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Stable carbenes as strong bases
Abstract
The stable carbene 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene has a pKa of 24 in (CD3)2SO and gives an elimination:substitution ratio with 2-bromopropane comparable to that of 1,5-diazabicyclo[4.3.0]non-5-ene (DBN).
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Citations
Cited by
Organocatalytic Ring-Opening Polymerization
Kamber, N. E., Jeong, W., Waymouth, R. M., Pratt, R. C., Lohmeijer, B. G. G., & Hedrick, J. L. (2007) · Chemical Reviews · doi:10.1021/cr068415b · Cited by 1,489
Organocatalysis: Opportunities and Challenges for Polymer Synthesis
Kiesewetter, M. K., Shin, E. J., Hedrick, J. L., & Waymouth, R. M. (2010) · Macromolecules · doi:10.1021/ma9025948 · Cited by 907
Stability of superoxide ion in imidazolium cation-based room-temperature ionic liquids
Islam, M. M., Imase, T., Okajima, T., Takahashi, M., Niikura, Y., Kawashima, N., Nakamura, Y., & Ohsaka, T. (2009) · The Journal of Physical Chemistry A · doi:10.1021/jp807541z · Cited by 85
Metadata
- Authors
- Alder, R. W., Allen, P. R., & Williams, S. J.
- Venue
- Journal of the Chemical Society, Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1995
- Issue
- 12
- Pages
- 1267
- ISSN
- 0022-4936 (ISSN-L)
- OpenAlex
- W2053543808
- Cited by
- 283
- References
- 0
- FWCI
- 5.14
- Type
- journal article
- Language
- en
- Open access
- closed
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How to cite
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- CoChat. (2026). Citation check: Stable carbenes as strong bases. https://app.cochat.ai/papers/10.1039/c39950001267
- The paper
- Alder, R. W., Allen, P. R., & Williams, S. J. (1995). Stable carbenes as strong bases. Journal of the Chemical Society, Chemical Communications. https://doi.org/10.1039/c39950001267
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
