New natural and renewable low transition temperature mixtures (LTTMs): screening as solvents for lignocellulosic biomass processing

Novel solvent properties of choline chloride/urea mixturesElectronic supplementary information (ESI) available: spectroscopic data. See http://www.rsc.org/suppdata/cc/b2/b210714g/

Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., & Tambyrajah, V. (2003) · Chemical Communications · doi:10.1039/b210714g · Cited by 5,738

Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids

Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048266j · Cited by 4,340

Ionic liquid processing of cellulose

Wang, H., Gurau, G., & Rogers, R. D. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15311d · Cited by 1,369

Are Natural Deep Eutectic Solvents the Missing Link in Understanding Cellular Metabolism and Physiology?

Choi, Y. H., van Spronsen, J., Dai, Y., Verberne, M., Hollmann, F., Arends, I. W. C. E., Witkamp, G.-J., & Verpoorte, R. (2011) · Plant Physiology · doi:10.1104/pp.111.178426 · Cited by 1,368

Glycerol eutectics as sustainable solvent systems

Abbott, A. P., Harris, R. C., Ryder, K. S., D’Agostino, C., Gladden, L. F., & Mantle, M. D. (2010) · Green Chemistry · doi:10.1039/c0gc00395f · Cited by 899

Predicting Hydrogen-Bond Strengths from Acid−Base Molecular Properties. The pKa Slide Rule: Toward the Solution of a Long-Lasting Problem

Gilli, P., Pretto, L., Bertolasi, V., & Gilli, G. (2008) · Accounts of Chemical Research · doi:10.1021/ar800001k · Cited by 745

Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems

Remsing, R. C., Swatloski, R. P., Rogers, R. D., & Moyna, G. (2006) · Chemical Communications · doi:10.1039/b600586c · Cited by 712

Shape‐Controlled Synthesis of Gold Nanoparticles in Deep Eutectic Solvents for Studies of Structure–Functionality Relationships in Electrocatalysis

Liao, H., Jiang, Y., Zhou, Z., Chen, S., & Sun, S. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200803202 · Cited by 450

Ionic liquids from renewable biomaterials: synthesis, characterization and application in the pretreatment of biomass

Liu, Q., Hou, X., Li, N., & Zong, M. (2011) · Green Chemistry · doi:10.1039/c2gc16128a · Cited by 441

Phosphonium-Based Ionic Liquids Analogues and Their Physical Properties

Kareem, M. A., Mjalli, F. S., Hashim, M. A., & AlNashef, I. M. (2010) · Journal of Chemical & Engineering Data · doi:10.1021/je100104v · Cited by 434

Design of Deep Eutectic Systems: A Simple Approach for Preselecting Eutectic Mixture Constituents

Alhadid, A., Mokrushina, L., & Minceva, M. (2020) · Molecules · doi:10.3390/molecules25051077 · Cited by 95

Hydrogels derived from lignocellulosic compounds: Evaluation of the compositional, structural, mechanical and antimicrobial properties

Kalinoski, R. M., & Shi, J. (2018) · Industrial Crops and Products · doi:10.1016/j.indcrop.2018.11.002 · Cited by 88

Evaluation of current and future solvents for selective lignin dissolution–A review

Rashid, T., Sher, F., Rasheed, T., Zafar, F., Zhang, S., & Murugesan, T. (2020) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2020.114577 · Cited by 90

Rapid and efficient microwave-assisted guanidine hydrochloride deep eutectic solvent pretreatment for biological conversion of castor stalk

Zhong, L., Wang, C., Yang, G., Chen, J., Xu, F., Yoo, C. G., & Lyu, G. (2021) · Bioresource Technology · doi:10.1016/j.biortech.2021.126022 · Cited by 90

Cellulose nanocrystals from lignocellulosic feedstock: a review of production technology and surface chemistry modification

Raza, M., & Abu‐Jdayil, B. (2022) · Cellulose · doi:10.1007/s10570-021-04371-y · Cited by 89

Applications of biomass-derived solvents in biomass pretreatment – Strategies, challenges, and prospects

Meng, X., Wang, Y., Conte, A. J., Zhang, S., Ryu, J.-A., Wie, J. J., Pu, Y., Davison, B. H., Yoo, C. G., & Ragauskas, A. J. (2022) · Bioresource Technology · doi:10.1016/j.biortech.2022.128280 · Cited by 88

