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Fluorescence spectroscopy and multi-way techniques. PARAFAC
Open accessAbstract
PARAllel FACtor analysis (PARAFAC) is increasingly used to decompose fluorescence excitation emission matrices (EEMs) into their underlying chemical components. In the ideal case where fluorescence conforms to Beers Law, this process can lead to the mathematical identification and quantification of independently varying fluorophores. However, many practical and analytical hurdles stand between EEM datasets and their chemical interpretation. This article provides a tutorial in the practical application of PARAFAC to fluorescence datasets, demonstrated using a dissolved organic matter (DOM) fluorescence dataset. A new toolbox for MATLAB is presented to support improved visualisation and sensitivity analyses of PARAFAC models in fluorescence spectroscopy.
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Cites
Pseudoreplication and the Design of Ecological Field Experiments
Hurlbert, S. H. (1984) · Ecological Monographs · doi:10.2307/1942661 · Cited by 8,377
Cited by
Lee, Y. K., Murphy, K. R., & Hur, J. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.0c00942 · Cited by 380
Self-citationBiochar affects carbon composition and stability in soil: a combined spectroscopy-microscopy study
Hernandez-Soriano, M. C., Kerré, B., Kopittke, P. M., Horemans, B., & Smolders, E. (2016) · Scientific Reports · doi:10.1038/srep25127 · Cited by 123
Fluorescence Spectroscopy and Chemometric Modeling for Bioprocess Monitoring
Faassen, S., & Hitzmann, B. (2015) · Sensors · doi:10.3390/s150510271 · Cited by 120
Liu, Y., Ye, Q., Huang, W.-L., Feng, L., Wang, Y.-H., Xie, Z., Yong, S.-S., Zhang, S., Jiang, B., Zheng, Y., et al. (2020) · Science of The Total Environment · doi:10.1016/j.scitotenv.2019.136307 · Cited by 75
The Analytical Possibilities of FT-IR Spectroscopy Powered by Vibrating Molecules
Koczoń, P., Hołaj-Krzak, J. T., Palani, B. K., Bolewski, T., Dąbrowski, J., Bartyzel, B. J., & Gruczyńska-Sękowska, E. (2023) · International Journal of Molecular Sciences · doi:10.3390/ijms24021013 · Cited by 62
Metadata
- Authors
- Murphy, K. R., Stedmon, C. A., Graeber, D., & Bro, R.
- Venue
- Analytical Methods
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 5
- Issue
- 23
- Pages
- 6557
- ISSN
- 1759-9660 (ISSN-L)
- 1759-9679
- OpenAlex
- W2157382843
- Cited by
- 2,060
- References
- 1
- FWCI
- 14.07
- Type
- journal article
- Language
- en
- Open access
- hybrid
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