Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Open accessAbstract
To date, copper is the only heterogeneous catalyst that has shown a propensity to produce valuable hydrocarbons and alcohols, such as ethylene and ethanol, from electrochemical CO2 reduction (CO2R). There are variety of factors that impact CO2R activity and selectivity, including the catalyst surface structure, morphology, composition, the choice of electrolyte ions and pH, and the electrochemical cell design. Many of these factors are often intertwined, which can complicate catalyst discovery and design efforts. Here we take a broad and historical view of these different aspects and their complex interplay in CO2R catalysis on Cu, with the purpose of providing new insights, critical evaluations, and guidance to the field with regard to research directions and best practices. First, we describe the various experimental probes and complementary theoretical methods that have been used to discern the mechanisms by which products are formed, and next we present our current understanding of the complex reaction networks for CO2R on Cu. We then analyze two key methods that have been used in attempts to alter the activity and selectivity of Cu: nanostructuring and the formation of bimetallic electrodes. Finally, we offer some perspectives on the future outlook for electrochemical CO2R.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Since pioneering works by Hori et al., massive efforts have been devoted to boost catalytic performance of electrochemical CO2RR, especially within the past decade.
“Since the pioneering works by Hori et al.,313,314 massive efforts have been devoted to boost the catalytic performance of electrochemical CO2RR, especially within the past decade.315, 316, 317, 318, 319, 320, 321”
From Technologies and perspectives for achieving carbon neutrality (2021) · cites this paper as [316]
Cites
Production, use, and fate of all plastics ever made
Geyer, R., Jambeck, J. R., & Law, K. L. (2017) · Science Advances · doi:10.1126/sciadv.1700782 · Cited by 18,606 · see citing works
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153 · see citing works
Self-citationCombining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114 · see citing works
Self-citationPowering the planet: Chemical challenges in solar energy utilization
Lewis, N. S., & Nocera, D. G. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0603395103 · Cited by 8,316 · see citing works
A comprehensive review on PEM water electrolysis
Carmo, M., Fritz, D., Mergel, J., & Stolten, D. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.01.151 · Cited by 5,588 · see citing works
THE INTERGOVERNMENTAL PANEL ON CLIMATE CHANGE
Shine, K. P. (1990) · Weather · doi:10.1002/j.1477-8696.1990.tb05660.x · Cited by 5,458 · see citing works
Electrochemical Energy Storage for Green Grid
Yang, Z. G., Zhang, J., Kintner-Meyer, M. C., Lu, X., Choi, D., Lemmon, J. P., & Liu, J. (2011) · Chemical Reviews · doi:10.1021/cr100290v · Cited by 5,251 · see citing works
Use of U.S. Croplands for Biofuels Increases Greenhouse Gases Through Emissions from Land-Use Change
Searchinger, T., Heimlich, R., Houghton, R. A., Dong, F., Elobeid, A., Fabiosa, J., Tokgoz, S., Hayes, D., & Yu, T.-H. (2008) · Science · doi:10.1126/science.1151861 · Cited by 4,888 · see citing works
Gasteiger, H. A., Kocha, S. S., Sompalli, B., & Wagner, F. T. (2005) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2004.06.021 · Cited by 4,876 · see citing works
The path towards sustainable energy
Chu, S., Cui, Y., & Liu, N. (2016) · Nature Materials · doi:10.1038/nmat4834 · Cited by 4,791 · see citing works
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784 · see citing works
Self-citationUllmann's Encyclopedia of Industrial Chemistry
(2000) · Wiley eBooks · doi:10.1002/14356007 · Cited by 3,601 · see citing works
Handbook of Chemistry and Physics.
Hodgman, C. D., & Lind, S. C. (1949) · The Journal of Physical Chemistry · doi:10.1021/j150472a018 · Cited by 3,581 · see citing works
Implicit solvation model for density-functional study of nanocrystal surfaces and reaction pathways
Mathew, K., Sundararaman, R., Letchworth-Weaver, K., Arias, T. A., & Hennig, R. G. (2014) · The Journal of Chemical Physics · doi:10.1063/1.4865107 · Cited by 3,196 · see citing works
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160 · see citing works
Self-citationA review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990 · see citing works
Renewable Power-to-Gas: A technological and economic review
Götz, M., Lefebvre, J., Mörs, F., Koch, A. M., Graf, F., Bajohr, S., Reimert, R., & Kolb, T. (2015) · Renewable Energy · doi:10.1016/j.renene.2015.07.066 · Cited by 2,587 · see citing works
Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515 · see citing works
Net-zero emissions energy systems
Davis, S. J., Lewis, N. S., Shaner, M., Aggarwal, S., Arent, D., Azevedo, I. L., Benson, S. M., Bradley, T., Brouwer, J., Chiang, Y.-M., et al. (2018) · Science · doi:10.1126/science.aas9793 · Cited by 2,391 · see citing works
Effect of Strain on the Reactivity of Metal Surfaces
Mavrikakis, M., Hammer, B., & Nørskov, J. K. (1998) · Physical Review Letters · doi:10.1103/physrevlett.81.2819 · Cited by 2,385 · see citing works
Self-citationAppel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193 · see citing works
Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide
Kortlever, R., Shen, J., Schouten, K. J. P., Calle‐Vallejo, F., & Koper, M. T. M. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01559 · Cited by 2,184 · see citing works
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140 · see citing works
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000 · see citing works
Electrochemical CO2 Reduction on Metal Electrodes
Hori, Y. (2008) · Springer eBooks · doi:10.1007/978-0-387-49489-0_3 · Cited by 1,904 · see citing works
Kondratenko, E. V., Mul, G., Baltrusaitis, J., Larrazábal, G. O., & Pérez-Ramírez, J. (2013) · Energy & Environmental Science · doi:10.1039/c3ee41272e · Cited by 1,802 · see citing works
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783 · see citing works
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728 · see citing works
Activity Descriptors for CO <sub>2</sub> Electroreduction to Methane on Transition-Metal Catalysts
Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667 · see citing works
Self-citationAqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
Chen, Y., Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309317u · Cited by 1,661 · see citing works
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649 · see citing works
Self-citationHori, Y., Murata, A., & Takahashi, R. (1989) · Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · doi:10.1039/f19898502309 · Cited by 1,644 · see citing works
General Techno-Economic Analysis of CO <sub>2</sub> Electrolysis Systems
Jouny, M., Luc, W., & Jiao, F. (2018) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b03514 · Cited by 1,628 · see citing works
Nitrogen Cycle Electrocatalysis
Roşca, V., Duca, M., de Groot, M. T., et al. (2009) · Chemical Reviews · doi:10.1021/cr8003696 · Cited by 1,609 · see citing works
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594 · see citing works
What Should We Make with CO2 and How Can We Make It?
