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Facile solution synthesis of Ag@Pt core–shell nanoparticles with dendritic Pt shells
Abstract
Ag@Pt nanoparticles with various dendritic Pt shells were successfully synthesized by using nonionic surfactants at room temperature. Our recent study demonstrated that the addition of nonionic surfactant plays an important key role in the synthesis of dendritic Pt nanostructures (J. Am. Chem. Soc., 2010, 132, 13636). Here we extend this synthetic concept to prepare various Ag@Pt nanoarchitectures. The different nanostructured Pt shells on the Ag core were confirmed by ultraviolet-visible absorption spectroscopy and transmission electron microscopy. As a preliminary electrochemical application, the obtained Ag@Pt nanostructures were applied in the methanol oxidation reaction (MOR) in 0.5 M H(2)SO(4) solution containing 0.5 M methanol. The Ag@Pt nanoparticles with thin dendritic Pt shells show superior CO-tolerance performance with a I(f)/I(b) value reaching 3.71. Our Ag@Pt nanostructures with good CO tolerant activity will be prominent catalysts for MOR.
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Opportunities and challenges for a sustainable energy future
Chu, S., & Majumdar, A. (2012) · Nature · doi:10.1038/nature11475 · Cited by 12,550
Wang, L., Nemoto, Y., & Yamauchi, Y. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202655j · Cited by 524
Self-citationGhosh, T., Vukmirovic, M. B., DiSalvo, F. J., & Adzic, R. R. (2010) · Journal of the American Chemical Society · doi:10.1021/ja905850c · Cited by 141
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Crystal phase-controlled synthesis, properties and applications of noble metal nanomaterials
Fan, Z., & Zhang, H. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00467e · Cited by 406
Li, M., Jiang, Q., Yan, M., Wei, Y., Zong, J., Zhang, J., Wu, Y., & Huang, H. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b00425 · Cited by 95
Du, L., Zhang, S., Chen, G., Yin, G., Du, C., Tan, Q., Sun, Y., Qu, Y., & Gao, Y. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am503372f · Cited by 52
Metadata
- Authors
- Li, C., & Yamauchi, Y.
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 15
- Issue
- 10
- Pages
- 3490
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2075191177
- Cited by
- 169
- References
- 3
- FWCI
- 10.70
- Type
- journal article
- Language
- en
- Open access
- closed
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