Activation of Microcrystalline Cellulose in a CO2‐Based Switchable System

Zhang, Q., Öztekin, N. S., Barrault, J., Vigier, K. D. O., & Jérôme, F. (2013) · ChemSusChem · doi:10.1002/cssc.201200815 · Cited by 86

Aqueous Two-Phase Systems Based on Ionic Liquids and Deep Eutectic Solvents as a Tool for the Recovery of Non-Protein Bioactive Compounds—A Review

Buarque, F. S., Gautério, G. V., Coelho, M. A. Z., Lemes, A. C., & Ribeiro, B. D. (2022) · Processes · doi:10.3390/pr11010031 · Cited by 88

Production of nanocellulose using acidic deep eutectic solvents based on choline chloride and carboxylic acids: A review

Wang, Y., Liu, H., Ji, X., Wang, Q., Tian, Z., & Fatehi, P. (2023) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2023.125227 · Cited by 90

New levulinic acid-based deep eutectic solvents: Synthesis and physicochemical property determination

Li, G., Jiang, Y., Liu, X., & Deng, D. (2016) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2016.07.039 · Cited by 88

Deep eutectic solvents for fractionation and valorization of lignocellulose

Bao, Y., Wang, Y., Yan, C., & Xue, Z. (2024) · Green Chemical Engineering · doi:10.1016/j.gce.2024.04.001 · Cited by 88

High Yield Protein Extraction from Brewer's Spent Grain with Novel Carboxylate Salt ‐ Urea Aqueous Deep Eutectic Solvents

Wahlström, R., Rommi, K., Willberg‐Keyriläinen, P., Ercili-Cura, D., Holopainen‐Mantila, U., Hiltunen, J., Mäkinen, O. E., Nygrén, H., Mikkelson, A., & Kuutti, L. (2017) · ChemistrySelect · doi:10.1002/slct.201701492 · Cited by 86

Assessing the Facile Pretreatments of Bagasse for Efficient Enzymatic Conversion and Their Impacts on Structural and Chemical Properties

Satlewal, A., Agrawal, R., Das, P., Bhagia, S., Pu, Y., Puri, S. K., Ramakumar, S. S. V., & Ragauskas, A. J. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b04773 · Cited by 86

Development of natural deep eutectic solvent (NADES) based on choline chloride as a green solvent to extract phenolic compound from coffee husk waste

Maimulyanti, A., Nurhidayati, I., Mellisani, B., Putri, F. A. R., Puspita, F., & Prihadi, A. R. (2023) · Arabian Journal of Chemistry · doi:10.1016/j.arabjc.2023.104634 · Cited by 94

Zinc-based deep eutectic solvent-mediated hydroxylation and demethoxylation of lignin for the production of wood adhesive

Hong, S., Lian, H., Sun, X., Pan, D., Carranza, A., Pojman, J. A., & Mota-Morales, J. D. (2016) · RSC Advances · doi:10.1039/c6ra18290a · Cited by 85

Lignin/polysaccharide composite: A nature-made match toward multifunctional bio-based materials

Yu, S., Chen, L., Xie, Y., Feng, Q., & Chen, C. (2024) · Progress in Materials Science · doi:10.1016/j.pmatsci.2024.101383 · Cited by 85

Dissolution of Cellulose: Are Ionic Liquids Innocent or Noninnocent Solvents?

Bodachivskyi, I., Page, C. J., Kuzhiumparambil, U., Hinkley, S. F. R., Sims, I. M., & Williams, D. B. G. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.0c02204 · Cited by 82

Deep Eutectic Solvent Extraction of High‐Purity Lignin from a Corn Stover Hydrolysate

Cronin, D. J., Chen, X., Moghaddam, L., & Zhang, X. (2020) · ChemSusChem · doi:10.1002/cssc.202001243 · Cited by 86

Comparison of Lignin Fractions Isolated from Wheat Straw Using Alkaline and Acidic Deep Eutectic Solvents

Xin, Y., Suopajärvi, T., Mankinen, O., Mikola, M., Mikkelson, A., Ahola, J., Hiltunen, S., Komulainen, S., Kantola, A. M., Telkki, V., et al. (2020) · Journal of Agricultural and Food Chemistry · doi:10.1021/acs.jafc.0c04981 · Cited by 83

Combination of ultrasonication and deep eutectic solvent in pretreatment of lignocellulosic biomass for enhanced enzymatic saccharification