Bushuyev, O. S., De Luna, P., Dinh, C. T., Tao, L., Saur, G., van de Lagemaat, J., Kelley, S. O., & Sargent, E. H. (2018) · Joule · doi:10.1016/j.joule.2017.09.003 · Cited by 1,593 · see citing works
Ionic Liquid–Mediated Selective Conversion of CO <sub>2</sub> to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558 · see citing works
CO Chemisorption at Metal Surfaces and Overlayers
Hammer, B., Morikawa, Y., & Nørskov, J. K. (1996) · Physical Review Letters · doi:10.1103/physrevlett.76.2141 · Cited by 1,499 · see citing works
Self-citationA review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper
Gattrell, M., Gupta, N., & Co, A. C. (2006) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2006.05.013 · Cited by 1,499 · see citing works
Kitchin, J. R., Nørskov, J. K., Barteau, M. A., & Chen, J. G. (2004) · Physical Review Letters · doi:10.1103/physrevlett.93.156801 · Cited by 1,491 · see citing works
Self-citationReview on methanation – From fundamentals to current projects
Rönsch, S., Schneider, J., Matthischke, S., Schlüter, M., Götz, M., Lefebvre, J., Prabhakaran, P., & Bajohr, S. (2015) · Fuel · doi:10.1016/j.fuel.2015.10.111 · Cited by 1,466 · see citing works
Particle Size Effects in the Catalytic Electroreduction of CO2 on Cu Nanoparticles
Reske, R., Mistry, H., Behafarid, F., Cuenya, B. R., & Strasser, P. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500328k · Cited by 1,435 · see citing works
Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption
Strmcnik, D., Uchimura, M., Wang, C., Subbaraman, R., Danilovic, N., van der Vliet, D., Paulikas, A. P., Stamenkovic, V. R., & Markovic, N. M. (2013) · Nature Chemistry · doi:10.1038/nchem.1574 · Cited by 1,426 · see citing works
Prospects of CO 2 Utilization via Direct Heterogeneous Electrochemical Reduction
Whipple, D. T., & Kenis, P. J. A. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1012627 · Cited by 1,419 · see citing works
Ullmann’s Encyclopedia of Industrial Chemistry
Gamble, A. (2019) · The Charleston Advisor · doi:10.5260/chara.20.4.46 · Cited by 1,417 · see citing works
Hori, Y., Kikuchi, K., & Suzuki, S. (1985) · Chemistry Letters · doi:10.1246/cl.1985.1695 · Cited by 1,401 · see citing works
Kim, D., Resasco, J., Yu, Y., Asiri, A. M., & Yang, P. (2014) · Nature Communications · doi:10.1038/ncomms5948 · Cited by 1,374 · see citing works
Kitchin, J. R., Nørskov, J. K., Barteau, M. A., & Chen, J. G. (2004) · The Journal of Chemical Physics · doi:10.1063/1.1737365 · Cited by 1,363 · see citing works
Self-citationThe irreversible momentum of clean energy
Obama, B. (2017) · Science · doi:10.1126/science.aam6284 · Cited by 1,238 · see citing works
Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide
Resasco, J., Chen, L. D., Clark, E. L., Tsai, C., Hahn, C., Jaramillo, T. F., Chan, K., & Bell, A. T. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b06765 · Cited by 1,199 · see citing works
Self-citationUnderstanding the electrocatalysis of oxygen reduction on platinum and its alloys
Stephens, I. E. L., Bandarenka, A. S., Vej-Hansen, U. G., Rossmeisl, J., & Chorkendorff, I. (2012) · Energy & Environmental Science · doi:10.1039/c2ee03590a · Cited by 1,179 · see citing works
Self-citationDopant-induced electron localization drives CO2 reduction to C2 hydrocarbons
Zhou, Y., Che, F., Liu, M., Zou, C., Liang, Z., De Luna, P., Yuan, H., Li, J., Wang, Z., Xie, H., et al. (2018) · Nature Chemistry · doi:10.1038/s41557-018-0092-x · Cited by 1,171 · see citing works
Balancing the Global Carbon Budget
Houghton, R. A. (2007) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev.earth.35.031306.140057 · Cited by 1,131 · see citing works
Electrochemical CO 2 Reduction: A Classification Problem
Bagger, A., Ju, W., Varela, A. S., Strasser, P., & Rossmeisl, J. (2017) · ChemPhysChem · doi:10.1002/cphc.201700736 · Cited by 1,075 · see citing works
Electrolytic CO2 Reduction in a Flow Cell
Weekes, D. M., Salvatore, D. A., Reyes, A., Huang, A., & Berlinguette, C. P. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00010 · Cited by 1,067 · see citing works
Sustainable hydrocarbon fuels by recycling CO 2 and H 2 O with renewable or nuclear energy
Graves, C., Ebbesen, S. D., Mogensen, M. B., & Lackner, K. S. (2010) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2010.07.014 · Cited by 1,058 · see citing works
De Luna, P., Quintero-Bermudez, R., Dinh, C.-T., Ross, M. B., Bushuyev, O. S., Todorović, P., Regier, T., Kelley, S. O., Yang, P., & Sargent, E. H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0018-9 · Cited by 1,046 · see citing works
The cost of CO2 capture and storage
Rubin, E. S., Davison, J. E., & Herzog, H. J. (2015) · International Journal of Greenhouse Gas Control · doi:10.1016/j.ijggc.2015.05.018 · Cited by 1,008 · see citing works
Singh, M. R., Kwon, Y., Lum, Y., Ager, J. W., & Bell, A. T. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07612 · Cited by 985 · see citing works
Schouten, K. J. P., Kwon, Y., van der Ham, C. J. M., Qin, Z., & Koper, M. T. M. (2011) · Chemical Science · doi:10.1039/c1sc00277e · Cited by 960 · see citing works
Feaster, J. T., Shi, C., Cave, E. R., Hatsukade, T., Abram, D. N., Kuhl, K. P., Hahn, C., Nørskov, J. K., & Jaramillo, T. F. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b00687 · Cited by 957 · see citing works
