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A nanoporous molybdenum carbide nanowire as an electrocatalyst for hydrogen evolution reaction
Open accessAbstract
A highly active and stable electrochemical catalyst of nanoporous molybdenum carbide nanowires (np-Mo2C NWs) has been developed for hydrogen evolution reaction (HER). The np-Mo2C NWs were synthesized simply by pyrolysis of a MoOx/amine hybrid precursor with sub-nanosized periodic structure under an inert atmosphere. The enriched nanoporosity and large reactive surface of these highly dispersed nanowires with uniform Mo2C nanocrystallites provide an efficient electrocatalysis, leading to their superior HER activity with lower onset overpotential and higher current densities than Mo2C microparticles. This study opens a new perspective for the development of highly active non-noble electrocatalysts for hydrogen production from water splitting.
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Vrubel, H., Moehl, T., Grätzel, M., & Hu, X. (2013) · Chemical Communications · doi:10.1039/c3cc45416a · Cited by 335
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Cited by
Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Self-citationDesign of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
Roger, I., Shipman, M. A., & Symes, M. D. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-016-0003 · Cited by 3,503
Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles
Zhu, J., Hu, L., Zhao, P., Lee, L. Y. S., & Wong, K.-Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00248 · Cited by 3,133
Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution
Morales-Guio, C. G., Stern, L.-A., & Hu, X. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60468c · Cited by 2,437
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Metadata
- Authors
- Liao, L., Wang, S., Xiao, J., Bian, X., Zhang, Y., Scanlon, M. D., Hu, X., Tang, Y., Liu, B., & Girault, H. H.
- Venue
- Energy Environ. Sci.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 7
- Issue
- 1
- Pages
- 387-392
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2043349833
- Cited by
- 1,044
- References
- 1
- FWCI
- 30.78
- Type
- journal article
- Language
- en
- Open access
- green
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- Liao, L., Wang, S., Xiao, J., Bian, X., Zhang, Y., Scanlon, M. D., Hu, X., Tang, Y., Liu, B., & Girault, H. H. (2014). A nanoporous molybdenum carbide nanowire as an electrocatalyst for hydrogen evolution reaction. Energy Environ. Sci. https://doi.org/10.1039/c3ee42441c
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