Lee, K. M., Hong, J. Y., & Tey, W. Y. (2021) · Cellulose · doi:10.1007/s10570-020-03598-5 · Cited by 83

Advances in green solvents for production of polysaccharide‐based packaging films: Insights of ionic liquids and deep eutectic solvents

Yu, J., Liu, X., Xu, S., Shao, P., Li, J., Chen, Z., Wang, X., Lin, Y., & Renard, C. M. G. C. (2022) · Comprehensive Reviews in Food Science and Food Safety · doi:10.1111/1541-4337.13099 · Cited by 87

Room temperature deep eutectic solvents of (1S)-(+)-10-camphorsulfonic acid and sulfobetaines: hydrogen bond-based mixtures with low ionicity and structure-dependent toxicity

Cardellini, F., Germani, R., Cardinali, G., Corte, L., Roscini, L., Spreti, N., & TIECCO, M. (2015) · RSC Advances · doi:10.1039/c5ra03932k · Cited by 81

Recent advances in bioethanol production from lignocelluloses: a comprehensive review with a focus on enzyme engineering and designer biocatalysts

Lugani, Y., Rai, R., Prabhu, A. A., Maan, P., Hans, M., Kumar, V., Kumar, S., Chandel, A. K., & Sengar, R. S. (2020) · Biofuel Research Journal · doi:10.18331/brj2020.7.4.5 · Cited by 80

Insights into alkaline choline chloride-based deep eutectic solvents pretreatment for Populus deltoides: Lignin structural features and modification mechanism

Li, H., Li, X., You, T., Li, D., Nawaz, H., Zhang, X., & Xu, F. (2021) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2021.10.134 · Cited by 79

Deep eutectic solvents for extraction of functional components from plant-based products: A promising approach

Bashir, I., Dar, A. H., Dash, K. K., Pandey, V. K., Fayaz, U., Shams, R., Srivastava, S., & Singh, R. (2023) · Sustainable Chemistry and Pharmacy · doi:10.1016/j.scp.2023.101102 · Cited by 81

Processing of lignin in urea–zinc chloride deep-eutectic solvent and its use as a filler in a phenol-formaldehyde resin

Lian, H., Hong, S., Carranza, A., Mota-Morales, J. D., & Pojman, J. A. (2015) · RSC Advances · doi:10.1039/c4ra16734a · Cited by 81

Integrated hydrothermal and deep eutectic solvent-mediated fractionation of lignocellulosic biocomponents for enhanced accessibility and efficient conversion in anaerobic digestion

Basak, B., Patil, S. M., Kumar, R., Ha, G.-S., Park, Y., Khan, M. A., Yadav, K. K., Fallatah, A. M., & Jeon, B. (2022) · Bioresource Technology · doi:10.1016/j.biortech.2022.127034 · Cited by 79

Emergence of deep eutectic solvents (DES): chemistry, preparation, properties, and applications in biorefineries and critical materials

Mani, K. A., Kumar, L., BARRIOS, N. A., Agate, S., Mittal, A., Yarbrough, J. M., Jameel, H., Lucia, L. A., & Pal, L. (2025) · Progress in Materials Science · doi:10.1016/j.pmatsci.2025.101586 · Cited by 87

Comparison of three deep eutectic solvents and 1-ethyl-3-methylimidazolium acetate in the pretreatment of lignocellulose: effect on enzyme stability, lignocellulose digestibility and one-pot hydrolysis

Wahlström, R., Hiltunen, J., Sirkka, M. P. D. S. N., Vuoti, S., & Kruus, K. (2016) · RSC Advances · doi:10.1039/c6ra11719h · Cited by 79

Structure and Properties of “Type IV” Lanthanide Nitrate Hydrate:Urea Deep Eutectic Solvents

Hammond, O. S., Bowron, D. T., & Edler, K. J. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b05548 · Cited by 78

Synergism of organic acid and deep eutectic solvents pretreatment for the co-production of oligosaccharides and enhancing enzymatic saccharification

Liu, X., Wei, W., & Wu, S. (2019) · Bioresource Technology · doi:10.1016/j.biortech.2019.121775 · Cited by 74

Temperature-switchable deep eutectic solvents for selective separation of aromatic amino acids in water

Xiong, D., Zhang, Q., Ma, W., Wang, Y., Wan, W., Shi, Y., & Wang, J. (2021) · Separation and Purification Technology · doi:10.1016/j.seppur.2021.118479 · Cited by 79