Self-citationCalle‐Vallejo, F., & Koper, M. T. M. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201301470 · Cited by 941 · see citing works
Mechanism of CO2 Reduction at Copper Surfaces: Pathways to C2 Products
Garza, A. J., Bell, A. T., & Head‐Gordon, M. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03477 · Cited by 940 · see citing works
Ren, D., Deng, Y., Handoko, A. D., Chen, C. S., Malkhandi, S., & Yeo, B. S. (2015) · ACS Catalysis · doi:10.1021/cs502128q · Cited by 930 · see citing works
Selectivity of CO 2 Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps
Nie, X., Esopi, M. R., Janik, M. J., & Asthagiri, A. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201208320 · Cited by 927 · see citing works
Design principles for hydrogen evolution reaction catalyst materials
Strmcnik, D. S., Lopes, P. P., Genorio, B., Stamenković, V. R., & Marković, N. M. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.04.017 · Cited by 921 · see citing works
Tran, K., & Ulissi, Z. W. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0142-1 · Cited by 920 · see citing works
Oxidation of Polycrystalline Copper Thin Films at Ambient Conditions
Platzman, I., Brener, R., Haick, H., & Tannenbaum, R. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp076981k · Cited by 919 · see citing works
Vasileff, A., Xu, C., Jiao, Y., Zheng, Y., & Qiao, S. (2018) · Chem · doi:10.1016/j.chempr.2018.05.001 · Cited by 902 · see citing works
Two Pathways for the Formation of Ethylene in CO Reduction on Single-Crystal Copper Electrodes
Schouten, K. J. P., Qin, Z., Pérez‐Gallent, E., & Koper, M. T. M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302668n · Cited by 898 · see citing works
Tailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction
Loiudice, A., Lobaccaro, P., Kamali, E. A., Thao, T., Huang, B. H., Ager, J. W., & Buonsanti, R. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201601582 · Cited by 896 · see citing works
Concepts of Modern Catalysis and Kinetics
Chorkendorff, I., & Niemantsverdriet, J. W. (2003) · Wiley eBooks · doi:10.1002/3527602658 · Cited by 874 · see citing works
Self-citationNanostructured electrocatalysts with tunable activity and selectivity
Mistry, H., Varela, A. S., Kühl, S., Strasser, P., & Cuenya, B. R. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.9 · Cited by 867 · see citing works
Theoretical Insights into a CO Dimerization Mechanism in CO 2 Electroreduction
Montoya, J. H., Shi, C., Chan, K., & Nørskov, J. K. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b00722 · Cited by 861 · see citing works
Self-citationZhu, S., Jiang, B., Cai, W., & Shao, M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10462 · Cited by 857 · see citing works
Ma, S., Sadakiyo, M., Heima, M., Luo, R., Haasch, R. T., Gold, J. I., Yamauchi, M., & Kenis, P. J. A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b10740 · Cited by 855 · see citing works
Hoang, T. T. H., Verma, S., Ma, S., Fister, T. T., Timoshenko, J., Frenkel, A. I., Kenis, P. J. A., & Gewirth, A. A. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b01868 · Cited by 852 · see citing works
Metal ion cycling of Cu foil for selective C–C coupling in electrochemical CO2 reduction
Jiang, K. P., Sandberg, R. B., Akey, A. J., Liu, X., Bell, D. C., Nørskov, J. K., Chan, K., & Wang, H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0009-x · Cited by 838 · see citing works
Self-citationHydrogénations et déshydrogénations par catalyse
Sabatier, P. (1911) · Berichte der deutschen chemischen Gesellschaft · doi:10.1002/cber.19110440303 · Cited by 827 · see citing works
Jhong, H. “., Ma, S., & Kenis, P. J. A. (2013) · Current Opinion in Chemical Engineering · doi:10.1016/j.coche.2013.03.005 · Cited by 824 · see citing works
Electrochemical Reduction of CO at a Copper Electrode
Hori, Y., Takahashi, R., Yoshinami, Y., & Murata, A. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp970284i · Cited by 818 · see citing works
Physical and chemical properties of bimetallic surfaces
Rodriguez, J. (1996) · Surface Science Reports · doi:10.1016/0167-5729(96)00004-0 · Cited by 812 · see citing works
Vesborg, P. C. K., & Jaramillo, T. F. (2012) · RSC Advances · doi:10.1039/c2ra20839c · Cited by 809 · see citing works
Self-citationUnderstanding trends in electrochemical carbon dioxide reduction rates
Liu, X., Xiao, J., Peng, H., Hong, X., Chan, K., & Nørskov, J. K. (2017) · Nature Communications · doi:10.1038/ncomms15438 · Cited by 805 · see citing works
Self-citationBeyond Oil and Gas: The Methanol Economy
Olah, G. A., Goeppert, A., & Prakash, G. K. S. (2009) · Wiley eBooks · doi:10.1002/9783527627806 · Cited by 792 · see citing works
Zhuang, T., Liang, Z., Seifitokaldani, A., Li, Y., Luna, P. D., Burdyny, T., Che, F., Meng, F., Min, Y., Quintero‐Bermudez, R., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0084-7 · Cited by 791 · see citing works
Role of Steps in N 2 Activation on Ru(0001)
Dahl, S., Logadóttir, Á., Egeberg, R. C., Larsen, J. H., Chorkendorff, I., Törnqvist, E., & Nørskov, J. K. (1999) · Physical Review Letters · doi:10.1103/physrevlett.83.1814 · Cited by 789 · see citing works
Self-citationImproved CO2 reduction activity towards C2+ alcohols on a tandem gold on copper electrocatalyst
