 · Cited by 76
Ikeda, T., Boero, M., Huang, S., Terakura, K., Oshima, M., Ozaki, J., & Miyata, S. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp100045e · Cited by 76
In Search for Structure of Active Site in Iron-Based Oxygen Reduction Electrocatalysts
Jain, M., Chou, S.-H., & Siedle, A. R. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp055799l · Cited by 30
Research works printed but not linked: 1
- Pattabi, 2001, Int. J. Hydrogen Energy, 26, 171, 10.1016/S0360-3199(00)00045-8 · DOI
Cited by
Metal-Free Catalysts for Oxygen Reduction Reaction
Dai, L., Xue, Y., Qu, L., Choi, H.-J., & Baek, J.-B. (2015) · Chemical Reviews · doi:10.1021/cr5003563 · Cited by 2,380
Heteroatom-doped graphene materials: syntheses, properties and applications
Wang, X., Sun, G., Routh, P., Kim, D.-H., Huang, W., & Chen, P. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00141a · Cited by 1,891
Rechargeable Batteries for Grid Scale Energy Storage
Zhu, Z., Jiang, T., Ali, M., Meng, Y., Jin, Y., Cui, Y., & Chen, W. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00289 · Cited by 1,769
Single-Atom Catalysts across the Periodic Table
Kaiser, S. K., Chen, Z., Faust Akl, D., Mitchell, S., & Pérez-Ramírez, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00576 · Cited by 1,367
Oxygen Reduction in Alkaline Media: From Mechanisms to Recent Advances of Catalysts
Ge, X., Sumboja, A., Wuu, D., An, T., Li, B., Goh, F. W. T., Hor, T. S. A., Zong, Y., & Liu, Z. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00524 · Cited by 1,341
Metadata
- Authors
- Lai, L., Potts, J. R., Zhan, D., Wang, L., Poh, C. K., Tang, C., Gong, H., Shen, Z., Lin, J., & Ruoff, R. S.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 5
- Issue
- 7
- Pages
- 7936
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2091938741
- Cited by
- 2,277
- References
- 34
- FWCI
- 47.37
- Type
- journal article
- Language
- en
- Open access
- closed
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