Sustainable polyesters for powder coating applications from recycled PET, isosorbide and succinic acid
Abstract
A new method for the synthesis of polyesters that combines the chemical recycling of poly(ethylene terephthalate) (PET) with the use of monomers derived from renewable resources, such as isosorbide and succinic acid, has been developed. A kinetic study has been performed in order to determine the best catalyst for PET depolymerisation with isosorbide and for the subsequent polycondensation of PET oligomers with succinic acid. Using the correct amounts of isosorbide and succinic acid it is possible to obtain polymers which well fit the properties (glass transition temperature and end-group composition) necessary for powder coating applications. The coating produced using this new environmentally friendly approach presents applicative properties similar, and in some cases superior, to those of a commercial coating obtained from non-renewable resources.
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Colonna reported a two-step one-pot strategy for converting PET to new polyesters using monomers available from renewable sources.
“Colonna reported a two-step one-pot strategy for converting PET to new polyesters using monomers available from renewable sources.414”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [414]
In the first step, PET was depolymerized using isosorbide to oligomers, which were chain extended by succinic acid in the second step to form a novel copolyester.
“In the first step, PET was depolymerized using isosorbide to oligomers, which were chain extended by succinic acid in the second step to form a novel copolyester (Scheme 18).”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [414]
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- Authors
- Gioia, C., Vannini, M., Marchese, P., Minesso, A., Cavalieri, R., Colonna, M., & Celli, A.
- Affiliations
- University of Bologna (IT)
- Corresponding author
- Colonna, M.
- Venue
- Green Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 16
- Issue
- 4
- Pages
- 1807-1815
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2135262848
- Cited by
- 71
- References
- 29
- Citations by year
- 2026: 4 · 2025: 2 · 2024: 2 · 2023: 7 · 2022: 6 · 2021: 5 · 2020: 8 · 2019: 6 · 2018: 10 · 2017: 5 · 2016: 8 · 2015: 8
- FWCI
- 2.04
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Green Chemistry (publishedVersion)
- Archivio istituzionale della ricerca (Alma Mater Studiorum Università di Bologna) (submittedVersion)
- Iris (University of Trento) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Keywords
- recycled PET, polyester synthesis, isosorbide, succinic acid, chemical recycling, PET depolymerization, polycondensation, powder coatings, kinetic analysis, catalyst selection, glass transition temperature, renewable monomers, sustainable polymers
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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