Morales‐Guio, C. G., Cave, E. R., Nitopi, S. A., Feaster, J. T., Wang, L., Kuhl, K. P., Jackson, A., Johnson, N. C., Abram, D. N., Hatsukade, T., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0139-9 · Cited by 776 · see citing works
Self-citationThe role of non-covalent interactions in electrocatalytic fuel-cell reactions on platinum
Strmcnik, D. S., Kodama, K., van der Vliet, D., Greeley, J., Stamenković, V. R., & Marković, N. M. (2009) · Nature Chemistry · doi:10.1038/nchem.330 · Cited by 770 · see citing works
Robust carbon dioxide reduction on molybdenum disulphide edges
Asadi, M., Kumar, B., Behranginia, A., Rosen, B. A., Baskin, A., Repnin, N., Pisasale, D., Phillips, P., Zhu, W. D., Haasch, R. T., et al. (2014) · Nature Communications · doi:10.1038/ncomms5470 · Cited by 765 · see citing works
Electrochemical reduction of carbon dioxide at various series of copper single crystal electrodes
Hori, Y., Takahashi, I., Koga, O., & Hoshi, N. (2003) · Journal of Molecular Catalysis A Chemical · doi:10.1016/s1381-1169(03)00016-5 · Cited by 762 · see citing works
Metal‐Free Carbon Materials for CO<sub>2</sub> Electrochemical Reduction
Duan, X., Xu, J., Wei, Z., Ma, J., Guo, S., Wang, S., Liu, H., & Dou, S. (2017) · Advanced Materials · doi:10.1002/adma.201701784 · Cited by 754 · see citing works
Quéré, C. L., Moriarty, R., Andrew, R. M., Canadell, J. G., Sitch, S. A., Korsbakken, J. I., Friedlingstein, P., Peters, G. P., Andres, R. J., Boden, T. A., et al. (2015) · Earth system science data · doi:10.5194/essd-7-349-2015 · Cited by 740 · see citing works
Understanding heterogeneous electrocatalytic carbon dioxide reduction through operando techniques
Handoko, A. D., Wei, F., Jenndy, Yeo, B. S., & Seh, Z. W. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0182-6 · Cited by 739 · see citing works
Technological trends, global market, and challenges of bio-ethanol production
Mussatto, S. I., Dragone, G., Guimarães, P. M. R., Silva, J. P. A., Carneiro, L. M., Roberto, I. C., Vicente, A. A., Domingues, L., & Teixeira, J. A. (2010) · Biotechnology Advances · doi:10.1016/j.biotechadv.2010.07.001 · Cited by 730 · see citing works
Ren, D., Ang, B. S.-H., & Yeo, B. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02162 · Cited by 724 · see citing works
The Central Role of Bicarbonate in the Electrochemical Reduction of Carbon Dioxide on Gold
Dunwell, M., Lu, Q., Heyes, J., Rosen, J., Chen, J. G., Yan, Y. S., Jiao, F., & Xu, B. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b13287 · Cited by 706 · see citing works
Powering denitrification: the perspectives of electrocatalytic nitrate reduction
Duca, M., & Koper, M. T. M. (2012) · Energy & Environmental Science · doi:10.1039/c2ee23062c · Cited by 702 · see citing works
Goodpaster, J. D., Bell, A. T., & Head-Gordon, M. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00358 · Cited by 702 · see citing works
Electric Field Effects in Electrochemical CO <sub>2</sub> Reduction
Chen, L. D., Urushihara, M., Chan, K., & Nørskov, J. K. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02299 · Cited by 702 · see citing works
Self-citationTang, W., Peterson, A. A., Varela, A. S., Jovanov, Z. P., Bech, L., Durand, W. J., Dahl, S., Nørskov, J. K., & Chorkendorff, I. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp22700a · Cited by 691 · see citing works
Self-citationHuang, Y., Handoko, A. D., Hirunsit, P., & Yeo, B. S. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b03147 · Cited by 689 · see citing works
The kinetics of combination of carbon dioxide with hydroxide ions
Pinsent, B. R. W., Pearson, L., & Roughton, F. J. W. (1956) · Transactions of the Faraday Society · doi:10.1039/tf9565201512 · Cited by 688 · see citing works
Schmickler, W., & Santos, E. (2010) · Springer eBooks · doi:10.1007/978-3-642-04937-8 · Cited by 680 · see citing works
Hori, Y., Takahashi, I., Koga, O., & Hoshi, N. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp013478d · Cited by 679 · see citing works
Electrochemical Activation of CO2 through Atomic Ordering Transformations of AuCu Nanoparticles
Kim, D., Xie, C., Becknell, N., Yu, Y., Karamad, M., Chan, K., Crumlin, E. J., Nørskov, J. K., & Yang, P. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03516 · Cited by 677 · see citing works
Self-citationLi, Q., Fu, J., Zhu, W., Chen, Z., Shen, B., Wu, L., Xi, Z., Wang, T., Lü, G., Zhu, J., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00261 · Cited by 676 · see citing works
Clark, E. L., Hahn, C., Jaramillo, T. F., & Bell, A. T. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b08607 · Cited by 676 · see citing works
Self-citationCheng, T., Xiao, H. Y., & Goddard, W. A. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1612106114 · Cited by 675 · see citing works
Hori, Y., Kikuchi, K., Murata, A., & Suzuki, S. (1986) · Chemistry Letters · doi:10.1246/cl.1986.897 · Cited by 668 · see citing works
Verma, S., Kim, B., Jhong, H. “., Ma, S., & Kenis, P. J. A. (2016) · ChemSusChem · doi:10.1002/cssc.201600394 · Cited by 655 · see citing works
Theoretical Insights into Heterogeneous (Photo)electrochemical CO<sub>2</sub>Reduction
Xu, S., & Carter, E. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00481 · Cited by 652 · see citing works
Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts
Verdaguer-Casadevall, A., Li, C. W., Johansson, T. P., Scott, S. B., McKeown, J. T., Kumar, M., Stephens, I. E. L., Kanan, M. W., & Chorkendorff, I. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06227 · Cited by 645 · see citing works
Self-citationCopper nanoparticle ensembles for selective electroreduction of CO 2 to C 2 –C 3 products
Kim, D., Kley, C. S., Li, Y., & Yang, P. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1711493114 · Cited by 645 · see citing works
Catalytic hydrogenolysis and dehydrogenation over copper-nickel alloys
Sinfelt, J. H. (1972) · Journal of Catalysis · doi:10.1016/0021-9517(72)90072-3 · Cited by 641 · see citing works
Ma, M., Djanashvili, K., & Smith, W. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201601282 · Cited by 640 · see citing works
Catalytic carbon dioxide hydrogenation to methanol: A review of recent studies
Jadhav, S. G., Vaidya, P. D., Bhanage, B. M., & Joshi, J. B. (2014) · Process Safety and Environmental Protection · doi:10.1016/j.cherd.2014.03.005 · Cited by 637 · see citing works
Pérez‐Gallent, E., Figueiredo, M. C., Calle‐Vallejo, F., & Koper, M. T. M. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201700580 · Cited by 636 · see citing works
Enhancing CO2 Electroreduction with the Metal–Oxide Interface
Gao, D., Zhang, Y., Zhou, Z., Cai, F., Zhao, X., Huang, W., Li, Y., Zhu, J., Liu, P., Yang, F., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00102 · Cited by 610 · see citing works
Gas-Diffusion Electrodes for Carbon Dioxide Reduction: A New Paradigm
Higgins, D. C., Hahn, C., Xiang, C., Jaramillo, T. F., & Weber, A. Z. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b02035 · Cited by 609 · see citing works
Self-citationpH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper
Liu, X., Schlexer, P., Xiao, J., Ji, Y., Wang, L., Sandberg, R. B., Tang, M. T., Brown, K. S., Peng, H., Ringe, S., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-07970-9 · Cited by 609 · see citing works
Self-citationFundamental Concepts in Heterogeneous Catalysis
Nørskov, J. K., Studt, F., Abild‐Pedersen, F., & Bligaard, T. (2014) · Wiley eBooks · doi:10.1002/9781118892114 · Cited by 598 · see citing works
Self-citationFacet Dependence of CO 2 Reduction Paths on Cu Electrodes
Luo, W., Nie, X., Janik, M. J., & Asthagiri, A. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01967 · Cited by 587 · see citing works
The Mechanism of CO and CO 2 Hydrogenation to Methanol over Cu‐Based Catalysts
Studt, F., Behrens, M., Kunkes, E. L., Thomas, N., Zander, S., Tarasov, A., Schumann, J., Frei, E., Varley, J. B., Abild‐Pedersen, F., et al. (2015) · ChemCatChem · doi:10.1002/cctc.201500123 · Cited by 568 · see citing works
Self-citationOn the origin of the elusive first intermediate of CO 2 electroreduction
Chernyshova, I. V., Somasundaran, P., & Ponnurangam, S. (2018) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1802256115 · Cited by 564 · see citing works
Cu-based nanocatalysts for electrochemical reduction of CO2
Xie, H., Wang, T., Liang, J., Li, Q., & Sun, S. (2018) · Nano Today · doi:10.1016/j.nantod.2018.05.001 · Cited by 562 · see citing works
Gupta, N., Gattrell, M., & MacDougall, B. (2006) · Journal of Applied Electrochemistry · doi:10.1007/s10800-005-9058-y · Cited by 558 · see citing works
Lee, S. Y., Jung, H., Kim, N.-K., Oh, H., Min, B. K., & Hwang, Y. J. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b02173 · Cited by 557 · see citing works
Kaş, R., Kortlever, R., Milbrat, A., Koper, M. T. M., Mul, G., & Baltrušaitis, J. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp01520g · Cited by 550 · see citing works
Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
Manthiram, K., Beberwyck, B. J., & Alivisatos, A. P. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5065284 · Cited by 546 · see citing works
Murata, A., & Hori, Y. (1991) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.64.123 · Cited by 544 · see citing works
Varela, A. S., Kroschel, M., Reier, T., & Strasser, P. (2016) · Catalysis Today · doi:10.1016/j.cattod.2015.06.009 · Cited by 542 · see citing works
Xiao, H. Y., Cheng, T., Goddard, W. A., & Sundararaman, R. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b11390 · Cited by 527 · see citing works
Favaro, M., Xiao, H. Y., Cheng, T., Goddard, W. A., Yano, J., & Crumlin, E. J. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1701405114 · Cited by 519 · see citing works
High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
Roberts, F. S., Kuhl, K. P., & Nilsson, A. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201412214 · Cited by 517 · see citing works
Waugh, K. C. (1992) · Catalysis Today · doi:10.1016/0920-5861(92)80122-4 · Cited by 517 · see citing works
Rasul, S., Anjum, D. H., Jedidi, A., Minenkov, Y. V., Cavallo, L., & Takanabe, K. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201410233 · Cited by 514 · see citing works
Mechanistic Insights into the Reduction of CO2 on Tin Electrodes using in Situ ATR-IR Spectroscopy
Baruch, M. F., Pander, J. E., White, J. L., & Bocarsly, A. B. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00402 · Cited by 509 · see citing works
Nie, X., Luo, W., Janik, M. J., & Asthagiri, A. (2014) · Journal of Catalysis · doi:10.1016/j.jcat.2014.01.013 · Cited by 505 · see citing works
