Three-Dimensional Boron- and Nitrogen-Codoped Graphene Aerogel-Supported Pt Nanoparticles as Highly Active Electrocatalysts for Methanol Oxidation Reaction
Abstract
Although direct methanol fuel cells have long been regarded as promising “green” power generators for portable electronics, their further development has been largely hampered by the high cost as well as the insufficient activity of the current Pt-based anode catalysts. Herein, we present a bottom-up approach to the large-scale fabrication of three-dimensional (3D) hybrid materials made from ultrafine Pt nanoparticles as well as B- and N-codoped graphene aerogel (BN-GA). The resulting Pt/BN-GA catalyst possesses 3D cross-linked porous networks, large specific surface areas, numerous B and N active sites, homogeneous Pt dispersion, and good electrical conductivity, which are all desirable for the anode catalytic system in direct methanol fuel cells. As a consequence, outstanding electrochemical properties in terms of high catalytic activity, reliable long-term durability, and strong antitoxic ability are achieved for the Pt/BN-GA catalyst, significantly superior to those for the conventional Pt/carbon black, Pt/graphene, and Pt/graphene aerogel catalysts. Density functional theory (DFT) calculations further reveal that the dramatically enhanced catalytic performance is attributed to the strong interaction between Pt and the BN-GA support, which generates remarkable synergetic coupling effects that enable rapid kinetics for the methanol oxidation reaction.
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The strong interaction between N and metal is conducive to firmly anchoring the metal on the base material, enhancing electrochemical stability of the catalyst.
“The strong interaction between N and metal is conducive to firmly anchoring the metal on the base material, so as to enhance the electrochemical stability of the catalyst [28].”
Doping carbon materials with N heteroatom has a positive effect on anchoring metal nanoparticles.
“As reported, doping carbon materials with N heteroatom has a positive effect on the anchoring of metal nanoparticles.”
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- Authors
- Li, M., Jiang, Q., Yan, M., Wei, Y., Zong, J., Zhang, J., Wu, Y., & Huang, H.
- Affiliations
- Hohai University (CN)
- Corresponding author
- Huang, Huajie
- Venue
- ACS Sustainable Chemistry & Engineering
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-04-04
- Volume
- 6
- Issue
- 5
- Pages
- 6644-6653
- ISSN
- 2168-0485 (ISSN-L)
- OpenAlex
- W2795603459
- Cited by
- 95
- References
- 62
- Citations by year
- 2026: 5 · 2025: 5 · 2024: 17 · 2023: 11 · 2022: 21 · 2021: 9 · 2020: 10 · 2019: 14 · 2018: 3
- FWCI
- 2.08
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ACS Sustainable Chemistry & Engineering (publishedVersion)
- Funders
- China Postdoctoral Science Foundation (2016T90414, 2015M580387)
- Natural Science Foundation of Jiangsu Province (BK20160871)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Keywords
- methanol oxidation, direct methanol fuel cells, platinum nanoparticles, graphene aerogel, electrocatalysts, Pt-support interaction, synergistic effect, anode catalysts
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