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Fluorescence spectroscopy and multi-way techniques. PARAFAC

Open access
Murphy, Kathleen R., Stedmon, Colin A., Graeber, Daniel, Bro, Rasmus·2013·Analytical Methods

Abstract

PARAllel FACtor analysis (PARAFAC) is increasingly used to decompose fluorescence excitation emission matrices (EEMs) into their underlying chemical components. In the ideal case where fluorescence conforms to Beers Law, this process can lead to the mathematical identification and quantification of independently varying fluorophores. However, many practical and analytical hurdles stand between EEM datasets and their chemical interpretation. This article provides a tutorial in the practical application of PARAFAC to fluorescence datasets, demonstrated using a dissolved organic matter (DOM) fluorescence dataset. A new toolbox for MATLAB is presented to support improved visualisation and sensitivity analyses of PARAFAC models in fluorescence spectroscopy.

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Metadata

Authors
Murphy, K. R., Stedmon, C. A., Graeber, D., & Bro, R.
Venue
Analytical Methods
Published
2013
Volume
5
Issue
23
Pages
6557
ISSN
  • 1759-9660 (ISSN-L)
  • 1759-9679
OpenAlex
W2157382843
Cited by
2,060
References
1
FWCI
14.07
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Fluorescence spectroscopy and multi-way techniques. PARAFAC. https://app.cochat.ai/papers/10.1039/c3ay41160e
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Murphy, K. R., Stedmon, C. A., Graeber, D., & Bro, R. (2013). Fluorescence spectroscopy and multi-way techniques. PARAFAC. Analytical Methods. https://doi.org/10.1039/c3ay41160e

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