Chymotrypsin‐Catalyzed Peptide Synthesis in Deep Eutectic Solvents

Maugeri, Z., Leitner, W., & de María, P. D. (2013) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201300448 · Cited by 78

Basic deep eutectic solvents as reactant, template and solvents for ultra-fast preparation of transition metal oxide nanomaterials

Chen, J., Ali, M. C., Liu, R., Munyemana, J. C., Li, Z., Zhai, H., & Qiu, H. (2019) · Chinese Chemical Letters · doi:10.1016/j.cclet.2019.09.055 · Cited by 75

Effect of choline chloride-based deep eutectic solvents on polyphenols extraction from cocoa (Theobroma cacao L.) bean shells and antioxidant activity of extracts

Benítez‐Correa, E., Bastías‐Montes, J. M., Acuña, S., & Muñoz-Fariña, O. (2023) · Current Research in Food Science · doi:10.1016/j.crfs.2023.100614 · Cited by 76

A Review of Chitin Solvents and Their Dissolution Mechanisms

Zhong, Y., Cai, J., & Zhang, L. (2020) · Chinese Journal of Polymer Science · doi:10.1007/s10118-020-2459-x · Cited by 78

Mechanistic insights into the lignin dissolution behavior in amino acid based deep eutectic solvents

Zhang, Y., Ren, H., Li, B., Udin, S. M., Maarof, H., Zhou, W. Y., Cheng, F., Yang, J., Liu, Y., Alias, H., et al. (2023) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2023.124829 · Cited by 75

Studying Two Series of Ternary Deep Eutectic Solvents (Choline Chloride–Urea–Glycerol) and (Choline Chloride–Malic Acid–Glycerol), Synthesis and Characterizations

Kadhom, M. A., Abdullah, G. H., & Albayati, N. (2017) · Arabian Journal for Science and Engineering · doi:10.1007/s13369-017-2431-4 · Cited by 76

Natural Deep Eutectics as a “Green” Cellulose Cosolvent

Nguyen, H. V. D., de Vries, R. J., & Stoyanov, S. D. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.0c04982 · Cited by 74

Emulsion electro-oxidation of kraft lignin

Marino, D. D., Aniko, V., Stocco, A., Kriescher, S. M. A., & Weßling, M. (2017) · Green Chemistry · doi:10.1039/c7gc02115a · Cited by 73

Application of a computational model of natural deep eutectic solvents utilizing the COSMO-RS approach for screening of solvents with high solubility of rutin

Jeliński, T., & Cysewski, P. (2018) · Journal of Molecular Modeling · doi:10.1007/s00894-018-3700-1 · Cited by 73

A novel deep eutectic solvent from lignin-derived acids for improving the enzymatic digestibility of herbal residues from cellulose

Chen, L., Yu, Q., Wang, Q., Wang, W., Qi, W., Zhuang, X., Wang, Z., & Yuan, Z. (2018) · Cellulose · doi:10.1007/s10570-018-2190-8 · Cited by 78

Efficient extraction of chitin from crustacean waste via a novel ternary natural deep eutectic solvents

Wang, Y., Yang, Y., Wang, R., Zhu, Y., Yang, P., Lin, Z., Wang, Z., & Cong, W. (2022) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2022.119281 · Cited by 72

Integration of deep eutectic solvent in biorefining process of lignocellulosic biomass valorization

Jose, D., Tawai, A., Divakaran, D., Bhattacharyya, D., Venkatachalam, P., Tantayotai, P., & Sriariyanun, M. (2023) · Bioresource Technology Reports · doi:10.1016/j.biteb.2023.101365 · Cited by 80

Lignin Fractionation Methods: Can Lignin Fractions Be Separated in a True Industrial Process?

Rodrigues, J. S., de Lima, V. H., Araújo, L. C. P., & Botaro, V. R. (2021) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.1c01704 · Cited by 71

Sequential natural deep eutectic solvent pretreatments of apple pomace: A novel way to promote water extraction of pectin and to tailor its main structural domains

Chen, M., Falourd, X., & Lahaye, M. (2021) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2021.118113 · Cited by 72

Biomass valorization by integrating ultrasonication and deep eutectic solvents: Delignification, cellulose digestibility and solvent reuse

Lee, K. M., Quek, J. D., Tey, W. Y., Lim, S., Kang, H. S., Quen, L. K., Mahmood, W. A. W., Jamaludin, S. I. S., Teng, K. H., & Khoo, K. S. (2022) · Biochemical Engineering Journal · doi:10.1016/j.bej.2022.108587 · Cited by 74