Mesostructure-Induced Selectivity in CO2 Reduction Catalysis
Hall, A. S., Yoon, Y., Wuttig, A., & Surendranath, Y. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08259 · Cited by 505 · see citing works
Spurgeon, J. M., & Kumar, B. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00097b · Cited by 505 · see citing works
A Highly Porous Copper Electrocatalyst for Carbon Dioxide Reduction
Lv, J., Jouny, M., Luc, W., Zhu, W., Zhu, J., & Jiao, F. (2018) · Advanced Materials · doi:10.1002/adma.201803111 · Cited by 499 · see citing works
High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
Roberts, F. S., Kuhl, K. P., & Nilsson, A. (2015) · Angewandte Chemie · doi:10.1002/ange.201412214 · Cited by 491 · see citing works
Electrochemical Reduction of CO2 to CH3OH at Copper Oxide Surfaces
Le, M., Ren, M.-Y., Zhang, Z., Sprunger, P. T., Kurtz, R. L., & Flake, J. C. (2011) · Journal of The Electrochemical Society · doi:10.1149/1.3561636 · Cited by 489 · see citing works
Varela, A. S., Ju, W., Reier, T., & Strasser, P. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02550 · Cited by 489 · see citing works
One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer
Ma, S., Sadakiyo, M., Luo, R., Heima, M., Yamauchi, M., & Kenis, P. J. A. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2015.09.124 · Cited by 488 · see citing works
Azuma, M., Hashimoto, K., Hiramoto, M., Watanabe, M., & Sakata, T. (1990) · Journal of The Electrochemical Society · doi:10.1149/1.2086796 · Cited by 482 · see citing works
Electrochemical Barriers Made Simple
Chan, K., & Nørskov, J. K. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01043 · Cited by 481 · see citing works
Self-citationTrends in electrochemical CO2 reduction activity for open and close-packed metal surfaces
Shi, C., Hansen, H. A., Lausche, A. C., & Nørskov, J. K. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp54822h · Cited by 465 · see citing works
Self-citationLi, Y., Cui, F., Ross, M. B., Kim, D., Sun, Y., & Yang, P. (2017) · Nano Letters · doi:10.1021/acs.nanolett.6b05287 · Cited by 465 · see citing works
Kas, R., Kortlever, R., Yılmaz, H., Koper, M. T. M., & Mul, G. (2015) · ChemElectroChem · doi:10.1002/celc.201402373 · Cited by 464 · see citing works
A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles
Feng, X., Jiang, K., Fan, S., & Kanan, M. W. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00022 · Cited by 460 · see citing works
Cu–Sn Bimetallic Catalyst for Selective Aqueous Electroreduction of CO 2 to CO
Sarfraz, S., Garcia‐Esparza, A. T., Jedidi, A., Cavallo, L., & Takanabe, K. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00269 · Cited by 460 · see citing works
Gao, D., Zegkinoglou, I., Divins, N. J., Scholten, F., Sinev, I., Grosse, P., & Cuenya, B. R. (2017) · ACS Nano · doi:10.1021/acsnano.7b01257 · Cited by 455 · see citing works
Dutta, A., Rahaman, M., Lüdi, N., Mohos, M., & Broekmann, P. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00770 · Cited by 453 · see citing works
Cheng, T., Xiao, H., & Goddard, W. A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08534 · Cited by 453 · see citing works
Wang, L., Nitopi, S. A., Bertheussen, E., Orazov, M., Morales‐Guio, C. G., Liu, X., Higgins, D. C., Chan, K., Nørskov, J. K., Hahn, C., et al. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01200 · Cited by 452 · see citing works
Self-citationSubsurface Oxygen in Oxide-Derived Copper Electrocatalysts for Carbon Dioxide Reduction
Eilert, A., Cavalca, F., Roberts, F. S., Osterwalder, J., Liu, C., Favaro, M., Crumlin, E. J., Ogasawara, H., Friebel, D., Pettersson, L. G. M., et al. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02273 · Cited by 443 · see citing works
Insights into CC Coupling in CO 2 Electroreduction on Copper Electrodes
Montoya, J. H., Peterson, A. A., & Nørskov, J. K. (2013) · ChemCatChem · doi:10.1002/cctc.201200564 · Cited by 435 · see citing works
Self-citation“Deactivation of copper electrode” in electrochemical reduction of CO2
Hori, Y., Konishi, H., Futamura, T., Murata, A., Koga, O., Sakurai, H., & Oguma, K. (2005) · Electrochimica Acta · doi:10.1016/j.electacta.2005.03.015 · Cited by 432 · see citing works
Grosse, P., Gao, D., Scholten, F., Sinev, I. V., Mistry, H., & Cuenya, B. R. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201802083 · Cited by 430 · see citing works
Machine-Learning-Augmented Chemisorption Model for CO2 Electroreduction Catalyst Screening
Ma, X., Li, Z., Achenie, L. E. K., & Xin, H. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01660 · Cited by 422 · see citing works
Ooka, H., Figueiredo, M. C., & Koper, M. T. M. (2017) · Langmuir · doi:10.1021/acs.langmuir.7b00696 · Cited by 421 · see citing works
Singh, M. R., Clark, E. L., & Bell, A. T. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp03283k · Cited by 416 · see citing works
Inhibited proton transfer enhances Au-catalyzed CO 2 -to-fuels selectivity
Wuttig, A., Yaguchi, M., Motobayashi, K., Osawa, M., & Surendranath, Y. (2016) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1602984113 · Cited by 416 · see citing works
Pérez‐Gallent, E., Marcandalli, G., Figueiredo, M. C., Calle‐Vallejo, F., & Koper, M. T. M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10142 · Cited by 412 · see citing works
