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Cited by 263

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One-pot selective conversion of furfural into 1,5-pentanediol over a Pd-added Ir–ReOx/SiO2bifunctional catalyst

Liu, Sibao, Amada, Yasushi, Tamura, Masazumi, Nakagawa, Yoshinao, Tomishige, Keiichi·2014·Green Chem.

Abstract

One-pot selective conversion of furfural into 1,5-pentanediol (1,5-PeD) was carried out over Pd-added Ir–ReOx/SiO2catalysts through two-step reaction temperatures. The Pd(0.66 wt%)–Ir–ReOx/SiO2catalyst showed the best performance in the production of 1,5-PeD from furfural. The maximum yield of 1,5-PeD was 71.4%. The furfural conversion and yield of 1,5-PeD was almost maintained during four repeated tests when the catalyst was calcined again. The characterization results from TPR, XRD, XANES, EXAFS and FT-IR of adsorbed CO indicated that Pd–Ir–ReOx/SiO2catalysts consisted of ReOx-modified Pd metal particles and ReOx-modified Ir metal particles. The lower-temperature reaction step was very crucial for the total hydrogenation of furfural into a tetrahydrofurfuryl alcohol intermediate, which was converted into 1,5-PeD by hydrogenolysis during the high temperature step over the ReOx-modified Ir metal particles.

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Metadata

Authors
Liu, S., Amada, Y., Tamura, M., Nakagawa, Y., & Tomishige, K.
Venue
Green Chem.
Published
2014
Volume
16
Issue
2
Pages
617-626
ISSN
  • 1463-9262 (ISSN-L)
  • 1463-9270
OpenAlex
W2017742383
Cited by
263
References
4
FWCI
9.03
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: One-pot selective conversion of furfural into 1,5-pentanediol over a Pd-added Ir–ReOx/SiO2bifunctional catalyst. https://app.cochat.ai/papers/10.1039/c3gc41335g
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Liu, S., Amada, Y., Tamura, M., Nakagawa, Y., & Tomishige, K. (2014). One-pot selective conversion of furfural into 1,5-pentanediol over a Pd-added Ir–ReOx/SiO2bifunctional catalyst. Green Chem. https://doi.org/10.1039/c3gc41335g

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