Natural deep eutectic solvents in phytonutrient extraction and other applications

Li, D. (2022) · Frontiers in Plant Science · doi:10.3389/fpls.2022.1004332 · Cited by 82

Comparison of a low transition temperature mixture (LTTM) formed by lactic acid and choline chloride with choline lactate ionic liquid and the choline chloride salt: physical properties and vapour–liquid equilibria of mixtures containing water and ethanol

Francisco, M., González, A. S. B., Lago, S., Weggemans, W. M. A., & Kroon, M. C. (2013) · RSC Advances · doi:10.1039/c3ra40303c · Cited by 72

Synergistic behavior of betaine–urea mixture: Formation of deep eutectic solvent

Zeng, C., Qi, S., Xin, R., Yang, B., & Wang, Y. (2016) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2016.02.076 · Cited by 71

Catalytic Conversion of Biomass to Furanic Derivatives with Deep Eutectic Solvents

Chen, B., Peng, Z., Li, C., Feng, Y., Sun, Y. Q., Tang, X., Zeng, X., & Lin, L. (2021) · ChemSusChem · doi:10.1002/cssc.202100001 · Cited by 68

Deep Eutectic Solvents for Starch Treatment

Skowrońska, D., & Wilpiszewska, K. (2022) · Polymers · doi:10.3390/polym14020220 · Cited by 72

Methods to convert lignocellulosic waste into biohydrogen, biogas, bioethanol, biodiesel and value-added chemicals: a review

Dutta, N., Usman, M., Ashraf, M. A., Luo, G., El‐Din, M. G., & Zhang, S. (2022) · Environmental Chemistry Letters · doi:10.1007/s10311-022-01511-z · Cited by 70

New Lignin Streams Derived from Heteropoly Acids Enhanced Neutral Deep Eutectic Solvent Fractionation: Toward Structural Elucidation and Antioxidant Performance

Guo, Z., Li, D., You, T., Zhang, X., Xu, F., Zhang, X., & Yang, Y. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.0c03491 · Cited by 68

Glycerol-Based Deep Eutectic Solvents as Extractants for the Separation of MEK and Ethanol via Liquid–Liquid Extraction

Rodriguez, N. R., Guell, J. F., & Kroon, M. C. (2016) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.5b00717 · Cited by 66

High-efficiency and recyclable ramie cellulose fiber degumming enabled by deep eutectic solvent

Huang, H., Tang, Q., Lin, G., Yu, C., Wang, H., & Li, Z. (2021) · Industrial Crops and Products · doi:10.1016/j.indcrop.2021.113879 · Cited by 68

Optimization of lignin extraction by response surface methodology from sugarcane bagasse using deep eutectic solvents (DES)

Varilla-Mazaba, A., Raggazo-Sánchez, J. A., Calderón‐Santoyo, M., Rodríguez, J. G., & Aguilar‐Uscanga, M. G. (2022) · Industrial Crops and Products · doi:10.1016/j.indcrop.2022.115040 · Cited by 72

Preparation of homogeneous lignin nanoparticles by efficient extraction of lignin and modification of its molecular structure using a functional deep eutectic solvent containing γ-valerolactone

Yao, M., Liu, B., Qin, L., Du, Z., Wang, Z., Qin, C., Liang, C., Huang, C., & Yao, S. (2024) · Green Chemistry · doi:10.1039/d3gc04897g · Cited by 69

Deep eutectic solvents based on urea, polyols and sugars for starch treatment

Zdanowicz, M. (2021) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2021.02.039 · Cited by 67

Controlling the critical parameters of ultrasonication to affect the dispersion state, isolation, and chiral nematic assembly of cellulose nanocrystals

Nugroho, R. W. N., Tardy, B. L., Eldin, S. M., Ilyas, R. A., Mahardika, M., & Masruchin, N. (2023) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2023.106581 · Cited by 73

Recent Advances in Green and Efficient Cellulose Utilization Through Structure Deconstruction and Regeneration

Huang, C., Yu, H., Gao, Y., Chen, Y., Abdalkarim, S. Y. H., & Tam, K. C. (2025) · Advanced Functional Materials · doi:10.1002/adfm.202424591 · Cited by 66

Hydrothermal pretreatment optimization and deep eutectic solvent pretreatment of lignocellulosic biomass: An integrated approach

