The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
A perspective on oxygenated species in the refinery integration of pyrolysis oil
Abstract
Pyrolysis offers a rapid and efficient means to depolymerize lignocellulosic biomass, resulting in gas, liquid, and solid products with varying yields and compositions depending on the process conditions. With respect to manufacture of “drop-in” liquid transportation fuels from biomass, a potential benefit from pyrolysis arises from the production of a liquid or vapor that could possibly be integrated into existing refinery infrastructure, thus offsetting the capital-intensive investment needed for a smaller scale, standalone biofuels production facility. However, pyrolysis typically yields a significant amount of reactive, oxygenated species including organic acids, aldehydes, ketones, and oxygenated aromatics. These oxygenated species present significant challenges that will undoubtedly require pre-processing of a pyrolysis-derived stream before the pyrolysis oil can be integrated into the existing refinery infrastructure. Here we present a perspective of how the overall chemistry of pyrolysis products must be modified to ensure optimal integration in standard petroleum refineries, and we explore the various points of integration in the refinery infrastructure. In addition, we identify several research and development needs that will answer critical questions regarding the technical and economic feasibility of refinery integration of pyrolysis-derived products.
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Cites
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review
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Product Distribution from the Fast Pyrolysis of Hemicellulose
Patwardhan, P. R., Brown, R. C., & Shanks, B. H. (2011) · ChemSusChem · doi:10.1002/cssc.201000425 · Cited by 463
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Fast Pyrolysis Bio-Oils from Wood and Agricultural Residues
Oasmaa, A., Solantausta, Y., Arpiainen, V., Kuoppala, E., & Sipilä, K. (2010) · Energy & Fuels · doi:10.1021/ef901107f · Cited by 407
Distinguishing primary and secondary reactions of cellulose pyrolysis
Patwardhan, P. R., Dalluge, D. L., Shanks, B. H., & Brown, R. C. (2011) · Bioresource Technology · doi:10.1016/j.biortech.2011.02.018 · Cited by 352
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Self-citationde Miguel Mercader, F., Groeneveld, M. J., Kersten, S. R. A., Geantet, C., Toussaint, G., Way, N. W. J., Schaverien, C. J., & Hogendoorn, K. J. A. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00523a · Cited by 218
Product compositions and kinetics in the rapid pyrolysis of milled wood lignin
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Cited by
Ghodake, G. S., Shinde, S. K., Kadam, A. A., Saratale, R. G., Saratale, G. D., Kumar, M., Palem, R. R., AL-Shwaiman, H. A., Elgorban, A. M., Syed, A., et al. (2021) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2021.126645 · Cited by 414
Bio-oil from fast pyrolysis of lignin: Effects of process and upgrading parameters
Fan, L., Zhang, Y., Liu, S., Zhou, N., Chen, P., Cheng, Y., Addy, M., Lu, Q., Omar, M. M., Liu, Y., et al. (2017) · Bioresource Technology · doi:10.1016/j.biortech.2017.05.129 · Cited by 265
Metadata
- Authors
- Talmadge, M. S., Baldwin, R. M., Biddy, M. J., McCormick, R. L., Beckham, G. T., Ferguson, G. A., Czernik, S., Magrini-Bair, K. A., Foust, T. D., Metelski, P. D., Hetrick, C., & Nimlos, M. R.
- Venue
- Green Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 16
- Issue
- 2
- Pages
- 407-453
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2049123266
- Cited by
- 272
- References
- 9
- FWCI
- 12.40
- Type
- journal article
- Language
- en
- Open access
- closed
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- Talmadge, M. S., Baldwin, R. M., Biddy, M. J., McCormick, R. L., Beckham, G. T., Ferguson, G. A., Czernik, S., Magrini-Bair, K. A., Foust, T. D., Metelski, P. D., Hetrick, C., & Nimlos, M. R. (2014). A perspective on oxygenated species in the refinery integration of pyrolysis oil. Green Chem. https://doi.org/10.1039/c3gc41951g
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