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Acyl anion free N-heterocyclic carbene organocatalysis
Abstract
Reaction discovery using N-heterocyclic carbene organocatalysis has been dominated by the chemistry of acyl anion equivalents. Recent studies demonstrate that NHCs are far more diverse catalysts, with a variety of reactions discovered that proceed without acyl anion equivalent formation. In this tutorial review selected examples of acyl anion free NHC catalysis using carbonyl compounds are presented.
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Cited by
A Dual Lewis Base Activation Strategy for Enantioselective Carbene-Catalyzed Annulations
Izquierdo, J., Orue, A., & Scheidt, K. A. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405833m · Cited by 332
Shee, S., Mukherjee, S., Gonnade, R. G., & Biju, A. T. (2020) · Organic Letters · doi:10.1021/acs.orglett.0c01756 · Cited by 34
Metadata
- Authors
- Ryan, S. J., Candish, L., & Lupton, D. W.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 42
- Issue
- 12
- Pages
- 4906
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2107167062
- Cited by
- 827
- References
- 0
- FWCI
- 3.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ryan, S. J., Candish, L., & Lupton, D. W. (2013). Acyl anion free N-heterocyclic carbene organocatalysis. Chemical Society Reviews. https://doi.org/10.1039/c3cs35522e
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