Gundupalli, M. P., Tantayotai, P., Panakkal, E. J., Chuetor, S., Kirdponpattara, S., Thomas, A. S. S., Sharma, B. K., & Sriariyanun, M. (2022) · Bioresource Technology Reports · doi:10.1016/j.biteb.2022.100957 · Cited by 65

Unveiling Modifications of Biomass Polysaccharides during Thermal Treatment in Cholinium Chloride : Lactic Acid Deep Eutectic Solvent

Morais, E. S., Lopes, A. M. D. C., Freire, M. G., Freire, C. S. R., & Silvestre, A. J. D. (2020) · ChemSusChem · doi:10.1002/cssc.202002301 · Cited by 65

Unveiling the potential of water as a co-solvent in microwave-assisted delignification of sugarcane bagasse using ternary deep eutectic solvents

Chourasia, V. R., Bisht, M., Pant, K. K., & Henry, R. J. (2022) · Bioresource Technology · doi:10.1016/j.biortech.2022.127005 · Cited by 64

A new era of chitin synthesis and dissolution using deep eutectic solvents- comparison with ionic liquids

Sulthan, R., Reghunadhan, A., & Sambhudevan, S. (2023) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2023.121794 · Cited by 68

Pandoraea sp. B-6 assists the deep eutectic solvent pretreatment of rice straw via promoting lignin depolymerization

Liu, D., Xu, Y., Zhuo, S., Si, M., Liu, M., Wang, S., Ren, L., Chai, L., & Shi, Y. (2018) · Bioresource Technology · doi:10.1016/j.biortech.2018.02.029 · Cited by 62

New generation of supramolecular mixtures: Characterization and solubilization studies

Achkar, T. E., Moura, L. M., Moufawad, T., Ruellan, S., Panda, S., Longuemart, S., Legrand, F., Gomes, M. C., Landy, D., Greige‐Gerges, H., et al. (2020) · International Journal of Pharmaceutics · doi:10.1016/j.ijpharm.2020.119443 · Cited by 65

Deep eutectic solvents in countercurrent and centrifugal partition chromatography

Roehrer, S., Bezold, F., García, E. M., & Minceva, M. (2016) · Journal of Chromatography A · doi:10.1016/j.chroma.2016.01.024 · Cited by 66

Hydrotropy and Cosolvency in Lignin Solubilization with Deep Eutectic Solvents

Soares, B., Silvestre, A. J. D., Pinto, P., Freire, C. S. R., & Coutinho, J. A. P. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.9b02109 · Cited by 65

Successive organic solvent fractionation and structural characterization of lignin extracted from hybrid poplar by deep eutectic solvent for improving the homogeneity and isolating narrow fractions

Song, Y., Ji, H., Shi, X., Yang, X., & Zhang, X. (2020) · Renewable Energy · doi:10.1016/j.renene.2020.04.159 · Cited by 60

Lightweight, High-Strength Wood Prepared by Deep Eutectic Solvent Treatment as a Green Structural Material

Fan, Z., Sun, H. Y., Zhang, L., Zhao, X., & Hu, Y. (2022) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.2c02606 · Cited by 61

Synthesis of a Novel Allyl-Functionalized Deep Eutectic Solvent to Promote Dissolution of Cellulose

Ren, H., Chen, C., Guo, S., Zhao, D., & Wang, Q. (2016) · BioResources · doi:10.15376/biores.11.4.8457-8469 · Cited by 61

Functionalization of carbon nanotubes using eutectic mixtures: A promising route for enhanced aqueous dispersibility and electrochemical activity

Abo-Hamad, A., Hayyan, M., Alsaadi, M. A., Mirghani, M. E. S., & Hashim, M. A. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.11.108 · Cited by 61

The use of NADES to support innovation in the cosmetic industry

Caprin, B., Charton, V., & Vogelgesang, B. (2020) · Advances in botanical research · doi:10.1016/bs.abr.2020.09.009 · Cited by 65

A Highly Transparent, Underwater Self-Healing, Self-Adhesive, and Recyclable Supramolecular Eutectogel for Liquid Metal Encapsulation

Zhang, H., Hu, Y., Liu, Z., Li, R., & Cao, Y. (2023) · ACS Materials Letters · doi:10.1021/acsmaterialslett.3c00555 · Cited by 60

