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The importance of being porous: polysaccharide-derived mesoporous materials for use in dye adsorption
Abstract
The controlled pyrolysis of mesoporous polysaccharide-derived materials, from starch and alginic acid, formed carbonaceous materials (Starbons®) and were demonstrated as efficient materials for the removal of dyes from wastewater. The resulting materials were characterised by solid-state NMR, N2 adsorption porosimetry, FT-IR, scanning electron microscopy (SEM) and tunnelling electron microscopy (TEM). The material’s efficiency for dye adsorption was tested using methylene blue (MB) and acid blue 92 (AB) dyes. Adsorption data indicated that the mesoporosity of the material had a far greater influence on the adsorption capacity and speed of adsorption, than high surface area alone. Mesoporous Starbon® (A300) was evaluated against commercially available activated carbon (Norit) and demonstrated a superior adsorption capacity of MB; 186 mg g−1vs. 42 mg g−1. The kinetic activity of Starbon® was also determined with A800 showing the fastest rate of adsorption compared to S800 and Norit, suggesting that it is a more suitable material for water purification.
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Citations
Cites
Starbons: New Starch‐Derived Mesoporous Carbonaceous Materials with Tunable Properties
Budarin, V., Clark, J. H., Hardy, J. J. E., Luque, R., Milkowski, K., Tavener, S. J., & Wilson, A. J. (2006) · Angewandte Chemie · doi:10.1002/ange.200600460 · Cited by 255
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Cited by
Li, R., Wang, J. J., Zhou, B., Zhang, Z., Liu, S., Lei, S., & Xiao, R. (2017) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2017.01.069 · Cited by 486
Tran, H. N., Tomul, F., Thi Hoang Ha, N., Nguyen, D. T., Lima, E. C., Le, G. T., Chang, C.-T., Masindi, V., & Woo, S. H. (2020) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.122255 · Cited by 426
Bio-derived materials as a green route for precious & critical metal recovery and re-use
Dodson, J. R., Parker, H. L., Muñoz García, A., Hicken, A., Asemave, K., Farmer, T. J., He, H., Clark, J. H., & Hunt, A. J. (2015) · Green Chemistry · doi:10.1039/c4gc02483d · Cited by 278
Self-citationJeyasubramanian, K., Thangagiri, B., Sakthivel, A., Dhaveethu Raja, J., Seenivasan, S., Vallinayagam, P., Madhavan, D., Malathi Devi, S., & Rathika, B. (2021) · Fuel · doi:10.1016/j.fuel.2021.120243 · Cited by 197
Bhowmik, T., Kundu, M. K., & Barman, S. (2015) · RSC Advances · doi:10.1039/c5ra04913j · Cited by 132
Metadata
- Authors
- Parker, H. L., Hunt, A. J., Budarin, V. L., Shuttleworth, P. S., Miller, K. L., & Clark, J. H.
- Venue
- RSC Advances
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 2
- Issue
- 24
- Pages
- 8992
- ISSN
- 2046-2069 (ISSN-L)
- OpenAlex
- W2049362650
- Cited by
- 172
- References
- 1
- FWCI
- 10.18
- Type
- journal article
- Language
- en
- Open access
- closed
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