The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Sodium insertion in carboxylate based materials and their application in 3.6 V full sodium cells
Abstract
The sodium battery has the potential to be the next generation rechargeable system which utilizes cheaper and more abundant sodium material but affords nearly the same power as lithium batteries. One of the key barriers for the sodium battery is the lack of stable anode materials which can insert sodium ions reversibly at relatively low potential. This contribution reports the sodium insertion in a series of organic carboxylate based materials: (C8H4Na2O4), (C8H6O4), (C8H5NaO4), (C8Na2F4O4), (C10H2Na4O8), (C14H4O6) and (C14H4Na4O8) at low voltage (below 0.6 V vs. Na/Na+). These organic anode materials can insert reversibly up to 2 Na per molecule with good cycleability. The Na insertion mechanism was proposed and 3.6 V full sodium batteries were made and cycled reversibly at room temperature and at 55 °C.
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Cites
The Surface Chemistry of Lithium Electrodes in Alkyl Carbonate Solutions
Aurbach, D., Ein‐Ely, Y., & Zaban, A. (1994) · Journal of The Electrochemical Society · doi:10.1149/1.2054718 · Cited by 344
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Update on Na-based battery materials. A growing research path
Palomares, V., Casas-Cabanas, M., Castillo-Martínez, E., Han, M. H., & Rojo, T. (2013) · Energy & Environmental Science · doi:10.1039/c3ee41031e · Cited by 992
Metal–organic frameworks as platforms for clean energy
Li, S.-L., & Xu, Q. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40507a · Cited by 970
Opportunities and Challenges for Organic Electrodes in Electrochemical Energy Storage
Poizot, P., Gaubicher, J., Renault, S., Dubois, L., Liang, Y., & Yao, Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00482 · Cited by 963
Carbonyls: Powerful Organic Materials for Secondary Batteries
Häupler, B., Wild, A., & Schubert, U. S. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201402034 · Cited by 819
A zero-strain layered metal oxide as the negative electrode for long-life sodium-ion batteries
Wang, Y., Yu, X., Xu, S., Bai, J., Xiao, R., Hu, Y.-S., Li, H., Yang, X.-Q., Chen, L., & Huang, X. (2013) · Nature Communications · doi:10.1038/ncomms3365 · Cited by 616
Metadata
- Authors
- Abouimrane, A., Weng, W., Eltayeb, H., Cui, Y., Niklas, J., Poluektov, O., & Amine, K.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 5
- Issue
- 11
- Pages
- 9632
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W1972894629
- Cited by
- 273
- References
- 1
- FWCI
- 16.48
- Type
- journal article
- Language
- en
- Open access
- closed
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