Natural Deep Eutectic Solvents in Extraction Process

Owczarek, K., Szczepańska, N., Płotka‐Wasylka, J., Rutkowska, M., Shyshchak, O., Bratychak, M., & Namieśnik, J. (2016) · Chemistry & Chemical Technology · doi:10.23939/chcht10.04si.601 · Cited by 61

Technical assessment of natural deep eutectic solvent (NADES) mediated biorefinery process: A case study

Kumar, A. K., Sharma, S., Shah, E., & Patel, A. (2018) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2018.03.107 · Cited by 60

Thermoplastic starch with deep eutectic solvents and montmorillonite as a base for composite materials

Adamus, J., Spychaj, T., Zdanowicz, M., & Jędrzejewski, R. (2018) · Industrial Crops and Products · doi:10.1016/j.indcrop.2018.06.069 · Cited by 61

Extraction cellulose from corn-stalk taking advantage of pretreatment technology with immobilized enzyme

Lou, C., Zhou, Y., An, Y., & Liu, Y. (2022) · RSC Advances · doi:10.1039/d1ra07513f · Cited by 59

An eco-friendly strategy for preparing lignin nanoparticles by self-assembly: Characterization, stability, bioactivity, and Pickering emulsion

Zhang, W., Shen, J., Gao, P., Jiang, Q., & Xia, W. (2022) · Industrial Crops and Products · doi:10.1016/j.indcrop.2022.115651 · Cited by 59

Synthesis and characterization of green menthol-based low transition temperature mixture with tunable thermophysical properties as hydrophobic low viscosity solvent

Mat Hussin, S. A., Varanusupakul, P., Shahabuddin, S., Yih Hui, B., & Mohamad, S. (2020) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2020.113015 · Cited by 60

A review on deep eutectic solvents: Physiochemical properties and its application as an absorbent for sulfur dioxide

Chandran, K., Kait, C. F., Wilfred, C. D., & Zaid, H. F. M. (2021) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2021.117021 · Cited by 58

An Insight into Valorization of Lignocellulosic Biomass by Optimization with the Combination of Hydrothermal (HT) and Biological Techniques: A Review

Dutta, N., Usman, M., Luo, G., & Zhang, S. (2022) · Sustainable Chemistry · doi:10.3390/suschem3010003 · Cited by 60

Choline and lactic acid covalently incorporate into the lignin structure during deep eutectic solvent pulping

van Erven, G., Boerkamp, V. J. P., van Groenestijn, J. W., & Gosselink, R. J. A. (2024) · Green Chemistry · doi:10.1039/d4gc00909f · Cited by 58

Synthesis and Physical and Thermodynamic Properties of Lactic Acid and Malic Acid-Based Natural Deep Eutectic Solvents

Castro, V. I. B., Mano, F., Reis, R. L., Paiva, A., & Duarte, A. R. C. (2018) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.7b01037 · Cited by 64

Bringing Material Concepts into Conventional Biorefineries: Considerations of Sources, Preparations, and Applications of Lignin Nanomaterials

Yan, Z., Song, B., Fang, G., Wu, T., Chen, N., Zhao, M., Zou, X., & Liao, G. (2021) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.1c02954 · Cited by 57

Elucidating the Structure, Dynamics, and Interaction of a Choline Chloride and Citric Acid Based Eutectic System by Spectroscopic and Molecular Modeling Investigations

Ali, M., Kaium, M. A., Uddin, S. N., Uddin, M. J., Olawuyi, O., Campbell, A. D., Saint‐Louis, C. J., & Halim, M. A. (2023) · ACS Omega · doi:10.1021/acsomega.3c04570 · Cited by 60

Preparation and characterization of cotton fabrics with antibacterial properties treated by crosslinkable benzophenone derivative in choline chloride-based deep eutectic solvents

Park, J. H., Oh, K. W., & Choi, H. (2013) · Cellulose · doi:10.1007/s10570-013-9957-8 · Cited by 57

Mischungen mit niedriger Übergangstemperatur (LTTMs) – eine neue Generation von Designer‐Lösungsmitteln

Francisco, M., van den Bruinhorst, A., & Kroon, M. C. (2013) · Angewandte Chemie · doi:10.1002/ange.201207548 · Cited by 57

Sugar Alcohol-Based Deep Eutectic Solvents as Potato Starch Plasticizers

Zdanowicz, M., Staciwa, P., Jędrzejewski, R., & Spychaj, T. (2019) · Polymers · doi:10.3390/polym11091385 · Cited by 57

