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Electrochemical reduction of carbon dioxides to carbon monoxide at a gold electrode in aqueous potassium hydrogen carbonate
Abstract
CO2 is electrochemically reduced to CO in 0.5 M aqueous KHCO3 solution at a gold electrode at 18°C, the reaction proceeding with markedly low overvoltage, starting at –0.8 V vs. normal hydrogen electrode (N.H.E.); the faradaic efficiency for CO formation is 91% at –1.10 V vs. N.H.E. with a partial current of 3.7 mA cm–2, and the reaction probably proceeds via adsorbed intermediates.
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Cited by
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140
Self-citationActivity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO2 to CO
Zhu, W., Michalsky, R., Metin, Ö., Lv, H., Guo, S., Wright, C. J., Sun, X., Peterson, A. A., & Sun, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja409445p · Cited by 1,382
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Chen, L. D., Urushihara, M., Chan, K., & Nørskov, J. K. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02299 · Cited by 702
Metadata
- Authors
- Hori, Y., Murata, A., Kikuchi, K., & Suzuki, S.
- Venue
- Journal of the Chemical Society, Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1987
- Issue
- 10
- Pages
- 728
- ISSN
- 0022-4936 (ISSN-L)
- OpenAlex
- W2066894213
- Cited by
- 281
- References
- 0
- FWCI
- 1.18
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Electrochemical reduction of carbon dioxides to carbon monoxide at a gold electrode in aqueous potassium hydrogen carbonate. https://app.cochat.ai/papers/10.1039/c39870000728
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- Hori, Y., Murata, A., Kikuchi, K., & Suzuki, S. (1987). Electrochemical reduction of carbon dioxides to carbon monoxide at a gold electrode in aqueous potassium hydrogen carbonate. Journal of the Chemical Society, Chemical Communications. https://doi.org/10.1039/c39870000728
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.