Hahn, C., Hatsukade, T., Kim, Y.-G., Vailionis, A., Baricuatro, J. H., Higgins, D. C., Nitopi, S. A., Soriaga, M. P., & Jaramillo, T. F. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1618935114 · Cited by 410 · see citing works
Self-citationLum, Y., & Ager, J. W. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710590 · Cited by 410 · see citing works
The influence of pH on the reduction of CO and CO2 to hydrocarbons on copper electrodes
Schouten, K. J. P., Pérez‐Gallent, E., & Koper, M. T. M. (2013) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2013.08.033 · Cited by 402 · see citing works
Effect of Substrate Strain on Adsorption
Gsell, M., Jakob, P., & MENZEL, D. (1998) · Science · doi:10.1126/science.280.5364.717 · Cited by 396 · see citing works
Highly Dense Cu Nanowires for Low-Overpotential CO <sub>2</sub> Reduction
Raciti, D., Livi, K. J., & Wang, C. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b03298 · Cited by 395 · see citing works
Lee, S., Park, G., & Lee, J. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b02822 · Cited by 391 · see citing works
Ulissi, Z. W., Tang, M. T., Xiao, J., Liu, X., Torelli, D. A., Karamad, M., Cummins, K., Hahn, C., Lewis, N. S., Jaramillo, T. F., et al. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01648 · Cited by 387 · see citing works
Self-citationRecent Advances in CO 2 Reduction Electrocatalysis on Copper
Raciti, D., & Wang, C. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00553 · Cited by 384 · see citing works
Continuous-flow electroreduction of carbon dioxide
Endrődi, B., Bencsik, G., Darvas, F., Jones, R. V., Rajeshwar, K., & Janáky, C. (2017) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2017.05.005 · Cited by 383 · see citing works
Activation of Cu(111) surface by decomposition into nanoclusters driven by CO adsorption
Eren, B., Zherebetskyy, D., Patera, L. L., Wu, C., Bluhm, H., Africh, C., Wang, L., Somorjai, G. A., & Salmerón, M. (2016) · Science · doi:10.1126/science.aad8868 · Cited by 381 · see citing works
Hydrogen Evolution Reaction on Copper, Gold, Molybdenum, Palladium, Rhodium, and Iron
Pentland, N., Bockris, J. O., & Sheldon, E. M. (1957) · Journal of The Electrochemical Society · doi:10.1149/1.2428530 · Cited by 374 · see citing works
DeWulf, D. W., Jin, T., & Bard, A. J. (1989) · Journal of The Electrochemical Society · doi:10.1149/1.2096993 · Cited by 372 · see citing works
Structure Sensitivity of the Electrochemical Reduction of Carbon Monoxide on Copper Single Crystals
Schouten, K. J. P., Gallent, E. P., & Koper, M. T. M. (2013) · ACS Catalysis · doi:10.1021/cs4002404 · Cited by 367 · see citing works
Kaş, R., Hummadi, K. K., Kortlever, R., de Wit, P., Milbrat, A., Luiten-Olieman, M. W. J., Benes, N. E., Koper, M. T. M., & Mul, G. (2016) · Nature Communications · doi:10.1038/ncomms10748 · Cited by 366 · see citing works
Clark, E. L., Resasco, J., Landers, A. T., Lin, J. C., Chung, L.-T., Walton, A., Hahn, C., Jaramillo, T. F., & Bell, A. T. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01340 · Cited by 355 · see citing works
Self-citationEffect of Cations on the Electrochemical Conversion of CO2to CO
Thorson, M. R., Siil, K. I., & Kenis, P. J. A. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.052301jes · Cited by 354 · see citing works
Hori, Y., Murata, A., Takahashi, R., & Suzuki, S. (1987) · Journal of the American Chemical Society · doi:10.1021/ja00250a044 · Cited by 354 · see citing works
Morphology‐Directed Selective Production of Ethylene or Ethane from CO2 on a Cu Mesopore Electrode
Yang, K. D., Ko, W. R., Lee, J., Kim, S. J., Lee, H., Lee, M. H., & Nam, K. T. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201610432 · Cited by 354 · see citing works
Stable and selective electrochemical reduction of carbon dioxide to ethylene on copper mesocrystals
Chen, C. S., Handoko, A. D., Wan, J. H., Ma, L., Ren, D., & Yeo, B. S. (2014) · Catalysis Science & Technology · doi:10.1039/c4cy00906a · Cited by 348 · see citing works
Optimizing C–C Coupling on Oxide-Derived Copper Catalysts for Electrochemical CO2 Reduction
Lum, Y., Yue, B., Lobaccaro, P., Bell, A. T., & Ager, J. W. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b03673 · Cited by 347 · see citing works
CO-CO coupling on Cu facets: Coverage, strain and field effects
Sandberg, R. B., Montoya, J. H., Chan, K., & Nørskov, J. K. (2016) · Surface Science · doi:10.1016/j.susc.2016.08.006 · Cited by 344 · see citing works
Self-citationGunathunge, C. M., Li, X., Li, J., et al. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b03910 · Cited by 342 · see citing works
Structure- and Electrolyte-Sensitivity in CO 2 Electroreduction
Arán‐Ais, R. M., Gao, D., & Cuenya, B. R. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00360 · Cited by 341 · see citing works
Gao, D., Scholten, F., & Cuenya, B. R. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01416 · Cited by 340 · see citing works
Kling, M. F., & Vrakking, M. J. J. (2007) · Annual Review of Physical Chemistry · doi:10.1146/annurev.physchem.59.032607.093532 · Cited by 334 · see citing works
Kim, Y.-G., Baricuatro, J. H., Javier, A. C., Gregoire, J. M., & Soriaga, M. P. (2014) · Langmuir · doi:10.1021/la504445g · Cited by 323 · see citing works
Potential Dependence of Electrochemical Barriers from ab Initio Calculations