Production of lignin-containing nanocellulose from poplar using ternary deep eutectic solvents pretreatment

Shu, F., Guo, Y., Huang, L., Zhou, M., Zhang, G., Yu, H., Zhang, J., & Yang, F. (2021) · Industrial Crops and Products · doi:10.1016/j.indcrop.2021.114404 · Cited by 55

Experimental determination of the LLE data of systems consisting of {hexane + benzene + deep eutectic solvent} and prediction using the Conductor-like Screening Model for Real Solvents

Rodriguez, N. R., Gerlach, T. H., Scheepers, D., Kroon, M. C., & Smirnova, I. V. (2016) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2016.09.021 · Cited by 54

Comparing a deep eutectic solvent (DES) to a hydrotrope for their ability to enhance the fractionation and enzymatic hydrolysis of willow and corn stover

Song, Y., Chandra, R. P., Zhang, X., Tan, T., & Saddler, J. N. (2019) · Sustainable Energy & Fuels · doi:10.1039/c8se00617b · Cited by 55

A methanol–choline chloride based deep eutectic solvent enhances the catalytic oxidation of lignin into acetovanillone and acetic acid

Yu, Q., Song, Z., Chen, X., Fan, J., Clark, J. H., Wang, Z., Sun, Y., & Yuan, Z. (2020) · Green Chemistry · doi:10.1039/d0gc02189j · Cited by 55

Chitin biorefinery: A narrative and prophecy of crustacean shell waste sustainable transformation into bioactives and renewable energy

Kumari, R., Kumar, M., Vivekanand, V., & Pareek, N. (2023) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2023.113595 · Cited by 54

Experimental and Molecular Modeling Evaluation of the Physicochemical Properties of Proline-Based Deep Eutectic Solvents

van den Bruinhorst, A., Spyriouni, T., Hill, J., & Kroon, M. C. (2017) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.7b09540 · Cited by 56

Study on the Desulfurization and Regeneration Performance of Functional Deep Eutectic Solvents

Wang, B., Cheng, J. B., Wang, D., Li, X., Meng, Q., Zhang, Z., An, J., Liu, X., & Li, M. (2020) · ACS Omega · doi:10.1021/acsomega.0c01467 · Cited by 54

Choline chloride/urea as a deep eutectic solvent/organocatalyst promoted three-component synthesis of 3-aminoimidazo-fused heterocycles via Groebke–Blackburn–Bienayme process

Shaabani, A., & Hooshmand, S. E. (2015) · Tetrahedron Letters · doi:10.1016/j.tetlet.2015.12.014 · Cited by 54

Evaluation on the properties of deep eutectic solvent-extracted lignin for potential aromatic bio-products conversion

Tan, Y. T., Chua, A. S. M., & Ngoh, G. C. (2020) · Industrial Crops and Products · doi:10.1016/j.indcrop.2020.112729 · Cited by 53

Atypical Deep Eutectic Solvents: New Opportunities for Chemical Analysis

Shishov, A., El-Deen, A. K., Godunov, P., & Bulatov, A. (2024) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2024.117752 · Cited by 51

Natural low transition temperature mixtures (LTTMs) as novel solvents for lignocellulosic biomass

Bruinhorst, V. D. A., Schoep, D., Rodriguez, N. R., Molina, A. A. R., & Kroon, M. C. (2013)

Green solvent for lignocellulosic biomass pretreatment: An overview of the performance of low transition temperature mixtures for enhanced bio-conversion

Wong, J. L., Khadaroo, S. N. B. A., Cheng, J. L. Y., Chew, J. J., Khaerudini, D. S., & Sunarso, J. (2023) · Next Materials · doi:10.1016/j.nxmate.2023.100012 · Cited by 31

Characterization of natural low transition temperature mixtures (LTTMs): Green solvents for biomass delignification

Yiin, C. L., Quitain, A. T., Yusup, S. B., Sasaki, M., Uemura, Y., & Kida, T. (2015) · Bioresource Technology · doi:10.1016/j.biortech.2015.07.103 · Cited by 101

Processing lignocellulosic biomass with natural Low Transition Temperature Mixtures (LTTMs)

van den Bruinhorst, A. (2012) · TU/e Research Portal

NATURAL LOW TRANSITION TEMPERATURE MIXTURES (LTTMS) FORBIOMASS DELIGNIFICATION

Yiin, C. L. (2015)