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Flower-like hierarchical h-MoO3: new findings of efficient visible light driven nano photocatalyst for methylene blue degradation

Chithambararaj, A., Sanjini, N. S., Bose, A. Chandra, Velmathi, S.·2013·Catalysis Science & Technology

Abstract

Hexagonal molybdenum oxide (h-MoO3) nanocrystals with a flower-like hierarchical structure have been successfully synthesized by a solution based self assembly route. The as-synthesized h-MoO3 was recognized as a photocatalyst for the photocatalytic degradation of methylene blue (MB) under various experimental conditions. Initially, the as-synthesized h-MoO3 was characterized by different physico-chemical techniques in order to study and reveal the structural, functional, morphological, and optical properties. The results indicated that the photocatalyst has a hexagonal crystal structure with an average crystallite size of 46 nm. The morphology analysis has proved that the h-MoO3 comprises one dimensional (1D) rods with a hexagonal cross section. The possible formation mechanism is proposed as a self assembly process for nucleation and an Ostwald ripening mechanism for particle growth. The optical band gap investigation showed that the Eg value of h-MoO3 (2.94 eV) lies in the visible region and can be an appropriate candidate for visible light photocatalytic application. Furthermore, the experimental observations demonstrate an excellent photocatalytic performance of h-MoO3 in the degradation of MB under visible light irradiation.

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Metadata

Authors
Chithambararaj, A., Sanjini, N. S., Bose, A. C., & Velmathi, S.
Venue
Catalysis Science & Technology
Published
2013
Volume
3
Issue
5
Pages
1405
ISSN
  • 2044-4753 (ISSN-L)
  • 2044-4761
OpenAlex
W2107853095
Cited by
272
References
22
FWCI
4.09
Type
journal article
Language
en
Open access
closed

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Chithambararaj, A., Sanjini, N. S., Bose, A. C., & Velmathi, S. (2013). Flower-like hierarchical h-MoO3: new findings of efficient visible light driven nano photocatalyst for methylene blue degradation. Catalysis Science & Technology. https://doi.org/10.1039/c3cy20764a

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