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Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts

Chen, Wei-Fu, Muckerman, James T., Fujita, Etsuko·2013·Chemical Communications

Abstract

The production of hydrogen by the electrolysis of water, a sustainable and greenhouse-gas-free source, requires an efficient and abundant electrocatalyst that minimizes energy consumption. Interest in transition metal carbides and nitrides has been aroused by their promising properties that make them potential substitutes for Pt-group metals as catalysts for the hydrogen evolution reaction. In this review, we discuss systematically the recent progress in the development of group IV-VI metal carbides and nitrides toward the hydrogen evolution reaction. Some strategies for designing such catalysts and improving their efficiency and reliability, including nanostructuring, optimizing hydrogen binding energy, interaction with the supporting material, and exploiting hybrid structures, are highlighted. We conclude with an outlook on the challenges in designing future HER electrocatalysts.

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Metadata

Authors
Chen, W.-F., Muckerman, J. T., & Fujita, E.
Venue
Chemical Communications
Published
2013
Volume
49
Issue
79
Pages
8896
ISSN
  • 1359-7345 (ISSN-L)
  • 1364-548X
OpenAlex
W2130789799
Cited by
1,179
References
5
FWCI
31.02
Type
journal article
Language
en
Open access
closed

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