Chan, K., & Nørskov, J. K. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00382 · Cited by 323 · see citing works
Self-citationKarlberg, G. S., Rossmeisl, J., & Nørskov, J. K. (2007) · Physical Chemistry Chemical Physics · doi:10.1039/b705938h · Cited by 322 · see citing works
Self-citationElectrocatalytic Alloys for CO2 Reduction
He, J., Johnson, N. J. J., Huang, A., & Berlinguette, C. P. (2017) · ChemSusChem · doi:10.1002/cssc.201701825 · Cited by 321 · see citing works
Lee, S., Kim, D., & Lee, J. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201505730 · Cited by 320 · see citing works
CO2 Electroreduction to Hydrocarbons on Carbon-Supported Cu Nanoparticles
Baturina, O. A., Lu, Q., Padilla, M. A., Xin, L., Li, W., Serov, A., Artyushkova, K., Atanassov, P. B., Xu, F., Epshteyn, A., et al. (2014) · ACS Catalysis · doi:10.1021/cs500537y · Cited by 320 · see citing works
Ren, D., Fong, J., & Yeo, B. S. (2018) · Nature Communications · doi:10.1038/s41467-018-03286-w · Cited by 319 · see citing works
Tracking a Common Surface-Bound Intermediate during CO 2 -to-Fuels Catalysis
Wuttig, A., Liu, C., Peng, Q., Yaguchi, M., Hendon, C. H., Motobayashi, K., Ye, S., Osawa, M., & Surendranath, Y. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00155 · Cited by 318 · see citing works
Existence of an Electrochemically Inert CO Population on Cu Electrodes in Alkaline pH
Gunathunge, C. M., Ovalle, V. J., Li, Y., Janik, M. J., & Waegele, M. M. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01552 · Cited by 317 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Ma, W., Xie, S., Liu, T., Fan, Q., Ye, J., Sun, F., Jiang, Z., Zhang, Q., Cheng, J., & Wang, Y. (2020) · Nature Catalysis · doi:10.1038/s41929-020-0450-0 · Cited by 1,468 · see citing works
Technologies and perspectives for achieving carbon neutrality
Wang, F., Harindintwali, J. D., Yuan, Z., Wang, M., Wang, F., Li, S., Yin, Z., Huang, L., Fu, Y., Li, L., et al. (2021) · The Innovation · doi:10.1016/j.xinn.2021.100180 · Cited by 1,330 · see citing works
Self-citationElectrocatalysis for CO <sub>2</sub> conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295 · see citing works
High-entropy alloys in electrocatalysis: from fundamentals to applications
Ren, J.-T., Chen, L., Wang, H.-Y., & Yuan, Z.-Y. (2023) · Chemical Society Reviews · doi:10.1039/d3cs00557g · Cited by 551 · see citing works
Impacts of the Catalyst Structures on CO2 Activation on Catalyst Surfaces
Etim, U. J., Zhang, C., & Zhong, Z. (2021) · Nanomaterials · doi:10.3390/nano11123265 · Cited by 175 · see citing works
Advanced manufacturing for electrosynthesis of fuels and chemicals from CO <sub>2</sub>
Corral, D., Feaster, J. T., Sobhani, S., DeOtte, J. R., Lee, D. U., Wong, A. A., Hamilton, J., Beck, V. A., Sarkar, A., Hahn, C., et al. (2021) · Energy & Environmental Science · doi:10.1039/d0ee03679j · Cited by 98 · see citing works
Self-citationInfluencing electrocatalytic processes through topographically disordered atomic sites
Prabhu, P., & Lee, J.-M. (2023) · Chem Catalysis · doi:10.1016/j.checat.2023.100621 · Cited by 84 · see citing works
Kim, J. Y., Hong, W. T., Phu, T. K. C., Cho, S. C., Kim, B., Baeck, U., Oh, H., Koh, J. H., Yu, X., Choi, C. H., et al. (2024) · Advanced Science · doi:10.1002/advs.202405154 · Cited by 41 · see citing works
Chen, H., Fu, W., Geng, Z., Zeng, J., & Yang, B. (2021) · Journal of Materials Chemistry A · doi:10.1039/d0ta11295j · Cited by 25 · see citing works
Vinayakumar, K., Palliyarayil, A., Kumar, N. S., & Sil, S. (2022) · Environmental Science and Pollution Research · doi:10.1007/s11356-022-20355-2 · Cited by 17 · see citing works
Wang, X., Li, Z., Zhang, D., Li, H., Xu, H., & Cheng, D. (2026) · Angewandte Chemie International Edition · doi:10.1002/anie.202524612 · Cited by 18 · see citing works
- Authors
- Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., Nørskov, J. K., Jaramillo, T. F., & Chorkendorff, I.
- Affiliations
- Stanford University (US)
- Technical University of Denmark (DK)
- Technical University of Denmark , , ,
- Universität Ulm (DE)
- Imperial College London (GB)
- SLAC National Accelerator Laboratory (US)
- Corresponding author
- Nørskov, Jens K.
- Jaramillo, Thomas F.
- Chorkendorff, Ib
- ORCID
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-05-22
- Volume
- 119
- Issue
- 12
- Pages
- 7610-7672
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2947264857
- Cited by
- 5,223
- References
- 411
- Citations by year
- 2026: 814 · 2025: 920 · 2024: 970 · 2023: 866 · 2022: 702 · 2021: 577 · 2020: 327 · 2019: 47
- FWCI
- 16.04
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Chemical Reviews (publishedVersion, other-oa)
- PubMed (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Technical University of Denmark, DTU Orbit (Technical University of Denmark, DTU) (submittedVersion, other-oa)
- Funders
- Office of Science (DE-SC0004993)
- Villum Fonden (9455)
- Innovationsfonden (8057-00018B)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electrochemical CO2 reduction, copper catalysts, aqueous electrolyte solutions, ethylene production, ethanol production, reaction mechanism, reaction networks, bimetallic electrodes, catalyst surface structure, electrolyte ions, pH effect, cell design, selectivity
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review