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Metallacyclohexatrienes or ‘metallabenzenes.’ Synthesis of osmabenzene derivatives and X-ray crystal structure of [Os(CSCHCHCHCH)(CO)(PPh3)2]
Abstract
The first metallabenzene,[O[graphic omitted]H)(CO)(PPh3)2] has been prepared from [Os(Co)(CS)(PPh3)3] and ethyen; X- ray crystal structure determination reveals a planar six-membered ring with no significant alternation of C–C bond lengths thus supporting the idea of electron delocalization within the ring.
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Citations
Cited by
All-Metal Aromaticity and Antiaromaticity
Boldyrev, A. I., & Wang, L.-S. (2005) · Chemical Reviews · doi:10.1021/cr030091t · Cited by 608
Recent Advances in Metallabenzene Chemistry
Landorf, C. W., & Haley, M. M. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200504358 · Cited by 295
Stabilization of anti-aromatic and strained five-membered rings with a transition metal
Zhu, C., Li, S., Luo, M., Zhou, X., Niu, Y., Lin, M., Zhu, J., Cao, Z., Lu, X., Wen, T., et al. (2013) · Nature Chemistry · doi:10.1038/nchem.1690 · Cited by 295
Solà, M., & Bickelhaupt, F. M. (2022) · Journal of Chemical Education · doi:10.1021/acs.jchemed.2c00523 · Cited by 21
Metadata
- Authors
- Elliott, G. P., Roper, W. R., & Waters, J. M.
- Venue
- J. Chem. Soc., Chem. Commun.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1982
- Issue
- 14
- Pages
- 811-813
- ISSN
- 0022-4936 (ISSN-L)
- OpenAlex
- W2149515824
- Cited by
- 282
- References
- 0
- FWCI
- 1.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Metallacyclohexatrienes or ‘metallabenzenes.’ Synthesis of osmabenzene derivatives and X-ray crystal structure of [Os(CSCHCHCHCH)(CO)(PPh3)2]. https://app.cochat.ai/papers/10.1039/c39820000811
- The paper
- Elliott, G. P., Roper, W. R., & Waters, J. M. (1982). Metallacyclohexatrienes or ‘metallabenzenes.’ Synthesis of osmabenzene derivatives and X-ray crystal structure of [Os(CSCHCHCHCH)(CO)(PPh3)2]. J. Chem. Soc., Chem. Commun. https://doi.org/10.1039/c39820000811
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
